• Title/Summary/Keyword: Green Hydrogen

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Effects of Heterologous Expression of Thioredoxin Reductase on the Level of Reactive Oxygen Species in COS-7 Cells

  • Kang, Hyun-Jung;Hong, Sung-Min;Kim, Byung-Chul;Park, Eun-Hee;Ahn, Kisup;Lim, Chang-Jin
    • Molecules and Cells
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    • v.22 no.1
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    • pp.113-118
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    • 2006
  • Thioredoxin reductase (TrxR), a component of the redox control system involving thioredoxin (Trx), is implicated in defense against oxidative stress, control of cell growth and proliferation, and regulation of apoptosis. In the present study a stable transfectant was made by introducing the vector pcDNA3.0 harboring the fission yeast TrxR gene into COS-7 African green monkey kidney fibroblast cells. The exogenous TrxR gene led to an increase in TrxR activity of up to 3.2-fold but did not affect glutathione (GSH) content, or glutaredoxin and caspase-3 activities. Levels of reactive oxygen species (ROS), but not those of nitric oxide (NO), were reduced. Conversely, 1-chloro-2,4-dinitrobezene (CDNB), an irreversible inhibitor of mammalian TrxR, enhanced ROS levels in the COS-7 cells. After treatment with hydrogen peroxide, the level of intracellular ROS was lower in the transfectants than in the vector control cells. These results confirm that TrxR is a crucial determinant of the level of cellular ROS during oxidative stress as well as in the normal state.

Operation Results of the SOFC System Using 2 Sub-Module Stacks (2 모듈 스택을 이용한 SOFC 시스템 운전결과)

  • Lee, Tae-Hee
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.405-411
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    • 2010
  • A 5kW class SOFC cogeneration system consisted of a hot box part, a cold BOP (balance of plant) part, and a hot water reservoir. The hot box part contained a stack, a fuel reformer, a catalytic combustor, and heat exchangers. A cold BOP part was composed of blowers, pumps, a water trap, and system control units. A 5kW stack was designed to integrate 2 sub-modules. In this paper, the 5kW class SOFC system was operated using 2 short stacks connected in parallel to test the sub-module and the system. A short stack had 15 cells with $15{\times}15 cm^2$ area. When a natural gas was used, the total power was about 1.38 kW at 120A. Because the sub-modules were connected in parallel and current was loaded using a DC load, voltages of sub-modules were same and the currents were distributed according to the resistance of sub-modules. The voltage of the first stack was 11.46 V at 61A and the voltage of the second stack was 11.49V at 59A.

Heat-treatment effects on oxygen evolution reaction of nickel-cobalt layered double hydroxide

  • Lee, Jung-Il;Ko, Daehyeon;Mhin, Sungwook;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.3
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    • pp.143-148
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    • 2021
  • Alkaline oxygen evolution reaction (OER) electrocatalysts have been widely studied for improving the efficiency and green hydrogen production through electrochemical water splitting. Transition metal-based electrocatalysts have emerged as promising materials that can significantly reduce the hydrogen production costs. Among the available electrocatalysts, transition metal-based layered double hydroxides (LDHs) have demonstrated outstanding OER performance owing to the abundant active sites and favorable adsorption-desorption energies for OER intermediates. Currently, cobalt doped nickel LDHs (NiCo LDHs) are regarded as the benchmark electrocatalyst for alkaline OER, primarily owing to the physicochemical synergetic effects between Ni and Co. We report effects of heat-treatment of the as-grown NiCo LDH on electrocatalytic activities in a temperature range from 250 to 400℃. Electrocatalytic OER properties were analysed by linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). The heat-treatment temperature was found to play a crucial role in catalytic activity. The optimum heat-treatment temperature was discussed with respect to their OER performance.

Mode 1 Fracture Toughness Test of CNT/Epoxy Composites with Different CNT Content (CNT 함량에 따른 CNT/Epoxy 복합재료 제작 및 모드 1 파괴 인성 평가)

  • KWON, DONG-JUN;YOO, HYEONGMIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.1
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    • pp.86-91
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    • 2021
  • In order to save the energy in vehicles using renewable energy, it is necessary to reduce the weight of parts with polymer matrix composites. Carbon nanotube (CNT) is the nano-scale reinforcement used to increase the interlaminar strength of fiber reinforced composites or enhance the fracture toughness of polymer. However, since the degree of improvement in mechanical properties varies according to the various experimental conditions such as shape of reinforcement, types of matrix and dispersion of reinforcement, research to find the optimal conditions is essentially needed. In this study, CNT/epoxy composites with different CNT concentration were fabricated under the same conditions, and the optimal CNT content (2 wt%) was found through Mode 1 fracture toughness test. Furthermore, through optical microscopy, it was confirmed that the fracture toughness was rather decreased due to the CNT aggregation when the CNT content exceeded 2 wt%.

Economic Analysis Study on the R&D Effect of Performance Improvement of the Tri-generation Fuel Cell System (연료전지 삼중열병합 시스템의 성능개선 R&D 효과에 대한 경제성 분석 연구)

  • Ahn, Jong-Deuk;Lee, Kwan-Young;Seo, Seok-Ho
    • New & Renewable Energy
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    • v.18 no.2
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    • pp.26-39
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    • 2022
  • Considering the recent substantial increase in national research and development (R&D) budgets in the energy sector there has been increased Interest in the effectiveness of government R&D investments. We conducted a case study to calculate the allowable scale and effectiveness of R&D investment by calculating the direct performance improvement effect resulting from R&D investment as an economic value. Using conditions that existed prior to R&D investments as a reference, five cases in which performance improved due to R&D investments were compared and analyzed. The government's financial investment is increasing rapidly in line with the establishment of the national hydrogen roadmap. R&D is needed to enhance the current low technology readiness level of hydrogen fuel cells compared to solar and wind energy fields. Therefore, an R&D project to improve the performance of the fuel cell system was selected as this case study's subject. Using the results in this study, the allowable level of investment in the task unit of national R&D projects could be calculated. Moreover, it is advisable to provide a standard for rational decision making for new R&D investments since it is possible to determine investment priorities among a large number of candidates.

Effects of Environmental Infrastructure Regeneration in Urban Region - A Case Study of M Apartment Complex in Daejeon (도시 단지내 환경 인프라 재생 효과 고찰 - 대전시 M 아파트 단지 사례연구)

  • Park, Kiyong;Choi, Changkyoo;Shin, Jongseok;Park, Heekyeng
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.2
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    • pp.353-359
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    • 2015
  • This study introduces a resource recycling system in urban apartment complex using four different technologies. The four technologies, called 4G, include a production technology for reclaimed water (Green water), a biogas production technology from organic waste (Green biogas), a reuse technology of rainwater (Green rainwater), and urban agropark (Green pyramid). Green water is the technology for producing the reclaimed water from wastewater, rainwater and underground water, and the average concentrations of BOD, SS, T-N and coliform of reclaimed water were 7.8mg/L, ND (not detected), 4.9mg/L and ND, respectively. Green biogas is the technology for producing biogas and effluent after treating organic wastes (e.g. food waste and night soil) discharged from households, and the average production rates of hydrogen and methane were $0.33m^3/m^3/d$ and $0.24m^3/m^3/d$, respectively. Green pyramid, agricultural farm operated by biogas and reclaimed water, provides a healthy and recreational space for residents, and plant growth rates using treated water and reclaimed water showed height of 1.32cm and weight of 112.8g. Therefore, 4G technologies can improve the recycling rate and treatment efficiencies of waste and wastewater in an apartment complex.

EV Energy Convergence Plan for Reshaping the European Automobile Industry According to the Green Deal Policy (그린딜 정책에 따른 유럽자동차 산업재편의 EV 에너지 융합방안)

  • Seo, Dae-Sung
    • Journal of Convergence for Information Technology
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    • v.11 no.6
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    • pp.40-48
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    • 2021
  • The paper dealt with the fact that the green deal took place when the demand for electrical energy surged. However, the procurement of electric vehicles and much of the electric energy of the future still depends on fossil fuels. Accordingly, the importance of the IT industry is highlighted, and the demand for hydrogen-electric vehicles and related industries increases. The method of this study investigated the relevance of EV charging as a future next-generation power source rather than the electric energy demand of the IT industry. This study derives the correlation between industrial electricity and household energy PPP according to economic growth through empirical regression analysis. As the result, it was found that the amount of change, including electric and next-generation electric vehicles, was significant for on thirds of the countries in the change in purchasing power compared to GDP. This affects overall purchasing power as twelve out of thirty two countries with EV demand (Italy, Canada, Switzerland, Poland, Slovenia, Germany, Slovakia, Finland, Sweden, Czech Republic, Estonia, Denmark) are more sensitive to electric energy. This is related to the charging of EVs or hydrogen as the next-generation power of the future rather than the electric energy demand of the IT industry. By preventing waste of unused electricity of IT-electric energy sources and charging-preserving hydrogen electricity, it seems indispensable to prepare for the national IT power conservation buffer facility for supply and demand in future growth.

Microbial Reduction of Fresh Vegetables by Treatment of Sanitizing Reagents (살균제의 처리에 의한 신선엽채류의 미생물 감소)

  • Park Heon-Kuk;Kim Sang-Bum
    • The Korean Journal of Food And Nutrition
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    • v.17 no.4
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    • pp.436-441
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    • 2004
  • As the production of agricultural products showing high quality and environmental safety is required increasingly these days, it is really necessary to study on technology for producing agricultural products which are safe microbiologically. Among several sanitizing reagents contacted easily, we investigated the most effective and useful method for reducing microorganisms by sanitizer treatment. From this study, it was showed that treatment of 3% hydrogen peroxide solution over 1 minute, which decreased microbiological level less than one tenth of natural state(no sanitizer treatment) in all microorganisms tested, was the most effective sanitizing method to green vegetables, especially raw lettuce used in this study, for reducing microorganisms. By utilizing this sanitizing method in farming step, the improvement of safety and added value of agricultural products, especially raw green vegetables, is expected.

Effects of Calcination Temperature on Characteristics of Electrospun TiO2 Catalyst Supports for PEMFCs (열처리 온도가 전기방사방법을 이용하여 제조한 PEMFC용 TiO2 담체의 물리적 특성에 미치는 영향)

  • Kwon, Chorong;Yoo, Sungjong;Jang, Jonghyun;Kim, Hyoungjuhn;Kim, Jihyun;Cho, Eunae
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.3
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    • pp.223-229
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    • 2013
  • Polymer Electrolyte Membrane Fuel Cell (PEMFC) is a power generation system to convert chemical energy of fuels and oxidants to electricity directly by electrochemical reactions. As a catalyst support for PEMFCs, carbon black has been generally used due to its large surface area and high electrical conductivity. However, under certain circumstances (start up/shut down, fuel starvation, ice formation etc.), carbon supports are subjected to serve corrosion in the presence of water. Therefore, it would be desirable to switch carbon supports to corrosion-resistive support materials such as metal oxide. $TiO_2$ has been attractive as a support with its stability in fuel cell operation atmosphere, low cost, commercial availability, and the ease to control size and structure. However, low electrical conductivity of $TiO_2$ still inhibits its application to catalyst support for PEMFCs. In this paper, to explore feasibility of $TiO_2$ as a catalyst support for PEMFCs, $TiO_2$ nanofibers were synthesized by electrospinning and calcinated at 600, 700, 800 and $900^{\circ}C$. Effects of calcination temperature on crystal structure and electrical conductivity of electrospun $TiO_2$ nanofibers were examined. Electrical conductivity of $TiO_2$ nanofibers increased significantly with increasing calcination temperature from $600^{\circ}C$ to $700^{\circ}C$ and then increased gradually with increasing the calcination temperature from $700^{\circ}C$ to $900^{\circ}C$. It was revealed that the remarkable increase in electrical conductivity could be attributed to phase transition of $TiO_2$ nanofibers from anatase to rutile at the temperature range from $600^{\circ}C$ to $700^{\circ}C$.

Biohydrogen Production from Food Waste by Two-Stage (Lactate+Photo)-Fermentation Process (2단(유산발효+광발효) 발효공정을 통한 음식물쓰레기로부터의 수소생산)

  • Kim, Ok-Sun;Son, Han-Na;Kim, Dong-Hoon;Jeon, Dong-Jin;Rhee, Young-Woo;Kim, Mi-Sun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.333-339
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    • 2011
  • In the present work, it was attempted to produce $H_2$ from food waste by the two-stage fermentation system. Food waste was acidified to lactate by using indigenous lactic acid bacteria under mesophilic condition, and the lactate fermentation effluent (LFE) was subsequently converted to $H_2$ by photo-fermentation. $Rhodobacter$ $sphaeroides$ KD131 was used as the photo-fermenting bacteria. The optimal conditions for lactate fermentation were found to be pH of 5.5 and substrate concentration of 30 g Carbo. COD/L, under which yielded 1.6 mol lactate/mol glucose. By filtering the LFE and adding trace metal, $H_2$ production increased by more than three times compared to using raw LFE, and finally reached the $H_2$ yield of 3.6 mol $H_2$/mol lactate. Via the developed two-stage fermentation system $H_2$ yield of 5.8 mol $H_2$/mol glucose was achieved from food waste, whose value was the highest that ever recorded.