• 제목/요약/키워드: Grain growth mechanism

검색결과 124건 처리시간 0.021초

Interface between the Electroplated Copper-cobalt Thin Films and the Substrate

  • Kim, Jin-Gyu;Lee, Jung-ju;Bae, Jong-hak;Bang, Won-bae;Hong, Kim-in;Yoon, C. H.;Son, Derac;Jeong, Kee-ju
    • Journal of Magnetics
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    • 제11권3호
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    • pp.119-122
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    • 2006
  • We electroplated copper-cobalt thin films on a silicon substrate, which had 150 nm thick copper seed layer. The adhesion between the two metallic layers could be increased by utilizing a proper organic additive, pulse plating technique, and high temperature annealing. The thin films exhibited columnar growth of the deposits and enhanced adhesion. This is attributed to the grain growth mechanism introduced by the additive and annealing.

조대조직을 갖는 비자성강의 피로균열진전거동 (A Behavior of Fatigue Crack Growth of Nonmagnetic Steel with Large Grain Size)

  • 이종형;최성대;정선환;권현규;양성현
    • 한국기계가공학회지
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    • 제3권4호
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    • pp.88-94
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    • 2004
  • High manganese steel was maintained stability of Non-Magnetics performance. Fatigue tests were carried out under constant stress amplitude, using a non-magnetic high manganese steel. The fatigue crack growth mechanism of the high manganese steel was clarified from results such as observation of crack growth path and fracture surface. The result of getting this study was shown as following: 1) Remarkably ${\Delta}Kth$ of the high manganese steel is big with about 3 times of the general steel product. 2) In the low ${\Delta}K$ value region, da/dN is dependent on Kmax, and in the high ${\Delta}K$ value region, it is dependent on ${\Delta}Keff$. The reason of this behavior is crack closure due to fracture surface roughness and fretting oxide. 3) It seems to ease the stress concentration of crack tip crack growth behavior in the ${\Delta}Kth$ vicinity by the generation of the secondary crack.

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낙산사 칠층석탑에 발달한 표면균열의 특성과 성장 메커니즘 (A Study on the Characteristics and the Growth Mechanism of Surface Cracks from the Naksansa Seven-Storied Stone Pagoda, Korea)

  • 박성철;김재환;좌용주
    • 헤리티지:역사와 과학
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    • 제46권2호
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    • pp.136-149
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    • 2013
  • 보물 제499호로 지정되어 있는 낙산사 칠층석탑에 대해 표면풍화로 인한 표면균열 발달 양상을 연구하였다. 이 석탑의 석재는 흑운모 화강암과 각섬석-흑운모 화강암으로, 중립질 이상의 입자크기와 회백색을 띄며 특징적으로 거정의 장석 반정을 수반하는 반상조직이 나타난다. 석탑에 나타나는 표면균열은 기단부 및 1층 탑신에서 많이 관찰되며, 대부분 수직, 수평, 대각선 방향으로 발달하고 있다. 석탑에 사용된 석재 내부의 미세균열은 원래부터 리프트 결과 그레인 결의 방향으로 잘 발달한 것이며, 이 두 결이 균열성장과 그에 따른 손상을 야기한 것으로 판단된다. 이와 더불어 석탑에서 나타나는 수직균열은 탑의 자체 하중에 의한 압축응력과 평행하게 미세균열이 성장하였으며, 수평균열은 주 압축응력에 대한 반발 인장력이 균열의 성장을 촉진시킨 것으로 판단된다. 한편, 석탑의 남동쪽 부재 탈락은 압축과 인장에 의한 것과 더불어 거정질 알칼리장석 반정의 벽개와 쌍정면의 영향으로 인해 발생한 것으로 해석된다.

MA법으로 제조된 Ni기 합금에서 Y2O3 첨가에 따른 인장강도변화와 시효처리 효과 (Variation of Tensile Strength by Addition of Y2O3 and Effect of Aging Treatment in Ni Base Alloy Fabricated by MA Method)

  • 김일호;이원식;고세현;장진만;권숙인
    • 한국분말재료학회지
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    • 제15권1호
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    • pp.23-30
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    • 2008
  • Ni-20Cr-20Fe-5Nb alloy with or without $Y_2O_3$ was manufactured by mechanical alloying process and consolidated by spark plasma sintering (SPS). The grain size of the alloy with $Y_2O_3$ was smaller than that of alloy without $Y_2O_3$ which results from the effect of $Y_2O_3$ suppressing grain growth. The tensile strength at room temperature was increased by the addition of $Y_2O_3$ but decreased abruptly at temperature above $600^{\circ}C$. It seems to result from the change of deformation mechanism due to fine grain size, that is, grain boundary sliding is predominant at above $600^{\circ}C$ while internal dislocation movement is predominant at below $600^{\circ}C$. After conventional heat treatment process of solution treatment and aging, a small amount of ${\delta}(Ni_3Nb)$ phase was formed in Ni-20Cr-20Fe-5Nb alloy while a large amount of ${\gamma}"(Ni_3Nb)$ was formed in Inconel 718 in the previous report. This is due to exhaustion of Nb content by the formation of NbC during consolidation.

On-Film Formation of Nanowires for High-efficiency Thermoelectric Devices

  • Ham, Jin-Hee;Shim, Woo-Young;Lee, Seung-Hyun;Voorhees, Peter W.;Lee, Woo-Young
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.17-17
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    • 2009
  • We report the invention of a direct growth method termed On-Film Formation of Nanowire (OFF-ON) for making high-quality single-crystal nanowires, i.e. Bi and $Bi_2Te_3$, without the use of conventional templates, catalysts, or starting materials. We have used the OFF-ON technique to grow single crystal semi-metallic Bi and compound semiconductor $Bi_2Te_3$ nanowires from sputtered Bi and BiTe films after thermal annealing, respectively. The mechanism for nanowire growth is stress-induced mass flow along grain boundaries in the polycrystalline films. OFF-ON is a simple but powerful method for growing perfect single-crystal semi-metallic and compound semiconductor nanowires of high aspect ratio with high crystallinity that distinguishes it from other competitive growth approaches that have been developed to date. Our results suggest that Bi and $Bi_2Te_3$ nanowires grown by OFF-ON can be an ideal material system for exploring their unique thermoelectric properties due to their high-quality single crystalline and high conductivity, which have consequence and relevance for high-efficiency thermoelectric devices.

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Output and Real Exchange Rate in Developing Countries: Evidence from China

  • Huan, Xingang;He, Yugang
    • 산경연구논집
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    • 제8권5호
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    • pp.7-13
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    • 2017
  • Purpose - The purpose of this paper is to analyze the relationship between the real exchange rate and the output, which is based on the macroeconomic equilibrium theory in China. Its aim will be to verify whether the change in the real exchange rate has a significant effect on the output or not. Research design, data, and methodology - This study endeavors tries to investigate the correlation among economic variables under the macroeconomic market (the commodity market and the money market) equilibrium. So, time-series data from 1990 to 2016 is applied to establish a vector auto-regression (VAR) model so as to perform an empirical analysis. Results - The empirical results reveal that an increase in the real exchange rate will result in an increase in the output in the short run. However, the empirical results also indicate that this kind of mechanism cannot work in the long run. Conclusions - The effect of a decrease of real exchange rate on output is significant in the short run. Also, this paper suggests that the total supply and the total demand can promote economic growth. The fiscal and money policy play a significant role in economic growth in China as well.

Ultraviolet-B radiation sensitivities in rice plant: cyclobutane pyrimidine dimer photolyase activities and gene mutations

  • Hidema, Jun;Kumagai, Tadashi
    • 한국식물생명공학회:학술대회논문집
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    • 한국식물생명공학회 2004년도 생명공학 실용화를 위한 비젼
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    • pp.29-34
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    • 2004
  • Reduction in stratospheric ozone layer increases the amount of ultraviolet-B radiation (UVB: 280-320 nm) that reaches the earth ’ s surface. UVB radiationcan damage plants, resulting in decrease in growth and productivity. UVB-augmentation studies have indicated that the sensitivity to UVB radiation in plants varies among the species and cultivars. However. there are no definitive answers for the mechanisms of UVB-resistance in higher plants and for bioengineering design and development of UVB-tolerant plants. We have been studying physiological and biochemical aspects of the effects of UVB radiation on growth and yield of rice COryza sativa LJ. aiming to clarify the mechanism of resistance to UVB radiationin rice. At this meeting. weintroduce our research as followed: (1) supplementary UVB radiation has inhibitory effects on the growth. yield and grain development of rice; (2) UVB sensitivity of rice varies widely among cultivars; (3) among Japanese rice cultivars. Sasanishiki. a leading variety in northeast Japan. is more resistant to UVB. while Norin 1. a progenitor of Sasanishiki. is less resistant; (4)UV-sensitive Norin 1 cultivar is deficient in photorepair of UVB-induced cyclobutane pyrimidine dimer (CPD). and this deficiency results from one amino acid residue alteration of CPD photolyase. These results suggest that spontaneously occurring mutation in CPD photolyase gene could lead to difference in UVB sensitivity in rice. and that CPD photolyase might be a useful target for improving UVB-sensitivity in rice by selective breeding or bioengineering of UVB-tolerant rice.

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New Hypothesis "Exhaustion of Diffusion-Contributable Vacancies in Core/Rim Structure"

  • Hayshi, Koji;Yanaba, Yutaka
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2002년도 추계학술강연 및 발표대회
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    • pp.8-8
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    • 2002
  • TiC core/(Ti,Mo)C rim structure in TiC-$Mo_2C$-Ni base cermet which is generally prepared by sintering below 145$0^{\circ}C$ had been believed to be generated by the solid diffusion of Mo atoms 1 into TiC grains (D. Moskowitz and M.Humenik, 1r.:1966). Afterward, it was clarified that the c core/rim structure is generated by solution/re-precipitation mechanism : (1) $Mo_2C$ grains and s small TiC grains dissolve into the Ni liquid, (2) the dissolved Mo, Ti and C atoms migrate to the s surface of TiC coarse grains, (3) the Mo, Ti and C precipitate on the surface of TiC coarse g grains and form (Ti,Mo)C solid solution rim, and (4) the Ostwald ripening (grain growth by s solution/re-precipitation mechanism) of TiC-core/(Ti,Mo)-rim grains continues, and thus the w width of (Ti,Mo)C rim (at the same time, the grain size) increases with sintering time, etc. ( (H.Suzuki, K.Hayashi and O.Terada: 1973). The TiC-core was found not to disappear even by s sintering at 190$0^{\circ}C$ (ibid.: 1974) Recently, FeSi core/$Fe_2Si_5$-rim structure in Fe-66.7at%Si thermoelectric aIloy was found to also h hardly shrink and disappear by long heating at an appropriate temperature (1999: M.Tajima and K K.hayashD. Then, the authors considered its cause, and clarified experimentaIly that the disappearance of FeSi-core/$Fe_2Ski_5$-rim structure could be attributed to the exhaustion of diffusion-contributable vacancies in core/rim structure (N.Taniguchi and K.Hayashi:2001). At p present, the authors and my coworker are investigating whether the non-disappearance of TiC c core can be explained also from the new hypothesis "Exhaustion of diffusion-contributable v vacancies in corelrim structure".ure".uot;.

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Co-Cr 주조합금의 미세구조에 미치는 GPS 열처리 효과 (Effects of GPS heat-treatment on microstructure of as-cast Co-Cr alloy)

  • 류정호;이호준;조현수;팽종민;박종범;이정일
    • 한국결정성장학회지
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    • 제27권5호
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    • pp.263-267
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    • 2017
  • Co-Cr 합금은 체내 인공관절용으로 사용될 때 세포 독성이 없고, 생체조직과 반응을 일으키지 않는 뛰어난 생체적합성과 인장강도, 연신율, 내마모성 등의 기계적 성질과 우수한 내마모 특성을 보유하고 있는 것으로 알려져 있다. 또한 Co-Cr 합금은 Carbon 원소를 첨가하여 고용체 강화와 탄화물에 의한 석출강화로 기계적 성질을 향상시키고 내식성을 크게 향상시키고 있다. 본 연구에서는 정밀주조법으로 제조된 인공관절용 Co-Cr 합금 시편의 GPS(Gas Pressured Sintering) 열처리공정에 따른 결정구조 및 미세조직 등의 재료특성 변화를 고찰하였다. XRD 분석을 통하여 as-cast 시편과 GPS 열처리 공정후 시편의 결정상 변화를 고찰하였으며, 제조된 합금의 입계사이에 metal carbide($Cr_{23}C_6$) 석출물들의 생성이 증가되었음을 OM, FE-SEM, EDS 분석으로 확인하였다.

고력황동의 Hard Spots형성에 미치는 첨가원소의 영향 (The effects of addition elements on the formation of the hard spots in High strength brass)

  • 박현식;나형용
    • 한국주조공학회지
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    • 제6권1호
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    • pp.12-19
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    • 1986
  • This study was undertaken to understand the formation mechanism of the hard spots in high strength brass. To investigate the behavior of the hard spots in the isothermal liquid state with varying silicon content, the rapidly quenched specimens were obtained by suctioning the melt into the silica tube and water quenching. To examine the growth process of the hard spots with holding time, the unidirectional solidification technique was used. The results of this study are summarized as follows: 1) With the addition of Fe in order to get the effects of grain refinement in high strength brass, the two different type of Fe-rich phases are occurred, which are defined as dendritic and globular phase. The chemical composition of the globular phase was different from that of the dendritic phase in that the globular phase contained Si. 2) With increasing Si content, the Fe-rich phase had a tendency to form globular phase. 3) As the holding time increased in the liquid state, globular was also prone to coalesce. The further growth of globular phase to large size was due to reducing the interfacial energy. 4) The primary phase of copper alloy was nucleated preferentially on the dendritic phase. It was noticeable that the dendritic phase acted as a grain refiner. However, the agglomerate (hard spots) which was composed of the globular phase decreased the mechanical properties of high strength brass. 5) Once the hard spots formed in the high strength brass casting, it was very difficult to remove them. This is due to the fact that their meting temperature is higher than the pouring temperature of high strength brass.

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