• Journal of the Korean Geosynthetics Society
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• v.11 no.2
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• pp.31-38
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• 2012

The recycled aggregate for construction, slag, coal ash and such may elute leachates by chemical reaction when in touch with water, and to confirm this, generally the waste process test is executed. If the test result criteria are met, it can be used as replacement aggregate. In case of steel slag, however, the chemical reaction does not end in a short term, but occurs over a long time, generating eluted leachate. Thus, in this study, the leachate from steel slag were analyzed for heavy metal, and the pH change and environmental characteristics of eluted leachate were analyzed. According to the experiment result, the chemical reaction of free CaO and water within the steel slag occurred more actively when stirred, and the smaller the grain size, the higher the pH was. As the result of waste process test, all test items for the two types of specimen were found to have no heavy metal, but from the ICP test analysis result, heavy metals such as Al, Pb, Zn, Fe were detected. It could be confirmed that chemical reaction would occur upon contact of steel slag and water, and heavy metal may be detected depending on experiment conditions and analysis methods, the long-term environmental characteristics should be examined for utilization of steel slag.

• Journal of the Korean Geographical Society
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• v.48 no.2
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• pp.204-217
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• 2013

This study shows the geomorphological processes of Yuga alluvial fan at Dalseong-gun, Daegu in Korea, based on characteristics of geomorphological surfaces, analysis of geomorphological deposits and OSL age dating. Alluvial fans of this area are classified into three surfaces(YG-F1, YG-F2, YG-F3) and were formed by the depositional processes resulting from the changes in hydraulic geometry of flowing water which was a stream flowing out of mountains debouched on to a plain, not by a sudden decrease in surface gradient of river bed. YG-F3 surface, about 110,000 yr B.P.(MIS 5.4), was formed as Yongri river deposited a lot of debris. This result was due to the process that the deposition took place actively with the upward of base level as the last interglacial period began. Later, the denudation of the river valley and geomorphological surface constantly occurred and the local and seasonal changes were found in precipitation and stream discharge with the beginning of the interstadial of the last glacial stages(MIS 3), leading to YG-F2 formed by debris flow, earth flow, mud flow and stream flow. Then, short-term climate changes and temporal climate events repeatedly caused aggradation and denudation over time and going through these processes, YG-F1 is believed to have been made by earth flow or mudflow during the last glacial maximum(MIS 2).

• Journal of the Korean earth science society
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• v.30 no.4
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• pp.409-426
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• 2009

In the four sedimentary cores from Yeoja Bay, the analyses of grain size, benthic foraminiferal species compositions, assemblages and statistics were carried out to investigate the effects of late Holocene sea-level change on benthic foraminifera. The core sediments were mainly composed of fine-grained silt and clay. The benthic foraminifera were classified into 27 species of 16 genera, 30 species of 21 genera, 50 species of 29 genera and 52 species of 29 genera in Core YC-1 to 4, respectively. In the result of cluster analysis, it seemed that Group 1 (Core YC-1 and 2) of representative A. beccarii assemblages was deposited in upper bay environment and Group 2 (Core YC-3 and 4) of representative E. clavatum-A. beccarii assemblages was deposited in inner bay environment affected by offshore water. In the result of species composition analysis, the production frequency of A. beccarii was gradually decreased from low layer to upper layer, whereas production frequency of E. clavatum and P.F./T.F. was gradually increased to upward. These change patterns appeared in benthic and planktonic foraminifera seemed to reflect the late Holocene sea-level rise in Yeoja Bay.

• Korean Journal of Remote Sensing
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• v.26 no.5
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• pp.497-510
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• 2010

In this study, comparisons of the backscattering coefficients and the coherence values which had been extracted from SAR (Synthetic Aperture Radar) images such as JERS-1, ENVISAT and ALOS satellites with surface roughness, surface geometric and soil moisture content were carried out. As the results of analysis using the backscattering coefficient and coherence values from SAR images, the coherence was shown high in the region containing more of mud fraction due to higher viscosity of fine grain-size. A lot of tidal channels were well developed in the Ganghwa tidal flat, affecting the drainage of seawater and subsequent soil moisture content by exposure time of tidal flat. The backscattering coefficient. consequently, appeared to be lower in sand flat and mix flat with decrease of soil moisture. In contrast, most mud flats were distributed at high elevation so that soil moisture was not much influenced by seawater. The backscattering coefficient in mud flat seemed to have a relationship with the density of tidal channel. In addition, lowering backscattering coefficients in the all Ganghwa tidal flat was observed when surface remnant water increased according to the amount of rainfall. The correlation between backscattering coefficient, coherence and sediment environment factors in the Ganghwa tidal flat was investigated. In the future, more quantitative spatial analysis will be helpful to well understand the sedimentary influence of various sediment environment factors.

• The Journal of Engineering Geology
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• v.29 no.3
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• pp.303-314
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• 2019

Surface permeability and shallow geological structures play significant roles in shaping the groundwater recharge of shallow aquifers. Surface permeability can be characterized by two concepts, intrinsic permeability and hydraulic conductivity, with the latter obtained from previous near-surface geological investigations. Here we propose a hydraulic equation via the cross-correlation analysis of the rainfall-groundwater levels using a regression equation that is based on the cross-correlation between the grain size distribution curve for unconsolidated sediments and the rainfall-groundwater levels measured in the Gyeongju area, Korea, and discuss its application by comparing these results to field-based aquifer test results. The maximum cross-correlation equation between the hydraulic conductivity derived from Zunker's observation equation in a sandy alluvial aquifer and the rainfall-groundwater levels increases as a natural logarithmic function with high correlation coefficients (0.95). A 2.83% difference between the field-based aquifer test and root mean square error is observed when this regression equation is applied to the other observation wells. Therefore, rainfall-groundwater level monitoring data as well as aquifer test are very useful in estimating hydraulic conductivity.

• Journal of the Korean Society of Marine Environment & Safety
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• v.30 no.1
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• pp.20-31
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• 2024

This study was conducted to investigate the changes in the structure of benthic communities resulting from aquaculture activities and to assess the benthic health status of surface sediment in Gangjin Bay, a region known for concentrated shellfish aquaculture on the southern coast of Korea. Survey stations were divided into longline culture, bottom culture, and non-cultivation areas. The spatiotemporal distribution of physiochemical factors such as the grain size, water temperature, salinity, and total organic carbon in Gangjin Bay showed no significant differences between sampling stations. However, the species number, density, and diversity were relatively lower at the sampling stations in the bottom culture areas than at the other stations throughout the entire survey period. Cluster analysis and principal coordinates analysis also clearly distinguished the benthic communities in the bottom culture areas from those in the other sampling areas. At the sampling stations in the longline culture and non-cultivation areas, Scolectoma longifolia and Sigambra tentaculata, which are indicator species of organically enriched areas, appeared as dominant species. However, excluding some stations influenced by physical factors such as the water depth and current speed, the occupancy rate was not high. The health assessment results, conducted using the fisheries environment assessment method, revealed good conditions with Grades 1 and 2 across the entire area. However, an examination of the spatiotemporal changes in benthic communities and the benthic health index indicated that the benthic environment in the bottom culture areas was affected by physical disturbances.

• 한국해양학회지
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• v.22 no.3
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• pp.130-142
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• 1987

Sedimentological characteristics of the surface sediments in the southern sea off Cheju Island are described from analyses of bottom sediments. The sediments are subdivided into seven textural classes, muddy sand, slightly gravelly muddy sand, sand, clayey sand, sandy clay, sandymud, silty sand. Sand-size sediments are distributed in the southeastern part and/or around the Island, whereas sandy and muddy sediments are mainly distributed in the central and southern parts of the study area. A small portion of mud patch is located in the southwestern part of the area. According to the textural parameters analysis, sediments in the study area are poorly sorted(av.2.52 ), positive skewed(av.1.61 ), leptokurtic(av.1.74 ), transported by saltation and/or suspension, and roundness of quartz is varied from angular to surrounded, which suggesting that the depositional environment is not simple. The calcium carbonate content is on the average 26.99%, and commonly abundant in sand-size sediments, whereas organic matter content in the bulk sediment is on the average 6.70% and usually dominant in fine-grained sediments.Light minerals consist of quartz(av56.01%),Na-Ca feldspar(av.6.15%),K-feldspar(av.9.22%) and rock fragments(av28.11%).The contect onquartz and K-feldspar increases continuously away from the Cheju Island. As a result of geochemical analysis,concentrations of the elements are as follow:Zn:19.42-43.52 ppm (av.30.67ppm),Mn:50-304 ppm(av139.39ppm),Cr:3.54-10.68ppm(av6.50ppm),Pb:5.52-41.68ppm(av.15.60ppm), Co:7.08-14.68ppm (av.10.78ppm),Ni:19.70-42.42ppm(av.29.57ppm),Cu:3.14-9.12ppm(av.5.14ppm),Fe:0.48-2.08% (av1.22%),Ca:0.32-13.16%(av6.60%),Al:0.06-0.08%(av.0.27%),Mg:0.12-0.76%(av.0.53%)na:0.11-0.51%(av.0.36%) Ag:0.48-4.08ppm(av.1.22ppm).Among these elements,the content of Zn,Cu,Cr,Mn,Fe,Al,Mg,Pb and Na increase toward the southwestern area,while the content of Ca and Ag SHOWS the reversed distribution trend.Such a distribution pattern seems to imply that spatial distrivution of heavy metals is closely related to the variation in grain size. X-ray diffractogram show that the minerals in clay from the southwestern mud patch are illite ,chlorite, kaolinte,feldspar and calcite.The bulk of illite in th mud zone is believed to be originated from Huanghe and Yangytze River.The mud patch in this region contains the diagnostic calcite peak,and the concentration of Ca,ni,Pb,Ag are similar to Huanghe type,which indicates that the greater part of these clay fractions may have been derived from the Huanghe River.

• Korean Journal of Breeding Science
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• v.42 no.2
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• pp.169-180
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• 2010

This study was conducted to investigate characteristics of panicle traits which are important factors affecting yield and grain quality of rice. Twelve panicle traits in 178 Korean rice varieties composed of 160 Japonica type varieties and 18 Tongil type varieties were investigated. Tongil type varieties had longer panicle and thicker neck node than Japonica type varieties. Other traits such as number of total spikelets, total rachis-branches, secondary rachis-branches (SRBs) per panicle, total spikelets on SRBs per panicle, mean number of spikelets on a SRB, and mean number of SRBs per primary rachis branch (PRB) in Tongil type varieties were also higher than in Japonica type varieties. On the other hand, Japonica type varieties were shown to have well exserted panicle and little more mean number of spikelets on a PRB than Tongil type varieties. According to cluster analysis based on 12 panicle traits, 178 varieties were divided into four main groups. Group I had 133 Japonica type varieties and was characterized by relatively well exserted short panicle, small thickness of neck node, few rachis-branches and little sink size than other group. Group II was composed of 24 Japonica type varieties and 6 Tongil type varieties showing medium value and range between Group I and III. Group III included 11 Tongil type varieties and 1 Japonica type variety 'Baegjinju1' characterized by relatively poor exserted long panicle, big thickness of neck node, many rachis-branches and large sink size. Group IV was solely composed of 'Nongan', which had well exserted long panicle, big thickness of neck node, many rachis-branches and large-sink size. In correlation analysis, number of total spikelets per panicle showed very high correlation with the number of total rachis-branches per panicle (r=0.975), number of spikelets on SRBs per panicle (0.962), number of SRBs per panicle (0.959), mean number of SRBs per PRB (0.746) and mean number of spikelets on SRBs (0.738).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.239-240
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• 2008

As semiconductor devices are scaled down for better performance and more functionality, the Cu-based interconnects suffer from the increase of the resistivity of the Cu wires. The resistivity increase, which is attributed to the electron scattering from grain boundaries and interfaces, needs to be addressed in order to further scale down semiconductor devices [1]. The increase in the resistivity of the interconnect can be alleviated by increasing the grain size of electroplating (EP)-Cu or by modifying the Cu surface [1]. Another possible solution is to maximize the portion of the EP-Cu volume in the vias or damascene structures with the conformal diffusion barrier and seed layer by optimizing their deposition processes during Cu interconnect fabrication, which are currently ionized physical vapor deposition (IPVD)-based Ta/TaN bilayer and IPVD-Cu, respectively. The use of in-situ etching, during IPVD of the barrier or the seed layer, has been effective in enlarging the trench volume where the Cu is filled, resulting in improved reliability and performance of the Cu-based interconnect. However, the application of IPVD technology is expected to be limited eventually because of poor sidewall step coverage and the narrow top part of the damascene structures. Recently, Ru has been suggested as a diffusion barrier that is compatible with the direct plating of Cu [2-3]. A single-layer diffusion barrier for the direct plating of Cu is desirable to optimize the resistance of the Cu interconnects because it eliminates the Cu-seed layer. However, previous studies have shown that the Ru by itself is not a suitable diffusion barrier for Cu metallization [4-6]. Thus, the diffusion barrier performance of the Ru film should be improved in order for it to be successfully incorporated as a seed layer/barrier layer for the direct plating of Cu. The improvement of its barrier performance, by modifying the Ru microstructure from columnar to amorphous (by incorporating the N into Ru during PVD), has been previously reported [7]. Another approach for improving the barrier performance of the Ru film is to use Ru as a just seed layer and combine it with superior materials to function as a diffusion barrier against the Cu. A RulTaN bilayer prepared by PVD has recently been suggested as a seed layer/diffusion barrier for Cu. This bilayer was stable between the Cu and Si after annealing at $700^{\circ}C$ for I min [8]. Although these reports dealt with the possible applications of Ru for Cu metallization, cases where the Ru film was prepared by atomic layer deposition (ALD) have not been identified. These are important because of ALD's excellent conformality. In this study, a bilayer diffusion barrier of Ru/TaCN prepared by ALD was investigated. As the addition of the third element into the transition metal nitride disrupts the crystal lattice and leads to the formation of a stable ternary amorphous material, as indicated by Nicolet [9], ALD-TaCN is expected to improve the diffusion barrier performance of the ALD-Ru against Cu. Ru was deposited by a sequential supply of bis(ethylcyclopentadienyl)ruthenium [Ru$(EtCp)_2$] and $NH_3$plasma and TaCN by a sequential supply of $(NEt_2)_3Ta=Nbu^t$ (tert-butylimido-trisdiethylamido-tantalum, TBTDET) and $H_2$ plasma. Sheet resistance measurements, X-ray diffractometry (XRD), and Auger electron spectroscopy (AES) analysis showed that the bilayer diffusion barriers of ALD-Ru (12 nm)/ALD-TaCN (2 nm) and ALD-Ru (4nm)/ALD-TaCN (2 nm) prevented the Cu diffusion up to annealing temperatures of 600 and $550^{\circ}C$ for 30 min, respectively. This is found to be due to the excellent diffusion barrier performance of the ALD-TaCN film against the Cu, due to it having an amorphous structure. A 5-nm-thick ALD-TaCN film was even stable up to annealing at $650^{\circ}C$ between Cu and Si. Transmission electron microscopy (TEM) investigation combined with energy dispersive spectroscopy (EDS) analysis revealed that the ALD-Ru/ALD-TaCN diffusion barrier failed by the Cu diffusion through the bilayer into the Si substrate. This is due to the ALD-TaCN interlayer preventing the interfacial reaction between the Ru and Si.

• Journal of the Korean earth science society
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• v.41 no.6
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• pp.588-598
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• 2020

The seafloor geology of Ieodo, a submerged volcanic island, has been poorly understood, although this place has gained considerable attention for ocean and climate studies. The main purpose of the study is to understand and elucidate types, distribution patterns and provenance of the surficial sediments in and around the Ieodo area. For this purpose, 25 seafloor sediments were collected using a box-corer, these having been analyzed for grain sizes. XRD (X-ray Diffraction) analysis of fine-grained sediments was conducted for characterizing clay minerals. The peak of Ieodo exists in the northern region, while in the southern area, shore platforms occur. The extensive platform in the south results from severe erosion by strong waves. However, the northern peak still survived from differential weathering. Grain size analyses indicated that gravels and gravelly sands with skeletons and shells were distributed predominantly on the volcanic apron and shore platform. Muddy sediments were found along the Ieodo and the adjacent deeper seafloor. Based on the analysis of clay mineral composition, illites were the most abundant in fine muds, followed by chlorites and kaolinites. The ratio plots of clay minerals for the provenance discrimination suggested that the Ieodo muds were likely to be derived from the Yangtze River (Changjiang River). As a consequence, gravels and gravelly sands with bioclastics may be supplied from the Ieodo volcanic apron by erosion processes. Wave activities might play a major role in transportation and sedimentation. In contrast, fine muds were assumed to be derived from the inflow of the Yangtze River, particularly in summer. Deposition in the Ieodo area is, therefore, probably controlled by the inflow from the Changjiang Dilute Water and summer typhoons from the south.