• 보존과학회지
• /
• 제38권1호
• /
• pp.1-13
• /
• 2022

Colour consistency is an important consideration when selecting pigments used on works of art. In this study, we analyse the colour difference between two sets of synthetic blue glass pigments acquired at least 8 years apart from the same manufacturer in Japan. The old pigment set (unused, dry powder with four different grain sizes) appears faded compared to the new set. These pigments are made available for artistic use, commonly in Nihonga or Japanese paintings. Raman spectroscopy and SEM-EDS results characterize these pigments as cobalt aluminate spinels dissolved in leaded glaze, a special class of complex coloured inorganic pigments that is not well-understood in the field of conservation. Colour difference between the old and new pigments with four different grain sizes were quantified by analysing photomicrographs with image analysis software. Blue pigments with coarse and extremely fine grains showed significant colour change compared to pigments with medium and fine grain sizes. The high occurrence of crystallites in the finer grains give a final colour that is bluer and lighter. Possible causes for the colour difference including manufacturing methods and storage environment are discussed.

• 한국공작기계학회논문집
• /
• 제12권4호
• /
• pp.9-16
• /
• 2003

In this study, the decision of dressing time for diamond wheel was analyzed by observing with acoustic emission signals and surface roughness, and also obtained the machining characteristics by weibull distribution plot for the values of bending strength. From the experimental study, it was possible to predict the time of re-dressing for the diamond grinding wheel with the analysis of acoustic emission signals and surface roughness values, and following conclusions were obtained. The root-mem-square values of acoustic emission signals were obtained low as the increased of table speed for different abrasive grain size. This is caused by the lack of grinding power which is not able to get rid of all real grinding mass of depth as the table speed is increased. The values of bending strength for ground $Si_3 N_4$ specimens were decreased for gain size of #400 than that of #60, but it was found that the surface roughness values for gain size of #60 were better than that of #400. As compared the shape parameter of weibull distribution plot for the values of bending strength, it was found that the reliability of bending strength for grain size of #60 increased than that of #400.

• Composites Research
• /
• 제32권3호
• /
• pp.141-147
• /
• 2019

In this study, micro-sized and nano-sized pure aluminum (Al) powders were compressed by unidirectional pressure at room temperature. Although neither type of Al bulk was heated, they had a high relative density and improved mechanical properties. The microstructural analysis showed a difference in the process of densification according to particle size, and the mechanical properties were measured by the Vickers hardness test and the nano indentation test. The Vickers hardness of micro Al and nano Al fabricated in this study was five to eight times that of ordinary Al. The grain refinement effect was considered to be one of the strengthening factors, and the Hall-Petch equation was introduced to analyze the improved hardness caused by grain size reduction. In addition, the effect of particle size and dispersion of aluminum oxide in the bulk were additionally considered. Based on these results, the present study facilitates the examination of the effect of particle size on the mechanical properties of compacted bulk fabricated by the powder metallurgy method and suggests the possible way to improve the mechanical properties of nano-crystalline powders.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1999년도 하계학술대회 논문집 D
• /
• pp.1864-1866
• /
• 1999

The magnetic nondestructive test can be applied to evaluate the magnetic material characteristics and the fracture properties through the internal defects of SA-508 used in the pressure vessels of the nuclear power plants as the direct and accurate in-situ testing methods. The fracture toughness, yield strength and the stress distribution around the defects in the surface and sub-surface of magnetic materials can be directly estimated by Bark-hausen noise(BN) methods as NDT. The testing process of SA-508 by Barkhausen noise method was advanced by controlling the austenizing peak temperature and the time of maintenance at a constant austenizing peak temperature, therefore causing the variation of fracture toughness. Through above process. we can evaluate the variations of effective grain size and the correlation of effective grain size and FATT at each situation. And the stress distribution around the defects can be quantified nondestructively through Barkhausen method.

• 반도체디스플레이기술학회지
• /
• 제14권1호
• /
• pp.67-71
• /
• 2015

Pulse electroplating was studied to form nanocrystal structure effectively by changing plating current density and duty cycle. When both of plating current density and duty cycle were decreased from $100mA/cm^2$ and 70% to $50mA/cm^2$ and 30%, the P content in the Ni matrix was increased almost up to the composition of $Ni_3P$ compound and the grain growth after annealing was retarded as well. The as-plated hardness values ranging from 660 to 753 HV are mainly based on the formation of nanocrystal structure. On the other hand, the post-anneal hardness values ranging from 898 to 1045 HV, which are comparable to the hardness of hard Cr, are coming from how competition worked between the precipitation of $Ni_3P$ and the grain coarsening. According to the ANOVA and regression analysis, the plating current density showed more strong effect on nanocrystal size and film hardness than the duty cycle.

• 한국전기전자재료학회논문지
• /
• 제15권6호
• /
• pp.518-523
• /
• 2002

The influences of ion beam energy and reactive oxygen partial pressure on the physical and crystallographic characteristics of transition metal oxide compound(CrOx) film were studied in this paper. Chromium oxide films were deposited onto a cover-glass using ion Beam Sputter Deposition(IBSD) technique according to the various processing parameters. Crystallinity and grain size of as-deposited films were analyzed using XRD analysis. Thickness and Resistivity of the films were measured by $\alpha$-step and 4-point probe measurement. According to the XRD, XPS and resistivity results, the deposited films were the cermet type films which had crystal structure including amorphous oxide(a-oxide) phase and metal Cr phase simultaneously. The increment of the ion beam energy during the deposition process led to decreasing of metal Cr grain size and the rapid change of resistivity above the critical $O_2$ partial pressure.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2004년도 추계학술대회 논문집
• /
• pp.774-777
• /
• 2004

A rheology casting technology has some advantages compared with conventional forming processes such as die casting, squeeze casting and hot/cold forming. The liquid segregation is important on mechanical properties of materials using rheology casting. In this study, so, molecular dynamics simulations were performed for the control of liquid segregation. Because the dynamics of fluid flow about nano-scaled materials is completely different from continuum, molecular dynamics simulations were used. The behavior of particles was far from the truth according to boundary conditions in simple flow. But various movement of particles appear at two or more molecular simulations.

• 한국재료학회지
• /
• 제16권9호
• /
• pp.578-583
• /
• 2006

We studied the physical properties of Ni-Zn ferrites by adding different chemicals such as $SO_4$, Cl, and $NO_3$. Specimens were prepared by the coprecipitation method and sintered at temperatures $950^{\circ}C,\;1,150^{\circ}C,\;and\;1,350^{\circ}C$, respectively. X-ray diffractions showed a spinel structure and the optical microscopy revealed grain size of 0.3 to 0.6 ${\mu}m$. The optimum sintering temperature to obtain fine, sintered microstructure depended on the additive : Cl and $NO_3\;at\;950^{\circ}C\;and\;SO_4\;at\;1,150^{\circ}C$. According to particle size analysis, higher magnetic permeability and magnetization value were observed with Cl and $NO_3\;than\;SO_4$. As sintering temperature was raised from $950^{\circ}C$ to $1,350^{\circ}C$, the average grain diameter, initial permeability and the magnetic moment also increased.

• 소성∙가공
• /
• 제14권2호
• /
• pp.121-125
• /
• 2005

Electroforming is a process that employs technology similar to that used for electroplating but which is used for manufacturing metallic articles, rather than as a means of producing surface coatings. Electroforming provides a cost-effective means of producing alloys and fully dense nanocrystalline metals as foils, sheets and complex shapes. Fe-Ni nanocrystalline alloy foils with composition in the $36\~80wt\%$ Ni range were fabricated by electroforming. The thickness of electroformed foils was in the range of $5\~30{\mu}m$. TEM and XRD analysis was applied for measuring the grain size. Very fine grain size$(\~10nm)$ was obtained in alloy foils. The yield and tensile strength of electroformed Fe-Ni alloy were 2000-2800 MPa and 2500-3300 MPa respectively. The magnetic permeability at high frequency of electroformed Fe-Ni foil was higher than that of thicker foils.

• Structural Engineering and Mechanics
• /
• 제65권4호
• /
• pp.465-476
• /
• 2018

This article investigates buckling behavior of a multi-phase nanocrystalline nanobeam resting on Winkler-Pasternak foundation in the framework of nonlocal couple stress elasticity and a higher order refined beam model. In this model, the essential measures to describe the real material structure of nanocrystalline nanobeams and the size effects were incorporated. This non-classical nanobeam model contains couple stress effect to capture grains micro-rotations. Moreover, the nonlocal elasticity theory is employed to study the nonlocal and long-range interactions between the particles. The present model can degenerate into the classical model if the nonlocal parameter, and couple stress effects are omitted. Hamilton's principle is employed to derive the governing equations and the related boundary conditions which are solved applying an analytical approach. The buckling loads are compared with those of nonlocal couple stress-based beams. It is showed that buckling loads of a nanocrystalline nanobeam depend on the grain size, grain rotations, porosities, interface, elastic foundation, shear deformation, surface effect, nonlocality and boundary conditions.