• Title/Summary/Keyword: Grain

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Abnormal Grain Growth Behaviors of $BaTiO_3$ Ceramics with Controlling of Particle Size Distributjion of Calcined Powder (하소분체의 입도조절에 따른 $BaTiO_3$ 요업체의 비정상 입성장거동)

  • 이태헌;김정주;김남경;조상희
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.147-154
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    • 1995
  • Abnormal grain growth behavior of BaTiO3 ceramics with controlling of particle size distribution of calcined powder was investigated. The particle size distribution was controlled by changing the calcining temperature or by using of classification and regrinding process. With broadening of the normallized size distribution in calcined powder, it showeda normal grain growth behavior in sintered body due to an increase of volume fraction of seed grain in the calcined powder. It was supposed that the seed grains could easily contact each other for the rapid grain growth during sintering process and resulted in fast switching-over from abnormal to normal grain growth stage.

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Genetic Ana1ysis for Rice Grain Properties Using a Doubled Haploid Population

  • Qin, Yang;Kim, Suk-Man;Sohn, Jae-Keun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.52 no.2
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    • pp.123-128
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    • 2007
  • Demand for high quality rice has always been a major factor in the international rice marketing. In the present study, doubled haploid (DH) population derived from anther culture of a Tongil/japonica hybrid was used for genetic analysis of rice grain quality. The average values of DH lines for grain weight, grain length and the ratio of grain length to width were near the mid-parent value. More than 40% DH lines showed transgressive segregation for grain weight, length, amylose and lipid content, but less than 10% DH lines observed on ratio of length to width and grain thickness were transgressive segregation. Correlation analysis between appearance qualities and physicochemical characters indicated that grain width and grain thickness both significantly and negatively correlated to protein and lipid content. A highly significant negative correlation between protein content and amylose content was observed.

The Piezoelectric Characteristics Depending on the GrainSize of the PT-PZ-PNN Ceramics (압전변압기용 PT-PZ-PNN 세라믹스의 그레인 크기에 따른 압전특성)

  • 박정호;김철수;김성곤;이상렬
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.10
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    • pp.815-820
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    • 2001
  • The piezoelectric properties of the PT-PZ-PNN system ceramics were investigated depending on the variati on of the grain size. The grain size was varied by sintering temperature, and additive. The effect of the grain size on the electrical, dielectric, and piezoelectric properties was studied with respect to the feasibility of the application for the piezoelectric transformer. Grain size increased as the PMW contents increased. The smaller the particle size used, the smaller the grain size obtained. Specimens are densily sintered. Dielectric and piezoelectric properties are not always improved in proportion to the grain sizes. When he particle size are fine and the grain size are increased properly with the optimum additives, the piezoelectric preperties have good values. the specimen sintered at 1200$\^{C}$ with PMW 2 mol% and MnO$\_$2/ 0.5wt% contents exhibited good piezoelectric properties for a piezoelectric transformer.

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A Study on the Saturation of Grain Size in Pb(Zr, Ti)$O_3$ Thin Films (Pb(Zr, Ti)$O_3$ 박막에서 결정립 크기 포화 현상에 관한 연구)

  • 이장식;김찬수;주승기
    • Journal of the Korean Ceramic Society
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    • v.37 no.6
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    • pp.530-536
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    • 2000
  • During the grain growth of the PZT thin films by selective nucleation method using PZT seed, it was found that the grain size was saturated with the annealing temperature. The saturation of grain size was analyzed by the interfacial energy which appeared during the crystallization. The factors affecting the saturation of grain size were found to be the interfacial energy between perovskite phase and pyrochlore phase, and PZT thin film and the bottom Pt electrode. When the ion damage was introduced to the grain-size saturated PZT thin films, further lateral growth was observed. Pt bottom electrode thickness was changed to control the interfacial energy between the PZT thin film and the Pt bottom electrode. When Pt thickness was increased, the grain size was also increased, because the lattice parameter of Pt films was increased with the thickness of the Pt films. The incubation time of nucleation was increased with the amount of the ion damage on the Pt films.

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The Production Technology of Surface Fine Grain Steels by Controlled Rolling and Cooling Technology (제어압연에 의한 표면미세립강의 제조 기술)

  • 신정호;박상덕;이정환;이용희;장병록
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.08a
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    • pp.188-197
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    • 1999
  • Grain refinement of the structural steels was selected as the most effective method to meet improvement of strength and toughness without heat treatment. So, the future research and developing direction of ultra fine grain steels are more and more required to response to the production of eco - materials(environmental consciousness - materials) In this paper, the product of surface fine grain steels by CRCT and Inverse Transformation Method by warm deformation of martensite is carried out in order to improve the production process of Dowel Bar. It is possible to obtain surface ultra fine grain steel, when warm deformation of martensite formed after quenching is carried out from 730$^{\circ}C$ to 800$^{\circ}C$ in the finishing rolling step. The characters of surface with ultra fine grain steel is showing the cementite particles inside the ferrite grain and fine ferrite grain of about 1.2$\mu\textrm{m}$ in size.

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Fabrication of Low Voltage ZnO Varistor by Seed Grain Method (종자 입정을 이용한 저전압용 ZnO 바리스터의 제조)

  • 강을손;성건용;김종희
    • Journal of the Korean Ceramic Society
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    • v.27 no.4
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    • pp.473-480
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    • 1990
  • Low-voltage ZnO-based varistors were made by seed grain method at various sintering conditions. Their microstructure and electrical properties were investigated and comlpared with those of the ZnO varistors made by a conventional method at the same sintering condition. During the sintering process, the added seed ZnO grain rapidly grew to be a gaint grain(above 500$\mu\textrm{m}$) provinding easy current path. Therefore the breakdown voltage was lowered as much as the order of 1/10-1/5 in comparison to that of the varistor made by a conventional method. But the grain size of the giant ZnO was little influenced by sintering condition, so the breakdown voltate was also little influenced. The weight loss was decreased by the addition of the seed grain, because the giant grain decreased the evaporation area. Therefore the nonobmic property of the specimen made by seed grain method was little influencedby sintering condition. In this research the low-voltage varistor made by seed grain method showed the least leakage current when sintered at 1150$^{\circ}C$ for zero hour.

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Estimation of the Effect of Grain Boundary Diffusion on Microstructure Development in Magnetite Bi-crystal under Oxygen Chemical Potential Gradient at 823 K

  • Ueda, Mitsutoshi;Maruyama, Toshio
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.37-42
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    • 2012
  • Mass transport near grain boundary in a magnetite bi-crystal has been estimated at 823 K by finite element method. Mass transport near grain boundary strongly depends on the diffusivities along grain boundary. If grain boundary diffusion has the same oxygen activity dependence as lattice diffusion, there is no mass transport between grains and grain boundary. On the other hand, mass transport between grains and grain boundary is observed in the case that grain boundary diffusion has different oxygen activity dependence.

Analysis of the effect on the whisker growth as grain size of plating and base metal (Plating 및 Base metal의 Grain size에 따른 Whisker 성장 영향 분석)

  • Kim, Su-Jin;Chang, Mi-Soon;Kwack, Kae-Dal
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1337-1342
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    • 2008
  • The whisker grows at the plating of a lead frame so that it causes the serious problem like the short. To prove this case, many people have studied the cause and influence of the tin whisker growth. This study explains the grain size affects the growth of the whisker in the lead frame. By these studies about the whisker, the whisker growth is discovered by stresses generated by the intermetallic compound and CTE mismatch in both plating and base metal. The stresses or lattice defect generated in the plating process changes grain structure of plating. Consequently, these various stresses are stabilized by forming unspecified whiskers through lots of grain boundaries. Because the grain boundary is the path of the whisker growth, the smaller grain size exists, the more whiskers grow.

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Critical currents across grain boundaries in YBCO : The role of grain boundary structure

  • Miller Dean J.;Gray Kenneth E.;Field Michael B.;Kim, Dong-Ho
    • Progress in Superconductivity
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    • v.1 no.1
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    • pp.14-19
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    • 1999
  • Measurements across single grain boundaries in YBCO thin films and bulk bicrystals have been used to demonstrate the influence of grain boundary structure on the critical current carried across the grain boundary. In particular, we show that one role of grain boundary structure is to change the degree of pinning along the boundary, thereby influencing the critical current. This effect can be used to explain the large difference in critical current density across grain boundaries in thin films compared to that for bulk bicrystal. These differences illustrate the distinction between the intrinsic mechanism of coupling across the grain boundary that determines the maximum possible critical current across a boundary and the measured critical current which is limited by dissipation due to the motion of vortices.

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Preparation of Ceria-stabilized Zirconia Ceramics with Irregular Grain Shape (불규칙 입자형상을 갖는 세리아 안정화 지르코니아 세라믹스의 제조)

  • 강현희;이종국
    • Journal of the Korean Ceramic Society
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    • v.36 no.4
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    • pp.372-379
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    • 1999
  • Hihg-toughened ceria-stabilized tetragonal zirconia ceramics with irregular grain shape and undulated grain boundary was prepared by ceria doping. Irregularity of grain shapes was increased with the amount of doped ceria. But in case of the large amount of doped ceria grain boundary was migrated to the reverse direction of DIGM. Ceria-stabilized zirconia ceramics annealed at 1650$^{\circ}C$ for 2h after twice dippings into cerium nitrate solu-tion of 0.2M and sintering at 1500$^{\circ}C$ for 2h showed the highest grain boundary length with a value of 23.6$\mu\textrm{m}$ Ceria concentration difference between convex and concave sides in irregular grains was observed over 1 mol% but not observed in normal grains, Specimens with normal grain shape showed intergranular fracture mode whereas the specimens with irregular grain shape showed transgranular fracture mode.

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