• Title/Summary/Keyword: Gr/Ep

Search Result 13, Processing Time 0.015 seconds

Al-Fe Partitioning between Coexisting Garnet and Epidote from Metamorphic Rocks

  • Kim, Hyung-Shik;Kim, Young-Kyum;Jang, Young-Nam
    • The Journal of the Petrological Society of Korea
    • /
    • v.2 no.2
    • /
    • pp.63-73
    • /
    • 1993
  • The assemblage epidote and grandite garnet occurs in low-to medium-grade metabasites and calc schists of various geotectonic settings and in hydrothermally altered calcareous rocks in skarn deposits. The compositions of sixteen epidote-garnet paris have been analysed by means of electron microprobe. Al-Fe partitioning between coexisting grandite garnet and epidote is considered and measured at the grain boundaries on the supposition that the surface equilibrium was maintained in the following exchange reaction: 2$Ca_2Al_3Si_3O_12$(OH)+$Ca_3Fe_2Si_3O_12$=2$Ca_2A_l2FeSi_3O_12$(OH)+$Ca_3Al_2Si_3O_12$ Partition coefficients confirms the differences in thermal conditions between low-grade and medium-grade metamorphic rocks. $K_D$ values ($X_{$CO_2$}$=($Fe^{+3}$/Al)$^{Ep}$/($Fe^{+3}$/Al)$^{Gr}$, where Fe=$Fe^{+3}$) from greenschist facies rocks of the estimated metamorphic temperatures, 330~$390^{\circ}C$, range approximately between 0.02 and 0.17. Epidote-amphibolite facies rocks and calcareous skarns of the estimated temperatures, 400~$550^{\circ}C$, have $K_D$ values between 0.24 and 0.37. $K_D$ values from the rocks of the temperatures, 640~$700^{\circ}C$, range nearly between 0.58 and 0.75. The diagrams in Figs. 2 and 3 can serve as a mineralogic thermometer for relatively shallow rocks, assuming that the pressure dependence of partition coefficients for the iron-exchange reaction in the two minerals can be neglected.

  • PDF

Papers : Simultaneous Monitoring of Strain and Temperature During and After Cure of Unsymmetric Cross - ply Composite Laminate Using Fiber Optic Sensors (논문 : 비대칭 직교적층 복합재료 적층판의 성형시 및 성형후 광섬유 센서를 이용한 변형률 및 온도의 동시 모니터링)

  • Gang,Hyeon-Gyu;Gang,Dong-Hun;Hong,Chang-Seon;Kim,Cheon-Gon
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.30 no.1
    • /
    • pp.49-55
    • /
    • 2002
  • In this paper, we present the simulation monitoring of strain and temperature during and after the cure of unsymmetric composite laminate using fiber optic sensors. Fiber Bragg grating/extrinsic Fabry-Perot interferometric (FBG/EFPI) hybrid sensors are used to measure those measurands. The characteristic matrix of the sensor is analytically derived and measurements can be done without sensor calibration. A wavelength-swept fiber laser is utilised as a lighr source. Two FBG/EFPI sensors are embedded in a graphite/epoxy unsymmetric cross-ply composite laminate in different directions and different locations. We perform a real time monitoring of fabrication strains and temperatures at two points of the composite laminate during cure process in an autoclave. Also, the thermal strains and temperatures of the fabricated laminate are measured in a thermal chamber. Through these experiments, we can provide a basis for the efficient smart processing of composite and know the thermal behavior of unsymmetric cross-ply composite laminate.

석류석과 녹염석간의 철-알루미늄 교환에 관한 실험암석학적 연구

  • 김형식;김진섭;김기영;이설경;신의철;권용완
    • The Journal of the Petrological Society of Korea
    • /
    • v.3 no.3
    • /
    • pp.185-195
    • /
    • 1994
  • An experimental study of iron-aluminium partitioning between synthetic garnet and synthetic epidote was carried out, as equilibrium was maintained in the exchange reaction expressed as follows : $Ca_3Fe_2Si_3O_12\+\2\Ca_2Al_2AlSi_3O_12$(0H) = $Ca_3Al_2Si_3O_12\+\Ca_2Al_2FeSi_3O_12$(0H) Temperature has a pronounced effect on the distribution of Fe and A1 between the minerals. However, the pressure effect is not so drastic as in the exchange reaction. With increasing temperature, $Fe^{+3}$ becomes redistributed from garnet into epidote, whereas A1 becomes redistributed from epidote into garnet. This is in line with the general principle of phase correspondence, as the temperature increases the more electropositive metal aluminium redistributes from epidote into garnet. The agreement between the experimental results of this study and the natural samples suggests that $K_D=X^{Ep}_{Fe}/X^{Gr}_{Fe}$ may be a useful geothermometer for metamorphic rocks containing garnet and epidote that are close to binary Fe-A1 compounds.

  • PDF