• 제목/요약/키워드: Global synthesis

검색결과 201건 처리시간 0.031초

STATUS AND PROSPECTS OF RESOLUTION OF THE VAPOUR EXPLOSION ISSUE IN LIGHT WATER REACTORS

  • Magallon, Daniel
    • Nuclear Engineering and Technology
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    • 제41권5호
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    • pp.603-616
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    • 2009
  • The past two decades were mainly devoted to model validation and computer code verification against global corium experiments, code application to reactor situations, and investigation of the role of melt properties in steam explosion energetics. Corium data were essentially provided by JRC-Ispra in the FARO and KROTOS facilities and by KAERI in the TROI facility. Verification of code applicability to reactor situations was performed essentially in the frame of the international OECD/SERENA programme. The paper makes a synthesis of the findings made during the above-mentioned period and expresses a personal view of the author with respect to the progress made and expected for the resolution of the steam explosion issue for light water reactors.

Rhodium-Catalyzed Reductive Decyanation of Nitriles Using Hydrosilane as a Reducing Agent: Scope, Mechanism and Synthetic Application

  • Tobisu, Mamoru;Nakamura, Ryo;Kita, Yusuke;Chatani, Naoto
    • Bulletin of the Korean Chemical Society
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    • 제31권3호
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    • pp.582-587
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    • 2010
  • A rhodium-catalyzed reductive cleavage reaction of carbon-cyano bonds is developed using hydrosilane as a mild reducing agent. A wide range of nitriles, including aryl, benzyl, and $\beta$-hydrogen containing alkyl cyanides are applicable to this decyanation reaction. The method is also applicable to organic synthesis, in which benzyl cyanide is used as a benzyl anion equivalent and a cyano group functions as a removable ortho-directing group.

Synthesis and comparison of pure TiO2 and metal/non-metal doped TiO2 as a photocatalyst

  • Moon, Jiyeon;Lee, Kyusang;Kim, Seonmin
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.370.1-370.1
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    • 2016
  • Volatile organic compounds (VOCs) are considered hazardous air pollutants and these are emitted from building materials and household products. VOCs can cause global warming as well as human sickness, and even cancer. Photocatalysis provides a way of converting VOCs into harmless materials. Various researches have shown that $TiO_2$ is the most efficient photocatalysts due to its excellent activity. In this study, metal/non-metal doped $TiO_2$ particles are synthesized for the enhancement of the photocatalytic properties of pure $TiO_2$. By metal/non-metal doping, band gap energies of prepared samples were analyzed by UV/Visible spectrophotometer. The physical and chemical properties of synthesized powder were characterized by field emission scanning electron microscope, by BET for measuring their specific surface area, and by XRD for phase identification and particle size determination. Degradation ability for p-xylene was evaluated through monitoring the concentration in a closed chamber. Relation between their properties and decomposition abilities for VOC were evaluated based on the experimental results.

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컬러재현을 위한 CMAC의 뉴로퍼지 설계 (CMAC Neuro-Fuzzy Design for Color Calibration)

  • 이철희;변오성;문성룡;임기영
    • 한국지능시스템학회논문지
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    • 제11권4호
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    • pp.331-335
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    • 2001
  • CMAC 모델은 인간의 소뇌의 처리 특성을 규정하기 위해 Albus[6]에 의해 제안되었다. 역전파에서 사용된 전역 가중 개선계획을 대신하기 위해, CMAC는 지역 가중 개선 계획을 사용한다. 그래서, CMAC는 빠른 학습과 높은 수렴률의 장점을 가지고 있다. 본 논문에서 컬러 영상에서 CMAC에 의해서 컬러 측정을 실험하고 그리고 높은 레벨 합성 기반인 VHDL로 설계하였다.

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Flame Synthesis of Silica-Coated Iron Oxide Nanoparticles and Their Characterization

  • Jun, Kimin;Yang, Sangsun;Lee, Jeonghoon;Pikhitsa, Peter V.;Choi, Mansoo
    • 한국입자에어로졸학회지
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    • 제9권4호
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    • pp.209-219
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    • 2013
  • We have used the modified diffusion flame burner to synthesize silica coated iron oxide nanoparticles having enhanced superparamagnetic property. Silica-encapsulated iron oxide particles were directly observed using a high resolution transmission electron microscope. From the energy dispersive X-ray spectroscopy (EDS) and zeta potential measurements, the iron oxide particles were found to be completely covered by a silica coating layer. X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) measurements revealed that the iron oxide core consists of ${\gamma}-Fe_2O_3$ rather than ${\alpha}-Fe_2O_3$. Our magnetization measurements support this conclusion. Biocompatibility test of the silica-coated iron oxide nanoparticles is also conducted using the protein adsorption onto the coated particle.

평판에서 빔 보강재의 결합 위치를 이용한 구조물 변경법 (Structural Dynamics Modification Using Position of Beam Stiffener on Plate)

  • 정의일;박윤식
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2002년도 추계학술대회논문집
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    • pp.599-604
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    • 2002
  • Substructures position is considered as design parameter to obtain optimal structural changes to raise its dynamic characteristics. In conventional SDM (structural dynamics modification) method, the layout of modifying substructures position is first fixed and at that condition the structural optimization is performed by using the substructures size and/or material property as design parameters. But in this paper as a design variable substructures global translational and rotational position is treated. For effective structural modification the eigenvalue sensitivity with respect to that design parameter is derived based on measured frequency response function. The optimal structural modification is calculated by combining eigenvalue sensitivities and eigenvalue reanalysis technique iteratively. Numerical examples are presented to the case of beam stiffener optimization to raise the natural frequency of plate.

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Novel Tools and Techniques of Today and Tomorrow: For Studying Catalysis and Energy Problems

  • Hussain, Zahid
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.127-127
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    • 2013
  • The quest for renewable energy requires us to understand, predict, and ultimately control matter and energy at the electronic, atomic, and molecular levels. The ever-increasing demand to diversify the energy portfolio and to minimize environmental impact while supplying global energy needs, has intensified the urgency for developing alternative energy sources and carriers. Significant research efforts are under way and will continue in a broad range of materials synthesis, use-inspired and fundamental science with the use of light sources such as synchrotron and free electron lasers. Energy-related materials research faces urgent challenges today. We need to go beyond the Edisonian hit and trial approach to more systematic research with the use of advanced tools applicable under realistic in-situ and in-operando conditions capable of exploring electronic and atomic structure of catalysts and energy relevant materials. Through various scientific examples, I will explain the current state-of-the art and future directions in the aforementioned areas of research.

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바이오디젤 구성성분 합성 및 연료특성 분석 (Synthesis of Biodiesel Components and Analysis of Their Fuel Characters)

  • 임영관;정충섭;한관욱;도진우
    • Tribology and Lubricants
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    • 제30권1호
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    • pp.52-58
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    • 2014
  • Because food crops serve as the raw materials for biodiesel, the increasing use of biodiesel as an alternative fuel can lead to adverse effects such as food price inflation and may contribute to global starvation. To solve these problems, efforts are being made to explore various nonedible raw materials for producing biodiesel. Different raw materials impart different fuel characteristics to biodiesel. In this study, we synthesized pure fatty acid methyl ester (FAME), which is a biodiesel component, and then analyzed its fuel properties. The fuel properties of pure FAME would be useful in producing biodiesel from various new raw materials.

H-infinity Discrete Time Fuzzy Controller Design Based on Bilinear Matrix Inequality

  • Chen M.;Feng G.;Zhou S.S.
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • 제6권2호
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    • pp.127-137
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    • 2006
  • This paper presents an $H_{\infty}$ controller synthesis method for discrete time fuzzy dynamic systems based on a piecewise smooth Lyapunov function. The basic idea of the proposed approach is to construct controllers for the fuzzy dynamic systems in such a way that a Piecewise smooth Lyapunov function can be used to establish the global stability with $H_{\infty}$ performance of the resulting closed loop fuzzy control systems. It is shown that the control laws can be obtained by solving a set of Bilinear Matrix Inequalities (BMIs). An example is given to illustrate the application of the proposed method.

향상된 인공생명 알고리듬에 의한 고속, 소폭 저널 베어링의 최적설계 (Optimum Design of High-Speed, Short Journal Bearings by Enhanced Artificial Life Algorithm)

  • 양보석;송진대
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.698-702
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    • 2001
  • This paper presents a combinatorial method to compute the solutions of optimization problem. The present hybrid algorithm is the synthesis of an artificial life algorithm and the random tabu search method. The hybrid algorithm is not only faster than the conventional artificial life algorithm, but also gives a more accurate solution. In addition, this algorithm can find all global optimum solutions. And the enhanced artificial life algorithm is applied to optimum design of high-speed, short journal bearings and the usefuless is verified through this example.

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