• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.1
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• pp.3-10
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• 2019

The purpose of this paper is to find the fire-protection method for keeping on the bond capacity of Near-Surface-Mounted (NSM) FRP under high temperature. Experiments have been carried out to evaluate the bond capacity of NSM FRP by using CFRP-plates and to confirm the heat transfer to the concrete block when the refractory insulation is attached to the surface of NSM FRP. Bond test of NSM FRP under room temperature was conducted to obtain the maximum bond strength. And then a heating tests were carried out with keeping the bond stress of 30% of the maximum bond strength. As a result, the bond capacity of NSM FRP was disappeared when the temperature at epoxy reached to its glass transition temperature (GTT). In order to secure the bond capacity of the NSM FRP, it is necessary to protect the front as well as side by using insulation materials.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.33 no.12
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• pp.19-27
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• 2017

This paper is a study to improve the fire-resistance capacity of reinforced concrete (RC) members strengthened by fiber-reinforced-polymer (FRP). The fire resistance of the RC members strengthened by FRP was evaluated through high temperature exposure test. In order to improve the fire resistance of the FRP reinforcing method, a fire-proof board was attached to the reinforced FRP surface and then the high temperature exposure test was carried out to evaluate the improvement of the fire resistance performance. It was confirmed that the resistance to high temperature of NSMR could be improved somewhat compared with that of EBR from the experiment that exposed to high temperature under the load corresponding to 40% of nominal strength. When 30 mm thick fire-resistance (FR) board is attached to the FRP surface, the surface of the reinforced FRP does not reach $65^{\circ}C$, which is the glass transition temperature (GTT) of the epoxy until the external temperature reaches $480^{\circ}C$. In particular, when a high performance fire-proof mortar was first applied prior to FR board attachment, the FRP portion did not reach the epoxy glass transition temperature until the external temperature reached $600^{\circ}C$.

• Journal of the Korean Electrochemical Society
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• v.24 no.3
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• pp.52-64
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• 2021

The effect of Fe and BO₃ doping on structure, thermal, and electrical properties of Li_1+xFe_xTi_2-x(PO₄)_3-y(BO₃)_y (x = 0.2, 0.5)-based glass and glass ceramics was investigated. In addition, their crystallization behavior during sintering and ionic conductivity were also investigated in terms of sintering temperature. FT-IR and XPS results indicated that Fe²⁺ and Fe³⁺ ions in Li_1+xFe_xTi_2-x(PO₄)_3-y(BO₃)_y glass worked as a network modifier (FeO₆ octahedra) and also as a network former (FeO₄ tetrahedra). In the case of the glass with low substitution of BO₃, boron formed (PB)O₄ network structure, while boron preferred BO₃ triangles or B₃O₃ boroxol rings with increasing the BO₃ content owing to boic oxide anomaly, which can result in an increased non-bridging oxygen. The glass transition temperature (GTT) and crystallization temperature (CT) was lowered as the BO₃ substitution was increased, while Fe²⁺ lowered the GTT and raised the CT. The ionic conductivity of Li_1+xFe_xTi_2-x(PO₄)_3-y(BO₃)_y glass ceramics were 8.85×10^-4 and 1.38×10^-4S/cm for x = 0.2 and 0.5, respectively. The oxidation state of doped Fe and boric oxide anomaly were due to the enhanced lithium ion conductivity of glass ceramics.