• Elastomers and Composites
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• v.24 no.1
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• pp.11-18
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• 1989

The thermal degradation of Poly(methyl methacrylate) (PMMA) and poly(acrylonitrile butadiene styrene)(ABS) terpolymer as well as their mixtures were carried out using the thermogravimetry and differential scanning calorimetry(DSC) in the stream of nitrogen and air with 50 ml/min at the various heating rate from 4 to $20^{\circ}C/min$ and temperature from 200 to $300^{\circ}C$ The values of activation energies of thermal degradation determined by TG and DSC in the various PMMA/ABS mixtures were $34{\sim}58Kcal/mol,\;35{\sim}54Kcal/mol$ in the stream of nitrogen. The values of activation energy of ABS20% mixture was appeared high in camparison with addition rule. According to increasing the composition of ABS, the temperatures of glass transition and initial decomposition temperature were increased. PMMA/ABS mixtures by the analysis of infrared spectrophotometer were decomposed by main chain scission in the stream of nitrogen.

• Elastomers and Composites
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• v.33 no.1
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• pp.37-43
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• 1998

The permeation of gas through polymer membrane at temperatures above its glass transition, generally occurs by a solution-diffusion mechanism. This mechanism is performed by the affinity difference between polymeric materials and gas molecules, and various technologies, such as copolymerization, impregnation and so on, have been researched to improve the affinity of polymeric material for the gases. In this study, permeability and selectivity for some gases were obtained from steady-state rates of gas permeation through silicone rubber membrane which is prepared by supercritical fluid extraction method. The permeability was measured by the volumetric method proposed by Barrer. Permeability was increased generally with temperature and permeation pressure. Silicone rubber membrane shows a higher permeability to $CO_2$ than to $O_2$, $N_2$. This results probably reflect the relatively high solubility of CO_2 in silicone rubber membrane, which is due to the affinity of $CO_2$ molecules. Since separation powers of $CO_2/N_2$, $CO_2/O_2$ were more than 200, and 100, respectively, it is able to separate $CO_2$ from the air, and the optimum temperature and pres-sure was 328.15 K, 60 cmHg respectively. In future, it is possible that the silicone rubber membrane can be used for separation or concentration of $CO_2$ through experiment for mixed gas separation.

• Journal of Ocean Engineering and Technology
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• v.15 no.2
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• pp.111-119
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• 2001

The application as the parts of an automobile, using the property of GMT-Sheet, is increasing. In order to exchange the parts of an automobile for GMT-Sheet, at first, the establishment and problem of exact joining strength must be determined. We have studied it using composites which is not same each other fiber oriented condition so as to determine joining strength and joining condition of GMT-Sheet. In this study, the result of experiment of forming condition concerned joining problem of GMT-Sheet is this; joining efficiency of GMT-Sheet, increases as lap joint length L increases. Increase of compression ratio causes decrease of joining efficiency after of GMT-Sheet joining. In the viewpoint of recycling, randomly oriented composite of GMT-Sheet is desirable more than unidirectional oriented composite. We has better design the structure so as not to occur to stress centralization on the joining part.

• Journal of the Korean Society of Safety
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• v.26 no.6
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• pp.54-63
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• 2011

Steel plate or FRP materials have been typically used for the seismic retrofit of civil infrastructures. In order to overcome the limitation of each retrofitting material, a composite material, which takes advantages from both metal and fiber polymer materials, has been developed. In the study herein, the composite retrofitting material consists of metal part(steel or aluminum) and FRP sheet part(glass or carbon fiber). The metal part can enhance the ductility and the FRP part the ultimate strength. As a preliminary study to investigate the fundamental mechanical characteristics of the metal-FRP laminated composite material this study performed the tensile test with various experimental variables including the number, the angle and the combination of FRP laminates. From the test results, both aluminum and steel-FRP laminate composite material showed increased fracture toughness. However, the angle and the kind of fibers should be carefully considered in conjunction with the expected loading conditions. In general, steel-FRP laminate composite showed better tensile performance in regards to the seismic retrofit purposes.

• Structural Engineering and Mechanics
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• v.55 no.1
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• pp.191-204
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• 2015

Control of the mechanical behavior of composite materials and structures under monotonic and dynamic loads for cracks and damage is a vast and complex area of research. The modeling of the different physical phenomena and behavior characteristics of a composite material during deformation play an important role in the structural design. Our study aims to analyze numerically the energy release rate parameter G of a composite laminated plate (glass or boron / epoxy) cross-ply [$+{\alpha}$, $-{\alpha}$] in the presence of a crack between two circular notches under the effect of several parameters such as fiber orientation ${\alpha}$, the crack orientation ${\beta}$, the orientation ${\gamma}$ of the two considered circular notches and the effect of mechanical properties. Our results show clearly that both notches orientation has more effect on G than the cracks and fibers orientations.

• Elastomers and Composites
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• v.45 no.3
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• pp.156-164
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• 2010

Thermoplastic elastomers (TPEs) exhibit both elastomeric behaviors at used temperature range and melt processibility. Polyamide based thermoplastic elastomers (TPAEs) are segmented block copolymers with hard blocks consisting of polyamide segments, while the soft blocks usually consist of flexible segments having a low glass transition temperature. The TPAE is one of the engineering TPEs possessing high thermal stability, excellent mechanical performances, chemical resistance and excellent processibility. And they showed wide range of physical and functional properties depending upon the structure of each segment and their relative contents and the hybridization with various inorganic particles. In this review, synthesis, properties, and possible applications of TPAEs are summarized.

• Elastomers and Composites
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• v.48 no.1
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• pp.85-91
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• 2013

In this study, we synthesized a terpolymer consisting of ethylene, 1-hexene, and styrenic monomer using a metallocene catalyst and cocatalyst ststem. The styrenic monomers empolyed as the third monomer were styrene, p-methylstyrene, and 4-tert-butylstyrene. The structure and composition of the terpolymers were characterized using $^{13}C$ NMR and $^1H$ NMR. Catalytic activity, polymer yield, molecular weight and molecular weight distribution of the terpolymers were analyzed. We also determined the glass transition temperature(Tg), crystallinity and thermal properties of the terpolymers by DMA, WAXS and TGA.

• Elastomers and Composites
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• v.45 no.1
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• pp.44-50
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• 2010

The butadiene rubber(BR) blends with chloroprene rubber(CR) were prepared by mechanical mixing method. Cure characteristics, mechanical properties, ozone resistance properties and dynamic mechanical properties were subsequently examined. The properties of ozone resistance of pure BR was significantly improved through blending with 50 wt% CR. Dynamic characteristics determined from a Rheovibron generally showed two glass transition($T_g$) for the entire blends, $tan{\delta}$ peak monotonically shifted toward the higher temperature with the increasing content of CR. Optimum cure time of compound was significantly lengthened with loading of CR.

• Elastomers and Composites
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• v.55 no.2
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• pp.120-127
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• 2020

In this study, molding shrinkage of PPS resin was investigated. Two types of PPS resins with differing glass fiber and calcium carbonate content were used for this purpose. To observe mold shrinkage, molding conditions based on injection temperature, injection speed, and the position of the cushion were selected. Circular and rectangular specimens were used for the study model. Injection molding simulation was performed to predict the filling pattern and mold shrinkage, and the simulation results were compared with the experimental conclusions. It was observed that the mold shrinkage showed the highest shrinkage (distributed from 0.05% to 0.32%) dependence on the injection temperature, and the lowest shrinkage (distributed from 0.05% to 0.31%) dependence on the injection speed. The role of the position of the cushion in mold shrinkage was difficult to observe. The results of the simulation mostly agreed with the experimental results; however, for some molding conditions, the mold shrinkage in the simulation was overestimated as compared to that in the experiment.

• Journal of the Society of Naval Architects of Korea
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• v.52 no.2
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• pp.143-152
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• 2015

In the present study, the fiber and matrix failure of composite laminates under arbitrary biaxial stresses were evaluated based on separate mode criteria such as Hasnin and Puck theories. There is a limitation to predict the fiber-dominant and/or matrix-dominant failures under arbitrary stress states using limit criteria (maximum stress and maximum strain theories) and interactive criteria (Tsai-Hill and Tsai-Wu theories). There is little literature for failure analysis of ships and offshore composite structures considering advanced failure theories such as Hashin and Puck theories. Furthermore, there is not enough practical commercial finite element analysis (FEA) code which is basically adopted the separate mode criteria. Hence, in the present study, the user-defined subroutine of commercial FEA code ABAQUS for evaluation of fiber and matrix failures of composite structures was developed based on Hashin and Puck failure criteria. And then, the proposed subroutine was validated by comparing with a series of experimental results of carbon- and glass-implemented composite laminates to guarantee the reliability and usefulness of the developed method.