• Journal of the Mineralogical Society of Korea
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• 제21권2호
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• pp.161-175
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• 2008

The soil developed from volcanic ash in Jeju Island, Korea, were classified as typical Andisols. The soils had acidic pH, high water contents, high organic matters and clay-silty textures. The crystalline minerals of the samples were mainly composed of ferromagnesian minerals such as olivine and pyroxene, and iron oxides such as magnetite and hematite derived from basaltic materials. A large amount of gibbsite was found at the subsurface horizon as a secondary product from the migration of excessive aluminum. In addition, our study has shown that considerable amounts of poorly ordered minerals like allophane and ferrihydrite were present in Jeju soils. The contents of $SiO_2$ were lower than those of other soil orders, but $A1_2O_3$ and $Fe_2O_3$ contents were higher. These results are some of the important chemical properties of Andisols. The contents of heavy metals were in the range of $84{\sim}198$ for Zn, $56{\sim}414$ for Ni, $38{\sim}150$ for Co, $132{\sim}1164\;mg\;kg^{-1}$ for Cr, which are higher than the worldwide values in most of the soils. Some soil samples contained relatively high levels of Cr exceeding 1000 mg/kg. Mean reduction capacity of the Jeju soils was $6.53\;mg\;L^{-1}$ reduced Cr(VI), 5.1 times higher than that of the non-volcanic ash soils from inland of Korea. The soil reduction capacity of the inland soils had a good correlation with total carbon content (R = 0.90). However, in spite of 20 times higher total carbon contents in the Jeju soils, there was a week negative correlation between the reduction capacity and the carbon content (R = -0.469), suggesting that the reduction capacity of Jeju soils is not mainly controlled by the carbon content and affected by other soil properties. Correlations of the reduction capacity with major elements showed that Al and Fe were closely connected with the reduction capacity in Jeju soil (R = 0.793; R = 0.626 respectively). Moreover, the amounts of Ni, Co and Cr had considerable correlations with the reduction capacity (R = 0.538; R = 0.647; R = 0.468 respectively). In particular, in relation to the behavior of redox-sensitive Cr, the oxidation of the trivalent chromium to mobile and toxic hexavalent chromium can be restricted by the high reduction capacity in Jeju soil. The factors controlling the reduction capacity in Jeju soils may have a close relation with the andic soil properties explained by the presence of considerable allophane and ferrihydrite in the soils.

• Analytical Science and Technology
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• 제20권6호
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• pp.516-523
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• 2007

Purification of silica mineral has been investigated by acid leaching of pulverized silica. A series of studies has been carried out on the effect of leaching silica powder as a function of the leaching time at the constant temperature of $80^{\circ}C$ in oxalic acid, aqua regia, and two mixed acids of HF/HCl, $HF/HNO_3$. The impurities of silica and leachantes were measured by neutron activation analysis (NAA), inductively coupled plasma atomic emission spectrometry (ICP-AES), atomic absorption spectrometry, x-ray fluorescence (XRF) method and wet analysis (WA). Certain metals, such as sodium, calcium, iron, aluminium and titanium, have been found in concentrations of hundreds or even thousands of mg/kg. Comparison of purification processes of silica and analytical methods of impurities in the silica was conducted in this study.

• Geophysics and Geophysical Exploration
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• 제8권2호
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• pp.145-155
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• 2005

A two-dimensional (2-D) interpretation of MT data has been performed for the purpose of fracture detection for geothermal development. Remote stations have been operated in Kyushu, Japan (480 km apart) as well as in Korea (60 km and 165 km apart in 2002 and 2003 data set, respectively). Apparent resistivity and phase curves calculated by remote processing with the Japan remote data showed enough quality for 2-D inversion for the whole frequency range. Remote reference processing with Korea remote reference data also showed quite good continuity in apparent resistivity and phase curves except some noisy frequency bands; around the power frequency, 60 Hz, and around the dead band $10^{-1}Hz\;Hz\;\~1\;Hz$, where the natural EM signal is known to be very weak. Even though the subsurface showed severe three-dimensional (3-D) characteristics in the survey area so that 2-D inversion by itself could not give enough information for deep geological structures, the 2-D inversion for the 5 survey lines showed several common features. The conductive semi-consolidate mudstone layer is dipping from north to south (about 500 m depth on the south and 200 m on the north most part of the survey area). The boundary between the low (L-2) and high (H-2) resistivity anomalies can be thought as a major fault with strike $N15^{\circ}E$, passing through the sites 206, 112 and 414. The shallow (< 1 km) conductive anomalies (L-4) seem to be fracture zones having strike E-W (at site 105) and $N60^{\circ}W$ (at site 434). And there exists a conductive layer in the western and west-southern part of the survey area in the depth below $2\~3\;km$, for which further investigation is to be needed.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.136.2-136.2
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• 2011

In this work, we analyzed correlations between life-cycle greenhouse gas (GHG) emissions and life-cycle cost of energy resources. Energy resources studied in this paper include coal, natural gas, nuclear power, hydropower, geothermal energy, wind power, solar thermal energy, and solar photovoltaic energy, and all of them are used to generate electricity. We calculated the mean values, ranges of maximum minus minimum values, and ranges of 90% confidence interval of life-cycle GHG emissions and life-cycle cost of each energy resource. Based on the values, we plotted them in two dimensional graphs to analyze a relationship and characteristics between GHG emissions and cost. Besides, to analyze the technical maturity, the GHG emissions and the range of minimum and maximum values were compared to each other. For the electric generation, energy resources are largely inverse proportional to the GHG emission and the corresponding cost.

• Proceedings of the Korea Water Resources Association Conference
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• 한국수자원학회 2012년도 학술발표회
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• pp.11-17
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• 2012

The Waikato River is New Zealand's longest River, though relatively small on international scales. It drains the central North Island and has New Zealand's largest lake (Lake Taupo) at its headwaters. The upper reaches have sustained flows fed by large aquifers which are recharged by rainfall events providing relatively constant river flows, whereas the lower reaches respond more directly to rainfall events having more peaky flows after rainfall and extreme low flows during dry periods. Consumptive allocation from the river is relatively low with only about 3% of the mean annual flow being allocated. However, more than seven times the river's flow is allocated for non-consumptive purposes before discharging to the Tasman Sea. The majority of this non-consumptive allocation is for hydro power generation and as cooling water at both thermal and geothermal power stations which produce up to 25% of New Zealand's electricity. The upper half of the river has been heavily modified with the construction of eight dams for power generation. This has resulted in a succession of cascading dams replacing the previously uncontrolled river. The Waikato River also provides drinking water for Auckland City (NZ's largest city) and Hamilton City (NZ's 4th largest city). In recent years there has also been considerable growth in water requirements for pasture irrigation to support the intensification of dairy farming in the catchment. Operators of the power stations are concerned that any further consumptive allocation will further reduce their ability to generate electricity. The Waikato Regional Council, who is charged with managing the river and allocation of water, has recently set new rules for managing the conflicting allocation demands on the Waikato River. This has resulted in an end to further allocation of water where it results in a loss of water for electricity generation from renewable resources (fresh water and geothermal water). The exception to this is the prioritisation of water for municipal supplies ahead of other consumptive uses such as industries and irrigators.

• Economic and Environmental Geology
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• 제39권5호
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• pp.607-613
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• 2006

For the reasonable use of low grade-shallow geothermal energy by Standing Column Well(SCW) system, the basic requirements are depth-wise increase of earth temperature like $2^{\circ}C$ per every 100m depth, sufficient amount of groundwater production being about 10 to 30% of the design flow rate of GSHP with good water quality and moderate temperature, and non-collapsing of borehole wall during reinjection of circulating water into the SCW. A closed loop type-vertical ground heat exchanger(GHEX) with $100{\sim}150m$ deep can supply geothermal energy of 2 to 3 RT but a SCW with $400{\sim}500m$ deep can provide $30{\sim}40RT$ being equivalent to 10 to 15 numbers of GHEX as well requires smaller space. Being considered as an alternative of vertical GHEX, many numbers of SCW have been widely constructed in whole country without any account for site specific hydrogeologic and geothermal characteristics. When those are designed and constructed under the base of insufficient knowledges of hydrgeothermal properties of the relevant specific site as our current situations, a bad reputation will be created and it will hamper a rational utilization of geothermal energy using SCW in the near future. This paper is prepared for providing a guideline of SCW design comportable to our hydrogeothermal system.

• Economic and Environmental Geology
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• 제37권6호
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• pp.585-601
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• 2004

A general study of domestic black sandstone and black shale quarries has not been made. For this reason it is difficult to know how the matter really stands. The objectives of this study are to achieve systematical and scientific study of the distribution, occurrences and rock quality of black sandstone and black shale resources exploited in existing quarries in the Boryeong area. The black sandstone bed survey was made from 54 mine claims on 4 sheets. In the area, 140 black sandstone and 22 black shale quarries were ascertained in 37 mine claims. The general development information data from that existing quarries were collected and synthesized. Among these black sandstone quarries for gravestones, monuments and black shale quarries for inkstone are in operation. Most of the black sandstone quarries were closed throughout the Gaewhari, Suburi, Seongjuri district in the investigated area even though these quarries had played a prominent part in the production of black sandstone. In view of commercial dimension stones, raw materials from black sandstone are classified as corestone and fresh rock body according to the characteristics of their occurrences and shape. Black sandstone beds are characteristically well-jointed and are particularly subdivided into cubic or quadrangular blocks in 3 joint sets. The colors of these black sandstones show medium dark $gray\~grayish$ black judging from the Rock Color Chart. The black sandstone beds which are intercalated in the Amisan, Jogeri, Baegunsa, Seongjuri Formations of the Daedong Supergroup are about $1\~10\;m$ in thickness.

• The Journal of Engineering Geology
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• 제15권3호
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• pp.289-301
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• 2005

Groundwater level drawdown of the first stage resulted from groundwater leakage into tunnel was predicted by an analytical approximation. And numerical modeling was performed to predict the flow rates into tunnel and the groundwater level decline in the vicinity of future proposed tunnel area using a groundwater flow model MODFLOW. Groundwater level of the first stage was predicted to decrease by 15.3 m in analytical approximation. The flow rates in the total length of the future tunnel, when it is excavated, would be approximately $1,870m^3/day$ in numerical model. The model predicts that the groundwater levels in the area around the future tunnel are expected to drop between 5 to 25 m relative to current groundwater levels. Under condition for a $50\%$ tunnel conductance increase, the flow rate was estimated to be $2,518m^3/day$ and the groundwater level drawdown was predicted to be between 5 to 35 m The flow rate and the predicted groundwater level drawdown under a $2,518m^3/day$ tunnel conductance decrease was estimated to be $1,273m^3/day$ and between 2 to 12 m.

• Geophysics and Geophysical Exploration
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• 제9권4호
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• pp.261-270
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• 2006

Two-dimensional (2-D) inversion of magnetotelluric (MT) data for two survey lines having south-north direction from Jeju Island has been carried out. Broad band MT sounding curves with good quality could be gathered by performing audio-frequency magnetotelluric (AMT) survey during the MT survey and by operating the remote reference in Kyushu Island, Japan. Comparison of the 2-D inversion model using MT band only and that using both AMT and MT bands for the field data as well as for the data from numerical 2-D modeling said that high frequency information from AMT survey can be useful for interpreting not only the shallow part but also the deep structures, especially when the formation is resistive. The 2-D inversion models of field data show a thick layer having around 10 ohm-m in the depth of a few hundred meters throughout the survey area, which can be considered as the unconsolidated sedimentary layer. And they also show a conductive anomaly at the central part of each survey lines. It can be either the effect of the surrounding sea water, or the structures due to ancient volcanic events. But unfortunately by now, we do not have any further information about the anomaly.

• Geophysics and Geophysical Exploration
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• 제10권4호
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• pp.361-368
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• 2007

In this paper, we suggested the relationship between resistivity of coastal groundwater and NaCl equivalent salinity for the quantitative interpretation the results of surface/borehole resistivity and electromagnetic data. 38 groundwater samples having electrical conductivity higher than about 1,000 ${\mu}S/cm$ were analyzed to derive the empirical relationship between groundwater resistivity and NaCl equivalent salinity. We used Schlumberger chart GEN-8 to convert ion concentration from hydrochemical analysis to the equivalent NaCl salinity, and the portable meter to measure the in situ electrical conductivity of groundwater samples. From the hydrochemical analysis, relationship between the groundwater resistivity $(R_w)$ and equivalent NaCl salinity (Eq_NaCl) is expressed as Eq_NaCl=$5935.3551{\times}R_w^{-1.0993}$, and relationship between the groundwater electrical conductivity (EC) and total dissolved solids (TDS) is expressed as TDS=0.721*EC. We believe these relationships are very useful to assess the seawater intrusion in western and southern coastal area.