• 제목/요약/키워드: GeO

검색결과 404건 처리시간 0.031초

$LaGaO_3$:$Eu^{3+}$형광체의 합성 및 발광 특성 (Synthesis and Anaiysis of Photohnninescence Properties of $^5D_1$$^7F_1$ Transition in $LaGaO_3$:$Eu^{3+}$ Red Phosphor)

  • 김경화;최윤영;손기선;김창해;박희동;최세영
    • 대한화학회지
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    • 제44권5호
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    • pp.453-459
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    • 2000
  • 최근 정보 표시 소자로 전계 방출 표시 소자(FED),PDP.LCD 등이 주목받고 있다. 음극선 발광 형광체는 FED뿐만 아니라 형광 표시판(VFD) 등이 중요한 핵심 소자이다. 따라서 본 연구에서는 FED에 응용 가능한 새로운 모체 탐색을 시도하였고 $LaGaO_3$모체에 $Eu^{3+}$를 첨가한 적색 형광체를 합성하여 광 특성을 분석하였다. $Eu^{3+}$의 농도에 따른 발광 스펙트럼, 여기 스펙트럼과 잔광 시간 곡선을 통해 $LaGaO_3$: $Eu^{3+}$의PL거동을 규명하였다. 잘 알려진 $Eu^{3+}$ 캐스캐이딩(cascading)과 다중 음향 양자(multiphonon emisson)에 의한 cross-relaxation은 $LaGaO_3$: $Eu^{3+}$ 형광체에서도 확인되었다. 또한, Inokutti-Hirayama식으로 부터 결정된 $Eu^{3+}$ 사이의 다중극자 상호 작용(multipolar interaction)유형은 이중 극자 상호 작용(dipole-dipole interaction)으로 밝혀졌다. 본 연구를 통해 $^5D_0$ 전이의 직접 소광 기구(direct quenching mechanism)를 새롭게 제안하였다. 소광 유형은 농도에 의존하며, 0.2몰 이하에서는 확산 율속 단계에 의한 소광 현상이 우세하다가 0.3몰 이상 부터는 $^5D_0$에서 전하 이동 띠(Charge Transfer Band,CTB)로 전이되는 직접 소광 유형이 지배적이다. 음극선 거동은 800V의 가속 전압하에서 여기시켜 측정하였고, PL거동과 같이 0.125몰일때 가장 큰 615nm의 발광 휘도를 나타내었다.

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나치언어의 구조 (Zur Sruktur der Nazisprache)

  • 김종영
    • 한국독어학회지:독어학
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    • 제8집
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    • pp.223-245
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    • 2003
  • In dieser Arbeit wird der Versuch unternommen, die Struktur der Nazisprache zu analysieren. Nazisprache hat die Aufgabe, die Ideologie des Nationalsozialisrnus zu rechtfertigen und zu starken. Um diese Aufgabe zu realisieren, haben sich die Nationalsozialisten viel bemuht Im zweiten Abschnitt wird die Charakteristk dieser Sprache $erw\"{a}hnt$ Hier handelt es sich urn den Hintergrund der Nazisprache und Sprachlenkung im Nationalsozialismus. Im Abschnitt drei wird die syntaktische Struktur der Nazisprache beschrieben. Syntaktisch betrachtet, kann man in der Nazisprache $a\"{u}ffallende$ Struktur feststellen, und zwar eine hohe Frequenz von Adjektiv- Attributen, Adverbiale und Superlative. Bei den Adjektivattributen $la{\ss}t$ sich eine Reihe interessanter Entwicklungen beobachten. In vielen $F\"{a}llen$ tendieren die Attributionen zur idiomatischen Verfestigung. Im Bereich des Adverbs finden $auff\"{a}llige$ Verschiebung statt Adverbien $geh\"{o}ren$ zu den wichtigsten Mitteln, um die Haltung des Sprechers $gegen\"{u}ber$ einem $ge\"{a}u{\ss}erten$ Sachverhalt auf die situativen Bedingungen, insbesondere auf die Haltung und Erwartungen der Adressanten, abzustimmen. Und $auff\"{a}lig$ ist die $H\"{a}ufungwie$ beispie!sweise am von Superlativen auf engern Raum. Durch den inflationaren Gebrauch der superlativischen $Ausdr\"{u}cke$ verlieren im $Bewu{\ss}tsein$ des nationalsozialistischen Redners $allm\"{a}hlich$ ihre $F\"{a}higkeit$, den qualitativen Extremwert eines Sachverhalts zu bezeichnen. Deshalb grief vor allem Hitler schon fruh zu starkeren Mitteln, indem er die Gradative des genannten Typs in den Superlativ setzt. Im Abschnitt vier wird die lexikaIische Struktur der Nazisprache beschrieben. Wahrend des Dritten Reiches war die Entwickiung auf den Wortschatz in lexikalischen Bereichen erheblich, wie beispielsweise am Gebrauch der $Modew\"{o}rter$, die sich auf ideologische, dynamische und $milit\"{a}rische$ Terminologie bezogen sind, am Gebrauch $altert\"{u}mlicher$ $W\"{o}rter$ und am Gebrauch von $Fremdw\"{o}rter$. In der Zeit des Natioalsozialismus bedienten sich die NationaIsoziaIisten neben vieIen $Modew\"{o}Iter$ veralteter $W\"{o}Iter$ zur Kennzeichnung von $\"{A}mtern$ und Einheiten, um dem Regime eine historische $Legitimit\"{a}t$ zu verschaffen. Und sie gebrauchten auch $Fremdw\"{o}rter$ sehr haufig, um ihren Reden einen pseudowissenschaftlichen Anstrich zu geben.

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HCB와 PCBs에 노출된 나일틸라피아, Oreochromis niloticus의 혈액성분의 변화 (Changes of Haematological Constituents in the Nile tilapia, Oreochromis niloticus Exposed to HCB and PCBs)

  • 조규석;민은영;강주찬
    • 한국수산과학회지
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    • 제35권2호
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    • pp.110-114
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    • 2002
  • 유용 양식어류인 틸라피아를 대상으로 어체중당 1일 0.05, 0.25 및 0.50mg/kg의 HCB와 PCBs의 경 구투여에 의해 30일 동안 혈액성상 및 혈액화학적 변동을 조사하였다. HCB의 투여에 의한 틸라피아의 RBC 수는 20일 이후 0.50mg/kg, 30일째는 0.25mg/kg의 농도, hemoglobin 농도와 hematocrit 값은 20일 이후 0.50mg/kg 농도에서 유의한 감소를 나타냈다. PCBs의 투여에 의한 틸라피아의 RBC 수, hemoglobin 농도 및 hematocrit 값은 20일 이후 0.25mg/kg 이상의 농도에서 유의한 감소를 나타냈다. 혈청 무기성분인 calcium, magnesium 및 inorganic phosphorus 농도는 HCB를 투여한 모든 실험에서 뚜렷한 차이가 인정되지 않았다. 또한, PCBs를 투여한 모든 실험에서도 magnesium과 inorganic phosphorus 농도의 변동은 관찰되지 않았으나, calcium 농도는 20일 이후 0.50mg/kg 농도, 30일째는 0.25mg/kg 이상의 농도에서 유의한 감소를 나타냈다 HCB의 경구투여에 의한 혈청 total protein 농도는 30일째 0.50mg/kg 농도에서, PCBs의 경구투여에 의해서는 20일 이후 0.25mgfg 이상의 농도에서 유의하게 감소하였다. HCB 및 PCBs의 경구투여에 의한 glucose 농도는 20일 이후 0.25mg/kg 이상의 농도에서 유의한 증가를 나타냈다. HCB 및 PCBs의 경구 투여에 의한 GOT와 GPT 활성은 20일 이후의 0.50mg/kg에서 유의한 증가를 나타냈다. 결론적으로 HCB 및 PCBs의 경구투여에 의한 틸라피아의 혈액화학적 변동은 0.25 mg/kg 농도 이상에서 적어도 20일 후부터 영향을 받을 것으로 생각된다.

A study of the inorganic element contents for the ginsengs of Keumsan, Chungnam

  • 송석환
    • 고려인삼학회:학술대회논문집
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    • 고려인삼학회 2008년도 춘계 학술대회
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    • pp.74-75
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    • 2008
  • This study is for geochemical relationships between ginsengs and soils from three representative soil types from Keumsan, shale, phyllite and granite. For these study, ginsengs, with the field and weathered soils were collected from the three regions, and are analysed for the major and trace elements. In the weathered soils(avg.), the granite and phyllite areas are high in the most of elements while the shale area is low. In the correlation coefficients, negative correlations are shown in the $Al_2O_3$-MgO pair while positive correlations, are shown in the Ba-Sr, Zr, Sr-Zr and Cs-Ge pairs. In the field soils(avg.), the granite and phyllite areas are, generally, high in the most of elements while the shale area is low. In the shale area, the major elements are high in the 4 year soils, but low in the 2 year soils. The LFS(Ba, Sr, Cs) and transitional elements are high in the 2 year soils, but low in the 4 year soils. The HFS(Y, Zr) is high in the 4 year soils. In the correlation coefficients, most of the elements from the 4 year show positive relationships. Positive correlations are shown in the $Al_2O_3$-CaO, MnO-MgO, V-Tl, and Ba-Sr pairs in all localities. In the ginseng contents, clear chemical differences with the ages are shown in the shale and granite ares, but not clear in the phyllite area. In the shale area Mn, Mg, Ba, Sr, and Y contents, increase with ages but decrease in Al, Cs, Be and Cd. In the correlation coefficients, degrees of the correlations for the major elements become low with the ages. Positive correlations are shown in the Al-Mn, Ti, Mn-Ti, Mg-Ca, Ca-K, Ba-Cs, Y and Cs-Y pairs. Comparisons with ginsengs of the same ages from the different areas suggest that generally, the 2 years in the shale and 3 and 4 years in the granite area are distinctive. Relative ratios(granite/ shale area) of the ginsengs are below 1 in the major elements except Mn in the 2 year ginsengs and above 1 in the other elements except Mg and Na in the 4 year. Relative ratios(granite/ phyllite area) of the ginsengs are high in the 3 year from the phyllite area. In the relative ratios(weathered/field soils) of the soils, numbers of the elements showing the ratios of above 1 increase from the shale, to phyllite and granite in the case of the major elements, but decrease in the case of the trace elements. These results suggest that major elements are high in the granite while trace elements are high in the shale area. In the relative ratios between field soils and ginsengs(field soils/ginseng), the shale area, regardless of the ages, show differences of several hundred times in the $Al_2O_3$, $TiO_2$, Y and Tl, of several ten times in the MnO, MgO and Ba and of several times in the CaO contents. These results suggest that ginseng contents are significantly different from the field soils in the $Al_2O_3$, $TiO_2$, Y and Tl, but similar in the CaO contents. The phyllite area, regardless of the ages, show differences of several hundred times in the $Al_2O_3$, $TiO_2$, Y, Tl and Be, of several ten times in the MnO, MgO, $Na_2O$ and Ba, and of several times to ten times in the CaO, $K_2O$ and Sr contents. These results suggest that ginseng contents are significantly different from those of the field soils in the $Al_2O_3$, $TiO_2$, Y, Tl and Be, but similar in the CaO, $K_2O$ and Sr contents. The granite area, regardless of the ages, show differences of several hundred times in the $Al_2O_3$, $TiO_2$, Tl and Be, of several ten times in the Ba, and of several times to ten times in the MgO and CaO contents. Of the other elements, differences of several times to ten times are shown in the MnO, $K_2O$ and Sr contents. These results suggest that ginseng contents are significantly different from those of the field soils in the $Al_2O_3$, $TiO_2$, Tl and Be, but similar in the $K_2O$ and Sr contents. Comparisons among the different ages from the same area suggest that, in the case of shale area, differences of several hundred times in the $Al_2O_3$ and $TiO_2$, of the several ten times in the MnO, MgO and Ba and several times in the CaO and $K_2O$ are shown in the 2 year ginsengs. Differences of several hundred times in the $Al_2O_3$, $TiO_2$, Cs, Y, Tl and Be, of above several ten times in the MnO, MgO, $K_2O$ and Ba, and of several times in the CaO and Sr are shown in the 3 year ginsengs. Differences of several hundred to thousand times in the $Al_2O_3$, of above several hundred times in the $TiO_2$, Cs and Y, and of several ten times in the MnO, MgO, $K_2O$ and Ba, and of several times in the $Na_2O$ are shown in the 4 year ginsengs. These relationships suggest that, regardless of the localities in the shale area, $Al_2O_3$ contents of the soils show big differences from those of the ginsengs. Regardless of the ages of ginsengs, comparisons with the overall average contents of each area show differences of several hundred times in the $Al_2O_3$, $TiO_2$, Cs and Tl and of several ten times in the MnO. These overall relationships suggest that the $Al_2O_3$, $TiO_2$, Cs and Tl contents of the soils are higher than those of the ginsengs, show big differences between two and low different contents are found in the MnO. In detail, differences of several hundred times in the Y, and ten times in the MgO and Sr, and of several times in the CaO, $Na_2O$, $K_2O$ in the case of shale area, are shown. These results suggest that the soils are higher than the ginsengs in the Y and significantly differences in Y, and moderately differences in the MgO and Sr, and low differences in the CaO, $Na_2O$ and $K_2O$ are shown between soils and ginsengs.

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Cascaded Raman fiber amplifier operating at 1.3.mu.m using WDM couplers

  • Chang, Do-Il;Kong, Hong-Jin;Chernikov, S.V.;Guy, M.-J.;Taylor, J. R.
    • Journal of the Optical Society of Korea
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    • 제1권2호
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    • pp.110-115
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    • 1997
  • We report effcient cascaded Raman generation and signal amplification at 1.3.mu.m achieved in a ring resonator constructed solely from fiber components, i.e. fusion WDM couplers. Low-loss single-mode fiber with moderate $GeO_2$ content (18 mole %) is used as an active medium and pumped by a Nd:YAG laser at 1.064.mu.m. In a resonant cascaded geometry, this generates the third Stokes line at 1.24.mu.m, which acts as a pump for signal wavelength around 1.3.mu.m. A DFB laser operating at 1.315.mu.m is used to provide an input signal. An output signal powers up to 20 dBm (100 mW) with a 28 dB Raman gain are attained, where the Nd:YAG pump power is 3.4 W. It is also shown experimentally that it is important to use optical filters to suppress feedback from the resonator, permitting high Raman gain and good signal quality.

개방형 수식모델링 툴을 이용한 IGCC 플랜트 공정모사 (Process Modeling of IGCC Power Plant using Open-Equation Modeling Framework)

  • 김시문;주용진;김미영;이중원
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.113.1-113.1
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    • 2010
  • IGCC(Integrated Coal Gasification and Combined Cycle) plants can be among the most advanced and environmental systems for electric energy generation from various feed stocks and is becoming more and more popular in new power generation fields. In this work, the performance of IGCC plants employing Shell gasification technology and a GE 7FB gas turbine engine was simulated using IPSEpro open-equation modeling environment for different operating conditions. Performance analyses and comparisons of all operating cases were performed based on the design cases. Discussions were focused on gas composition, syngas production rate and overall performance. The validation of key steady-state performance values calculated from the process models were compared with values from the provided heat and material balances for Shell coal gasification technology. The key values included in the validation included the inlet coal flow rate; the mass flow rate, heating value, and composition of major gas species (CO, H2, CH4, H2O, CO2, H2S, N2, Ar) for the syngas exiting the gasifier island; and the HP and MP steam flows exiting the gasifier island.

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원자 현미경을 이용한 접촉 면적에 따른 마찰 및 마멸 특성 분석 (Effect of Contact Area on Friction and Wear Behavior in Atomic Force Microscope)

  • 최덕현;황운봉
    • 한국정밀공학회지
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    • 제21권12호
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    • pp.167-173
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    • 2004
  • Recently, it has been reported that frictional behavior at nanometer scale can be different from that at macro scale. In this article, friction and wear tests were conducted using an AFM to investigate the effect of real contact area on the coefficient of friction and wear property. SiO$_2$, Hica, and SiGe were used in friction test and the AFM tip was Si$_3$N$_4$. The real contact area between an AFM tip and flat surface was calculated by the Johnson-Kendall-Roberts (JKR) theory. Wear specimen was Mica, and the diamond tip was used. We found that the coefficient of friction is constant below a critical area, but it is degraded over the area. Moreover, it is found that wear depth increased rapidly from a certain load and was degraded as a function of the number of the scanning cycles. Also, the range of scanning velocity used in this study had little effect on the wear depth.

Characterization of Cone Index and Tillage Draft Data to Define Design Parameters for an On-the-go Soil Strength Profile Sensor

  • Chung S. O.;Sudduth Kenneth A.
    • Agricultural and Biosystems Engineering
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    • 제5권1호
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    • pp.10-20
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    • 2004
  • Precision agriculture aims to minimize costs and environmental damage caused by agriculture and to maximize crop yield and profitability, based on information collected at within-field locations. In this process, quantification of soil physical properties, including soil strength, would be useful. To quantify and manage variability in soil strength, there is need for a strength sensor that can take measurements continuously while traveling across the field. In this paper, preliminary analyses were conducted using two datasets available with current technology, (1) cone penetrometer readings collected at different compaction levels and for different soil textures and (2) tillage draft (TD) collected from an entire field. The objective was to provide information useful for design of an on-the-go soil strength profile sensor and for interpretation of sensor test results. Analysis of cone index (CI) profiles led to the selection of a 0.5-m design sensing depth, 10-MPa maximum expected soil strength, and 0.1-MPa sensing resolution. Compaction level, depth, texture, and water content of the soil all affected CI. The effects of these interacting factors on data obtained with the soil strength sensor should be investigated through experiments. Spatial analyses of CI and TD indicated that the on-the-go soil strength sensor should acquire high spatial-resolution, high-frequency ($\ge$ 4 Hz) measurements to capture within-field spatial variability.

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Cl2-Ar 혼합가스를 이용한 GST 박막의 유도결합 플라즈마 식각 (Etching Characteristics of GST Thin Films using Inductively Coupled Plasma of Cl2-Ar Gas Mixtures)

  • 민남기;김만수;;김성일;권광호
    • 한국전기전자재료학회논문지
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    • 제20권10호
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    • pp.846-851
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    • 2007
  • In this work, the etching characteristics of $Ge_2Sb_2Te_5(GST)$ thin films were investigated using an inductively coupled plasma (ICP) of $Cl_2/Ar$ gas mixture. To analyze the etching mechanism, an optical emission spectroscopy (OES) and surface analysis using X-ray photoelectron spectroscopy (XPS) were carried out. The etch rate of the GST films decreased with decreasing Ar fraction. At the same time, high selective etch rate over $SiO_2$ films was obtained and the selectivity over photoresist films decreased with increasing the he fraction. From XPS results, we found that Te halides were formed at the etching surface and Te halides limited the etch rate of the GST films.

부산시 도심지역의 주차행동결정 수량화 모형에 관한 연구 (A Study on the Quantification Model of Parking Behaviors in Pusan C. B. D)

  • 오윤표;김희생
    • 대한교통학회지
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    • 제9권1호
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    • pp.29-46
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    • 1991
  • The purpose of this study is to develop a parking behavior model in prior step for solv-ing parking problems in Pusan C. B. D. The results of this study are as follows; In the C. B. D of Pusan the peak parking time is between 2 and 3 o'clock P. M., and the average parking duration is 237 minutes. It means the use of parking lots is very ineffi-cient. Hence in order to shorten the parking duration, it is very urgent for drivers to chan-ge parking attitude. The walking distance from the parking lots to his destination is below 300∼500m, so the establishment of parking areas and the arrangement of parking lots in C. B. D should be planned on the base of the above walking distance. The model distinguishing between legal and illegal parking behaviors is derived from the binary decision model. The selected model has the correlation rate, η2=0.505 which is relatively high value This result shows that the detetminating judgement on the legal and illegal parking behavior is influenced mutually such factors as driver's occupation parking purpose monthly income distance to his destination averaged parking duration and age.

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