• Journal of the Korean Applied Science and Technology
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• v.23 no.4
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• pp.307-318
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• 2006

The pyrolysis of high density polyethylene(HDPE) and low density polyethylene(LDPE) was carried out at temperature between 425 and $500^{\circ}C$ from 35 to 80 minutes. The liquid products formed during pyrolysis were classified into gasoline, kerosene, gas oil and wax according to the petroleum product quality standard of Korea Petroleum Quality Inspection Institute. The conversion and yield of liquid products for HDPE pyrolysis increased continuously according to pyrolysis temperature and pyrolysis time. The influence of pyrolysis temperature was more severe than pyrolysis time for the conversion of HDPE. For example, the liquid products of HDPE pyrolysis at $450^{\circ}C$ for 65 minutes were ca. 30wt.% gas oil, 15wt.% wax, 14wt.% kerosene and 11wt.% gasoline. The increase of pyrolysis temperature up to $500^{\circ}C$ showed the increase of wax product and the decrease of kerosene. The conversion and yield of liquid products for LDPE pyrolysis continuously increased according to pyrolysis temperature and pyrolysis time, similar to HDPE pyrolysis. The liquid products of LDPE pyrolysis at $450^{\circ}C$ for 65 minutes were ca. 27wt.% gas oil, 18wt.% wax, 16wt.% kerosene and 13wt.% gasoline.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.4
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• pp.151-158
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• 2008

Gasoline Homogeneous Charge Compression Ignition (HCCI) combustion is a new combustion concept. Unlike the conventional internal combustion engine, the premixed fuel mixture with high residual gas rate is auto-ignited and burned without flame propagation. There are several operating factors which affect HCCI combustion such as start of combustion (SOC), residual gas fraction, engine rpm, etc. Among these factors SOC is a critical factor in the combustion because it affects exhaust gas emissions, engine power, fuel economy and combustion characteristics. Therefore SOC of gasoline HCCI should be controlled precisely, and SOC detection should be preceded SOC control. This paper presents a control oriented SOC detection method using 50 percent normalized difference pressure. Normalized difference pressure is defined as the normalized value of difference pressure and difference pressure is difference between the in-cylinder firing pressure and the motoring pressure. These methods were verified through the HCCI combustion experiments. The SOC detection method using difference pressure provides a fast and precise SOC detection.

• Tribology and Lubricants
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• v.37 no.6
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• pp.232-239
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• 2021

Petroleum is the most consumed energy source in Korea with a usage rate of 38.7% among the available primary energy sources. The price of liquid petroleum products in Korea includes taxes such as transportation·environment·energy tax. Thus, illegal production and distribution of liquid petroleum is widespread because of its huge price difference from that of the normal product and its tax-free nature. Generally, the illegal petroleum product is produced by mixing liquid petroleum with other similar petroleum alternatives. The two kinds of gasoline, common gasoline and premium gasoline, are being distributed in Korea. The premium gasoline is often adulterated with cheaper common gasoline that lowers the octane number of gasoline. It is possible to distinguish them with their color difference, green and yellow for different grade gasoline. However, when small volume of common gasoline is added to premium gasoline, it is difficult to determine whether premium gasoline contained common grade or not. In this study, we inspect gasoline, which is illegally produced by mixing common gasoline to premium gasoline. When the ratio of mixing common gasoline is increased, premium gasoline shows decreasing absorbance at 600 nm and 650 nm under UV-Vis spectrometer. Moreover, the detected intensity (mV·s) of green dye in high performance liquid chromatography (HPLC) was decreased by common gasoline under 0.99 correlation value. The more the common gasoline is mixed, the more olefin and naphthene are detected by gas chromatography. In addition, trimethyl pentane as octane improver, paraffin and toluene are decreased by common gasoline mixing. The findings of this study suggests that illegal petroleum can be identified by analysis of components and simulated samples.

• Applied Chemistry for Engineering
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• v.18 no.1
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• pp.1-9
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• 2007

Compressed natural gas (CNG) has been used as a vehicular fuel compressed at 24.8 MPa because the energy density of natural gas is extremely low compared with gasoline. Thus it has problems in both safety and cost for multiple stage compression. For these reasons the use of adsorbed natural gas (ANG) has been pursued since the storage of natural gas is possible at a relatively low pressure. The present target is to obtain media to store natural gas at 3.5 MPa as ANG that ensures the comparable energy density of CNG, giving approximately one-fourth the driving range of an equivalent volume gasoline tank. In this review, the recent development of carbon media, their characteristics, and practical applications for natural gas storage are introduced and some recommendations are also suggested.

• Journal of Power System Engineering
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• v.22 no.6
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• pp.67-73
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• 2018

Gasoline that meets the quality standards is distributed in Korea. However, consumers who use toluene or solvent mixed with gasoline have appeared due to rising crude oil prices and for the purpose of tax evasion. Gasoline quality standard is enacted by the domestic and international research reference. A wrong fuel can influence automobile performance or environmental issue. Thus, empirical data from this issue is necessary. Therefore, this research observed catalyst influence by gasoline property change and inspect influence of environment. In this study, fuel property evaluation, lean-burn evaluation, and real vehicle exhaust emission test were performed. In the result of fuel property, the fuel "A" was measured to be up to 27% less octane than the normal gasoline and the distillation property was measured 24% higher than normal gasoline. In the test result of single cylinder engine lean-burn test, the fuels "A" and "B" show torque value 20% less than the normal gasoline. As a result of vehicle test using the catalyst, the fuel "A" was increased more than the normal gasoline with 83% THC, 1,806% CO and 128% NOx, and the fuel "B" was increased more than normal gasoline with 1.6% THC, 391% CO and 142% NOx.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.3
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• pp.54-62
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• 2007

The knock characteristics in an engine were investigated under homogeneous charge compression ignition (HCCI) operation. Liquefied petroleum gas (LPG)and gasoline were used as fuels and injected at the intake port using port fuel injection equipment. Di-methyl ether (DME) was used as an ignition promoter and was injected directly into the cylinder near compression top dead center (TDC). A commercial variable valve timing device was used to control the volumetric efficiency and the amount of internal residual gas. Different intake valve timingsand fuel injection amounts were tested to verify the knock characteristics of the HCCI engine. The ringing intensity (RI) was used to define the intensity of knock according to the operating conditions. The RI of the LPG HCCI engine was lower than that of the gasoline HCCI engine at every experimental condition. The indicated mean effective pressure (IMEP) dropped when the RI was over 0.5 MW/m2and the maximum combustion pressure was over 6.5MPa. There was no significant relationship between RI and fuel type. The RI can be predicted by the crank angle degree (CAD) at 50 CA. Carbon monoxide (CO) and hydrocarbon (HC) emissions were minimized at high RI conditions. The shortest burn duration under low RI was effective in achieving low HC and CO emissions.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.2
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• pp.27-32
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• 2000

The main objective of this work is to investigate the effect of ambient conditions on the spray behavior and spray characteristics of high-pressure fuel injector. For this purpose, the effects of ambient pressure and temperature on the spray characteristics have been studied by applying the analysis of visualization system and phase Doppler particle analyzer. In this experiment, the visualization of spray behavior was performed under various ambient gas conditions and injection parameters such as gas temperature, ambient pressure, injection pressure of injector, and axial distance from the nozzle tip. Based on the investigation results, the spray tip penetration and spray width decrease with the increase of ambient gas pressure in the spray chamber. The effects of the spray parameters on the microscopic characteristics of gasoline spray were discussed.

• Journal of Mechanical Science and Technology
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• v.15 no.1
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• pp.108-116
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• 2001

The in-cylinder flow field of gasoline engine comprises unsteady compressible turbulent flows caused by the intake port, combustion chamber geometry. Thus, the quantitative analysis of the in-cylinder flow characteristics plays an important role in the improvement of engine performances and the reduction of exhaust emission. In order to obtain the quantitative analysis of the in-cylinder gas flows for a gasoline engine, the single-frame particle tracking velocimetry was developed, which is designed to measure 2-dimensional gas flow field. In this paper, influences of the swirl and tumble intensifying valves on the in-cylinder flow characteristics under the various intake flow conditions were investigated by using this PTV method. Based on the results of experiment, the generation process of swirl and tumble flow in a cylinder during intake stroke was clarified. Its effect on the tumble ratio at the end of compression stroke was also investigated.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.4
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• pp.10-17
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• 2000

This work presents an investigation of aerodynamic characteristics of fuel spray injected from a high pressure hollow cone swirl injector into a constant volume chamber. Laser tomography visualization was used to interrogate the fuel and air mixing characteristics and the effect of chamber pressure and temperature increase was analyzed, Preliminary results on spray development showed that mixing effect tends to increase with the increase of injection pressure and chamber gas pressure yielding a decrease of spray penetration and an attenuation of well-defined vortex structure. Topological analysis of the spray structure has been performed to initiate the understanding of mixing and vaporization process. For the present experimental conditions fuel injection pressure and chamber gas pressure appear as the dominant factors which govern the transient mixing characteristics. Moreover spray atmixation characteristics are improved by increasing chamber gas temperature.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.3
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• pp.1-6
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• 2003

Natural gas is one of the promising alternative fuels because of the abundant deposits and the cleanness of emission gas. CNG has a lot of merits except lower burning speed has a slow disadvantage. One way to overcome the disadvantage is to raise a turbulence intensity. We give various intake for changing turbulence intensity in the cylinder by three kinds of swirl control valve with a way to raise a turbulence intensity. In the present study, a $1.8\ell$ conventional gasoline engine is modified to use a CNG as a fuel instead of gasoline. We try to virify combustion and emission characteristics in each engine parameters. Parameters of experimentation are equivalence ratio, spark timing and intake flow change. The results of this study are as swirl flows. In the case of adding swirl flow, burning speed and torque are increased. But NOx and THC concentration are increased a little respectively.