• Title/Summary/Keyword: Gaseous pollutants

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Organic Pollutant Transport in Unsaturated Porous Media by Atmospheric Breathing Processes( I ) - Partition Coefficient -

  • Ja-Kong;Lim, Jae-Shin;Do, Nam-Young
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1996.11a
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    • pp.50-53
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    • 1996
  • This paper reports the experimental results for the determination of the overall partition coefficient of VOCs in unsaturated soil, A chromatographic method was used for the determination of gaseous partition coefficients to natural soil under various water content conditions. The equilibrium vapor pressure of water over saturated salt solution was used to fix the relative humidity of the air and control the water content of the soil systems. The transport behavior was studied for dichloromethane, trichloroethane and dichlorobenzene pollutants, with log octanol-water partition coefficients(log $K_{ow}$ ) which range from 1.25 to 3.39, or water to soil partitioning which varies by 135 times; water solubility constants which vary by 3 times; and vapor pressures which range from 1 to 362 torr. Water content of the soil had a pronounced effect on the effective partition coefficient(between gas and soil + water stationary phase) as well as on the effective dispersion coefficient.

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Preparation and Structural Characterization of Silver-Deposited Activated Carbons (은도금 활성탄소의 제조 및 기공구조 분석)

  • Jung, Woo-Young;Park, Soo-Jin;Pak, Pyong-Ki
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.173-174
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    • 2003
  • Activated carbons (ACs) are widely used in adsorption for the removal of gaseous and aqueous pollutants[1,2]. The microbicidal property of ACs is also very important, in order to decrease the risk of water and air contamination with microorganisms. For this purpose, ACs have impregnated with silver or with metallic oxides[2]. However, in the case of Ag supported ACs prepared by impregnation, there are some problem, such as, heat-treatment, highly decrease in specific surface area and pore volume by deposited Ag, and rapidly elution of Ag at the initial stage of usage[3]. (omitted)

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Correlation of $CO_2$ Concentration with Number of Passengers and Tunnel Regions in the KTX Cabin (KTX 객실의 $CO_2$ 농도와 승객 수 및 터널구간과의 상관관계)

  • Kwon, Soon-Bark;Cho, Young-Min;Park, Duck-Shin;Park, Eun-Young
    • Proceedings of the KSR Conference
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    • 2006.11b
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    • pp.192-195
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    • 2006
  • With increasing concerns of indoor air quality, $CO_2$ concentration in the public transportation, such as train, bus, and subway, draws big interests. The $CO_2$ concentration in the indoor air is regarded as index of ventilation status rather than that of adverse health effect. In this study, we measured the time-series of $CO_2$ concentrations in the KTX cabin during the journey of Gyongbu-line (Seoul-Busan) and Honam-line (Seoul-Mokpo) with the number of passengers on board. At the same time, the concentration of particulate matter (PM), temperature, humidity and gaseous pollutants including HCHO and VOCs were monitored. It is found that the $CO_2$ concentration was correlated linearly with number of passengers and was highly correlated with tunnel regions where the ventilation unit (flap) was closed.

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Properties of Adsorption Matrix for Improving Indoor Air Quality using Cork (코르크를 활용한 실내공기질 개선용 흡착 경화체의 특성)

  • Kim, Yeon-Ho;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.56-57
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    • 2019
  • Recently, the risk of fine dust is emerging in Korea. According to the OECD report, the incidence of hospitalization and mortality from lung disease is increased, and the incidence of lung cancer and mortality from ischemic heart disease with prolonged exposure are increased. In addition, indoor air quality has become an important factor affecting the human body as indoor life has increased due to the Industrial Revolution. Air pollutants that cause indoor air deterioration typically include particulate dusts as described above, formaldehyde and VOCs released in gaseous form from adhesive wood products used in building materials and furniture. May cause breathing problems. In this study, we analyzed the properties of adsorption matrix for improving indoor air quality using cork.

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The Evaluation of Catalytic Trap Oxidizer on a City Bus (市內버스 煤煙防止를 위한 觸媒酸化濾過裝置의 實用化 硏究)

  • Cho, Kang-Rae;Kim, Yang-Kyun;Eom, Myung-Do;Kim, Chong-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.1
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    • pp.79-87
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    • 1989
  • In order to reduce the smoke emission from the in-service city bus, this study was evaluated the particulate reduction efficiency and regeneration ability of the catalitic trap oxidizer (CTO) on the city bus (D0846HM engine) equipped with it. Before the on-road CTO test, the laboratory test of CTO on engine test-bench was performed. Reduction efficiencies of smokes and particulates were 54 and 45%, and those of gaseous pollutants such as carbon monoxide (CO) and hydrocarbons (HC) were 90 and 60%. In order to evaluate the regeneration ability of the CTO by the catalytic oxidation of trapped particulate, field test was performed on the in-service road. The regeneration temperature was 350$^\circ$ which was same with the exhaust temperature of city bus.

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A Field Survey on the Characteristics of Air Pollutants Emission from Commercial Charcoal Kiln (숯가마에서 발생하는 대기오염물질의 배출특성에 관한 현장조사 연구)

  • Park, Seong-Kyu;Choi, Sang-Jin;Kim, Jin-Yun;Park, Gun-Jin;Hwang, Ui-Hyun;Lee, Jeong-Joo;Kim, Tae-Sik
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.5
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    • pp.601-614
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    • 2013
  • The commercial charcoal kiln was projected the largest source of biomass burning sector in Korea. Commercial charcoal kiln was operated to emit air pollutants into the air without any air pollution prevention equipment. The object of this field survey was to understand characteristics of air pollutants concentration and emission factors and to provide preliminary data for effective processor from oak charcoal manufacturing process. As result of field survey, TSP, $PM_{10}$ and $PM_{2.5}$ concentration from charcoal kiln were 400~37,000 $mg/m^3$. These values were over the 100 $mg/m^3$ in TSP, this value was effluent quality standard of Clean Air Conservation Act. The average concentration of CO, $SO_2$ and TVOC were 2~5%. 0~110 ppm and 820~10,000 ppm respectively. The emission factors were 42.4 g-PM/kg-oak in TSP, 40.3 g-PM/kg-oak in $PM_{10}$, 38.2 g-PM/kg-oak in $PM_{2.5}$, 182.5 g-CO/kg-oak, 1.0 g-NO/kg-oak, $SO_2$ 0.2 g-$SO_2/kg$-oak and 104.4 g-TVOC/kg-oak. The part of commercial charcoal kiln had air pollution prevention equipment but it was difficult to work properly. Much wood tar excreted in exhaust emissions from oak charcoal manufacturing process. This wood tar was cause of many troubles sticking in the air pollutant prevention equipment. For handling particulate matters and gaseous air pollutants from oak charcoal manufacturing process in biomass burning, air pollutant prevention equipment design and management needs preprocessor for removal wood tar.

Studies on the Behavior of SO2 and NOx over Yellow Sea Area during Long Term Aircraft Measurements(1997~2007) (장기간(1997~2007) 창공관측을 이용한 서해상 SO2 및 NOx의 거동 연구)

  • Song, Hyung-Do;Choi, Jin-Soo;Jang, Im-Suk;Kim, Jeong-Soo;Lee, Suk-Jo
    • Journal of Environmental Science International
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    • v.18 no.5
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    • pp.569-578
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    • 2009
  • Aircraft Measurements of gaseous pollutants($SO_2$, NOx and $O_3$) in the Yellow Sea area, were carried out on 1997-2007. Main measurement site in 124$^{\circ}$-127$^{\circ}$E, 35$^{\circ}$-37$^{\circ}$N (in the Yellow Sea), have been done along the paths classified vertically and zonally. To understand how the air stream affects Long-range transboundary pollutants in Northease Asia (LTP), the tracks of pollutants in northeast Asia have been analyzed by dividing into 6 different regions(regions I-V and L). Compared with Korea's local sources and western north Pacific influenced by the Yellow Sea, when the air stream from region II is dominant, the $SO_2$ concentrations are 3-6times higher. In region II and III, $SO_2$ concentrations are represented highest at 25.0 and 14.7 ppb, respectively. However, in other regions, $SO_2$ concentration was recorderd the highest at 1.1-3.8 ppb, which is 7-15% higher then the highest one over the region II and III. During 1997-2007, the mean amount of incoming pollutants is 0.162 $ton/km{\cdot}hr$ exceeding about 5-times mean amount of outgoing pollutants over the West Sea. During the observed period, the amount of incoming and outgoing $SO_2$ over the Yellow Sea is the highest in winter, at 0.224 $ton/(km{\cdot}hr)$ and 0.120 $ton/(km{\cdot}hr)$, respectively.

Study on the Distributions of VOCs, Aldehydes, PAHs Concentration in Seoul Metropolitan Area (수도권 지역에서 환경대기 중 유해대기오염물질 (VOCs, Aldehydes, PAHs) 농도분포 특성 연구)

  • Han, Jin-Seok;Lee, Min-Do;Lim, Young-Jae;Lee, Sang-Uk;Kim, Young-Mi;Kong, Boo-Joo;An, Jun-Young;Hong, You-Deog
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.574-589
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    • 2006
  • Although concentrations of hazardous air pollutants(HAPs) are very low in the atmosphere, a growing attention has been paid on such compounds due to their high toxicity and bioaccumulation potentials into human body. In order to control and manage the amount of these materials in ambient air, it is necessary to construct monitoring system of them and to know the current concentration level of HAPs above all. In this work, a wide range of HAPs has been measured in metropolitan area to recognize the present state of HAPs in this area. The measured concentration of VOCs was higher in order of Jeonnongdong, Jeongdong, and Yangsuri. The regional difference of VOCs concentration was also highest in spring. Its total VOCs was ranged from $15.17{\sim}41.45$ ppb. Benzene $0.43{\sim}2.32$ ppb showed similar concentration level with the result of previous researches in Seoul. This value is a little higher than the average concentration 0.92 ppb for national ambient air quality standards in Japan. The concentration of aldehydes in this study was lower than those of other researches. Previous works in Seoul metropolitan area showed that the concentration of formaldehyde and acetaldehyde were higher than 5 ppb. The concentration of gaseous and particulate PAHs was high in order of winter, spring, and summer More than 90% of PAHs with low molecular weight such as 2-rings and 3-rings PAHs existed in gas phase. On the other hands, PAHs with high molecular weight more than 5-rings PAHs almost existed in particulate. In spring, the concentration of gaseous PAHs was 24.38 $ng/m^3$ in Jeongdong. Among the particulate PAHs, the concentrations of Naphthalene, Benzo(b)fluoranthene, and Benzo(g, h, i)perylene were higher than others. Especially, the concentration of Benzo(a)pyrene, a important carcinogenic pollutant, was highest in winter 0.5 $ng/m^3$ and ranged from 0.03 to 0.3 $ng/m^3$ in spring and summer, which is lower than the monitoring result in 90's. These components were mainly originated from the vehicle exhaust or heating equipment use.

Measurement of Dry deposition at Seoul, Chunchon and Anmyon-do by Using Filter pack Method (필터팩을 이용한 서울과 춘천, 안면도의 건성 강하량 측정)

  • Kim, Man-Goo;Kang, Mi-Hee;Hong, Young-Min;Park, Ki-Jun;Lee, Bo-Kyung;Lee, Dong-Soo;Kim, San
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.1
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    • pp.19-29
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    • 2001
  • Atmospheric concentrations of acidic pollutant were measured by the 4 stage filter pak method at Chunchon and by the 3 stage filter pack method at Seoul and Anmyon-do from January to December 1998. The sample was collected for 24 hours on every Wednesday. Concentrations of particulate matters were highest at Anmyon-do. The particulate concentration was much higher during the warm season than other seasons. While the particulate concentration was higher during the warm season, the concentration of gaseous matter was higher in winter. Dry deposition flux was calculated by using reported deposition velocities and concentration of pollutants measured in this study. The dry deposition velocities used in this study for SO$_2$, SO$_{4}^{2}$, HNO$_3$,NO$_{3}^{-}$ and NH$_3$ were 0.29, 0.15, 2.08( 2.13 only for Anmyon-do), 0.20 and 1.00cm/sec, respectively. At Chunchon, annual sulfur flux originated from dry deposition was 384 kg/$textrm{km}^2$, and the flux from wet deposition was 782kg/$textrm{km}^2$. Dry deposition of sulfur was 33% of total sulfur deposition. The annual nitrogen flux originated from dry deposition was 1,892kg/$textrm{km}^2$. And the flux from wet deposition was 1,066kg/$textrm{km}^2$. Dry deposition of nitrogen was 64% of total nitrogen deposition. Dry deposition as well as wet deposition have to be considerd in the study on acidification of environment such as soil or watershed.

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Waste Minimization Technology Trends in Semiconductor Industries (반도체 제조 공정에서의 환경 유해성 배출물 절감 기술 동향)

  • Lee, Hyunjoo;Yi, Jongheop
    • Clean Technology
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    • v.4 no.1
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    • pp.6-23
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    • 1998
  • Recently, semiconductor industry has grown rapidly because of the large demand for electronic devices and equipment. The semiconductor industries have also played an important role on the economic growth in Korea. As the environmental regulations become strict, the proper environmental management and the well-developed waste minimization technologies in semiconductor industries are two of urgent problems to be solved. The semiconductor manufacturing process consists of a series of continuous chemical processes, such as cleaning, oxidation, diffusion, photolithography, etching and film deposition. During the processes, various environmentally hazardous wastes are produced. The wastes may be classified as wastewater, gaseous pollutants, and solid wastes. For waste minimization, the substitution of raw materials and process optimization techniques are used, while the selective destruction technologies of toxic chemicals contained in the wastes have been reported. Also, new technologies have been developed for source reduction and waste reduction, such as reduction of toxic chemical use and substitution of hazardous liquids with gaseous reactants or solvent.

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