• Title/Summary/Keyword: Gaseous hydrogen

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Recent Developments of Tubular Flame Burners

  • Ishizuka, S.
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.7-8
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    • 2006
  • As a new type of flame, tubular flame has attracted much attention from a fundamental viewpoint and many experimental and theoretical studies have been made on its characteristics. Recently, it is also recognized that the tubular flame has great potentials as practical combustor because its stability range is very wide in fuel concentration and also in injection velocity. Thus, tubular flame burners have been developed for various kinds of fuels. They are gaseous fuels of methane, propane, hydrogen, and by-product fuels gases in steel making processes including BFG (Blast Furnace Gas), LDG (LD Converter Gas), and COG (Cokes-Oven Gas), liquid fuels of kerosene, A-type and C-type heavy oils, and a solid fuel of biomass powder. In this paper, recent developments of the tubular flame burners have been briefly introduced.

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Numerical Analysis of Dynamic Combustion in HyShot Scramjet Combustor with a Transverse Fuel Injection (수직 연료 분사기구를 포함하는 HyShot 스크램제트 연소기의 동적 연소 유동해석)

  • Won, Su-Hee;Jeung, In-Seuck;Choi, Jeong-Yeol
    • Journal of the Korean Society of Combustion
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    • v.12 no.2
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    • pp.1-9
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    • 2007
  • This paper describes numerical efforts to investigate combustion characteristics of HyShot scramjet combustor, where gaseous hydrogen is transversely injected into a supersonic cross flow. The corresponding altitude, angle of attack, and equivalence ratio are 35-23 km, $0^{\circ}$, and 0.426 respectively. Two-dimensional simulation reasonably predicts combustor inner pressure distribution and reveals periodic combustion characteristics of HyShot scramjet combustor. Altitude effects are also investigated and the strength of flow instability and subsonic boundary layer thickness affect the combustion efficiency according to altitudes. Frequency analyses provide the flow instability effects on the turbulent combustion in HyShot scramjet combustor.

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Numerical Analysis of Dynamic Combustion in HyShot Scramjet Combustor with a Transverse Fuel Injection (수직 연료 분사기구를 포함하는 HyShot 스크램제트 연소기의 동적 연소 유동해석)

  • Won, Su-Hee;Jeung, In-Seuck;Choi, Jeong-Yeol
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.79-85
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    • 2007
  • This paper describes numerical efforts to investigate combustion characteristics of HyShot scramjet combustor, where gaseous hydrogen is transversely injected into a supersonic cross flow. The corresponding altitude, angle of attack, and equivalence ratio are 35-23 km, $0^{\circ}$, and 0.426 respectively. Two-dimensional simulation reasonably predicts combustor inner pressure distribution and reveals periodic combustion characteristics of HyShot scramjet combustor. Altitude effects are also investigated and the strength of flow instability and subsonic boundary layer thickness affect the combustion efficiency according to altitudes. Frequency analyses provide the flow instability effects on the turbulent combustion in HyShot scramjet combustor.

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Foodborne Pathogen Reduction을 위한 항균제의 새로운 Delivery System인 Aerosolization

  • O, Se-Uk;Gang, Dong-Hyeon
    • Bulletin of Food Technology
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    • v.18 no.1
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    • pp.91-98
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    • 2005
  • Aims: As a preliminary experiment on new sanitizer delivery tools, the efficacy of aerosolizedsanitizer on foodborne pathogens was investigated in larger model chamber system.Methods: Peroxyacetic acid and hydrogen peroxide were aerosolized in a model system againstartificially inoculated target microorganisms on laboratory media. Cultures of 4 different foodborne pathogens were inoculated and affixed onto 3 different heights (bottom, wall, and ceiling), and 3different orientations (face-down, vertical, and face-down) inside a commercial semi-trailer cabinet(14.6 x 2.6 x 2.8 m). Sanitizer was aerosolized into 2 m droplet size fog and treated for 1 h atambient temperature.Results: Populations of Bacillus cereus, Listeria innocua, Staphylococcus aureus, and Salmonellatyphimurium were reduced by an average of 3.09, 7.69, 6.93 and 8.18 log units per plate, respectively.Interestingly, L. innocua, Staph. aureus, and Salm. typhimurium showed statistically not different (P$\leq$ 0.05) reduction patterns relative to height and orientation that were never expected in a sprayingsystemConclusion and significance: Aerosolized sanitizers diffuse like gaseous sanitizers, so it has greatpotential for use in commercial applications.

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The Origin of Diamonds (I). Experimental Data

  • R. LEverett angford
    • Journal of the Korean Chemical Society
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    • v.22 no.2
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    • pp.95-98
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    • 1978
  • Using gases trapped within natural diamonds as defected by crushing in the sample system of a research mass spectrometer, a proposed gaseous environment for the formation of diamonds is presented. Diamonds crushed under a vacuum of $10^{-9}$torr at a temperature of $200^{\circ}C$ yielded in order of abundance, water, hydrogen, nitrogen, carbon dioxide, methane, carbon monoxide, argon, and ethanol.

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Electrochemical model for the simulation of solid oxide fuel cells (고체산화물연료전지의 시뮬레이션을 위한 전기화학모델)

  • Park, Joon-Guen;Lee, Shin-Ku;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.63-66
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    • 2008
  • This study presents 0-dimensional model for solid oxide fuel cells(SOFCs). The physics of the cell and the simplifying assumptions are presented, and only hydrogen participates in the electrochemical reaction. The electrical potential is predicted using this model. The Butler-Volmer equation is used to describe the activation polarization and the exchange current density is changed according to the partial pressure of reactants and the temperature. The electrical conductivities of electrodes and an electrolyte are calculated for the ohmic polarization. Material characteristics and temperature affect those factors. Analysis of concentration polarization based on transport of gaseous species through porous electrodes is incorporated in this model. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results and numerical results by other researchers.

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Experimental Study for the Identification of the Nascent Product of OH Heterogeneous Reaction with NaCl using Chemical Ionization Mass Spectrometry

  • Park, Jong-Ho;Ivanov, Andrey V.;Molina, Mario J.
    • Mass Spectrometry Letters
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    • v.3 no.4
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    • pp.108-111
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    • 2012
  • An experimental study on the nascent product of the OH heterogeneous reaction with NaCl was performed under dry and wet conditions using a bead-filled flow tube system coupled to a high-pressure chemical ionization mass spectrometer. The ozone concentration in the flow tube for the atomic hydrogen removal was varied in order to control the conversion reaction of molecular chlorine into HCl for the identification of the nascent product. The mass spectrometric observation was that the $O_3$ introduction reduced the concentration HCl, while it increased the concentration of $Cl_2$ and ClO. Based on the experimental results, we suggest that the nascent product of the titled reaction is gaseous $Cl_2$, which is followed by fast conversion into HCl in presence of H. No significant difference in the concentration profile between under dry and wet (RH = 2%) conditions was observed.

Microstructural Changes of $SiO_2-Si$ During Liquid-Phase Sintering (액상소결단계에서 $SiO_2-Si$의 미세조직 변화)

  • 강대갑;정충환
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.443-447
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    • 1994
  • Compacts of mixed SiO2-Si powder were liquid phase sintered at 145$0^{\circ}C$ for up to 60 min in a hydrogen atmosphere. In contrast to the conventional microstructures of liquid phase sintered materials, the specimens showed that the solid phase of SiO2 formed a matrix while the liquid phase of Si was the dispersed in the solid matrix. The dispersion of liquid Si pockets was attributed to the high wetting angle of liquid Si on solid SiO2. Because of relatively high solubility of SiO2 in liquid Si at 145$0^{\circ}C$, SiO2 particles accommodated their shape via a solution-reprecipitation process. The liquid Si pockets grew by coalescing with their neighbour pockets. In the latter stage of the sintering, plate-shape grains appeared in the liquid Si pockets. The grains were SiO2 phase precipitated from the liquid Si which was oversaturated with oxygen during cooling to room temperature. By the formation and subsequent removal of the gaseous SiO phase due to the reaction between SiO2 and Si, the specimens became porous.

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Kinetic Analysis of Diffusion Aluminide Coating (확산 알루미나이드 코팅의 속도론적 해석)

  • 손희식;김문일
    • Journal of the Korean institute of surface engineering
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    • v.28 no.3
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    • pp.152-163
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    • 1995
  • A theoretical model which combines gaseous transport and solid state diffusion with the multi-component equilibrium at the gas/pack and gas/coating interfaces was used to study the kinetics of diffusion aluminide coating. The diffusion aluminide coatings were applied by pack cementation with Ni substrate under argon atmosphere in the high activity and the low activity pack containing $NH_4CL$ or $AlF_3$ activator. On the basis of the process conditions, the suggested model allows the surface composition, the growth rate of coating layers and the aluminium concentration profiles in coatings to be calculated. In the case of $NH_4$Cl activator, careful consideration was required in the analysis, because activator contains nitrogen and hydrogen as well as halogen element to activate the pack. A good agreement is obtained between the theoretical predictions and the experimental results.

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Computer simulation of aluminide coating by pack cementation (팩 세멘테이션에 의한 알루미나이드 코팅의 컴퓨터 시뮬레이션)

  • Kim, M.I.;Sohn, H.S.;Lee, I.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.1
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    • pp.3-11
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    • 1995
  • A theoretical model which combines gaseous transport and solid state diffusion was used to study aluminide coating process by pack cementation. The aluminide coatings were applied in the high activity pack containing $NH_4Cl$ activator with Ni substrate under argon atmosphere. On the basis of the process conditions, the suggested model allows the surface composition, the growth rate of coating layers and the aluminium concentration profiles in coatings to be calculated. In the case of $NH_4Cl$ activator, careful consideration was required in the analysis, because activator contains nitrogen and hydrogen as well as halogen element to activate the pack. A good agreement is obtained between the theoretical predictions and the experimental results.

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