• 제목/요약/키워드: Gas-phase Analysis

검색결과 878건 처리시간 0.022초

CARS를 이용한 희박 예혼합 가스터빈 연소기내 온도 측정 (2);당량비가 위상별 온도에 미치는 영향 (Phase-resolved CARS Temperature Measurements in a Lean Premixed Gas Turbine Combustor (2);Effect of equivalence ratio on phase-resolved gas temperature)

  • 이종호;문건필;박철웅;한재원;전충환;장영준
    • 한국연소학회:학술대회논문집
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    • 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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    • pp.103-108
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    • 2003
  • The effect of equivalence ratio and fuel/air mixing quality on the phase-resolved gas temperatures at different phases of the oscillating pressure cycle was experimentally investigated. An atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane with heat release rate of 1.59kW was used. Temperature measurements were made using coherent anti-Stokes Raman spectroscopy (CARS) at several spatial locations for typical unstable combustion conditions. Analysis was conducted using parameters such as phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs). Also the probability on the occurrence of high temperature (over 1900K) was investigated to get the information on the perturbation of equivalence ratio and NOx emission characteristics. It was shown that most of temperature histograms exhibit Gaussian profile which has short breadth of temperature fluctuation at equivalence ratio of 0.6, while beta profile was predominant for the cases of other equivalence ratios (${\Phi}$=0.55, 0.50). The characteristics on the occurrence of high temperature also displayed periodic wave form which is very similar to the pressure signal. And the amplitude of this profile goes larger as the fuel/air mixing quality become poorer. These also provided additional information on the perturbation of equivalence ratio at flame as well as NOx emission characteristics.

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Gas chromatograph-mass selective detector를 이용한 식육 중 잔류농약의 동시분석 (Simultaneous detection method for pesticide residues in meat by gas chromatograph-mass selective detector)

  • 홍인석;최윤화;권택부;이정학
    • 한국동물위생학회지
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    • 제28권3호
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    • pp.285-294
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    • 2005
  • This study was conducted to investigate the extraction method for the determination of organochlorine, organophosphorus and synthetic pyrethroid pesticide residues in beef fat by gas chromatography-mass selective detector(GC-MSD). Twenty one pesticide residues in fat were determined using a simple and rapid procedure based on solid- phase extraction(SPE) clean-up cartridges with octadecyl $(C_{18})-bonded$ porous silica, florisil, $10\%$ deactivated florisil. a tandem $C_{18}$ and florisil and a tandem $C_{18}$ and $10\%$ deactivated florisil. Solvent-solvent extraction using acetonitrile was not satisfied to eliminate fat interference for pesticide residue analysis by GC-MSD, and the recoveries of the method in fat ranged from 16.2 to $57.3\%$ except DDT$(83.2\%)$. The recoveries of SPE methods using a tandem $C_{18}$ and Florisil was $59.6\~123.8\%$ except fenitrothion $(135.2\%)$. the SPE method was verified the satisfactory performance of pre-treatment for pesticide residues analysis in fat by GC-MSD. The efficiency of florisil deactivated with $10\%$ water has been not proved significantly on recoveries of pesticide residues in fat.

가스 하이드레이트 부존층의 구조 파악을 위한 탄성파 전산처리 및 AVO 분석 (Seismic Pre-processing and AVO analysis for understanding the gas-hydrate structure)

  • 정부흥
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 춘계학술대회
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    • pp.634-637
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    • 2005
  • Multichannel seismic data acquired in Ulleung Basin of East Sea for gas hydrate exploration. The seismic sections of this area show strong BSR(bottom simulating reflections) associated with methane hydrate occurrence in deep marine sediments. Very limited information is available from deep sea drilling as the risk of heating and destabilizing the initial hydrate conditions during the processing of drilling is considerably high. Not so many advanced status of gas hydrate exploration in Korea, the most of information of gas hydrate characteristics and properties are inferred from seismic reflection data. In this study, The AVO analysis using the long offset seismic data acquired in Ulleung Basin used to explain the characteristics and structure of gas hydrate. It is used primarily P-wave velocity accessible from seismic data. To make a good quality of AVO analysis input data, seismic preprocessing including 'true gain correction', 'source signature deconvolution', twice velocity analysis and some kinds of multiple rejection and enhancing the signal to noise ratio processes is carried out very carefully. The results of AVO analysis, the eight kinds of AVO attributes are estimated basically and some others of AVO attributes are evaluated for interpretation of AVO analysis additionally. The impedance variation at the boundary of gas hydrate and free gas is estimated for investing the BSR characteristics and properties. The complex analysis is performed also to verifying the amplitude variation and phase shift occurrence at BSR. Type III AVO anomaly appearance at saturated free gas area is detected on BSR. It can be an important evidence of gas hydrate deposition upper the BSR.

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화염전달함수의 위상차를 이용한 시간지연 분석 (Time Lag Analysis Using Phase of Flame Transfer Function)

  • 표영민;김지환;김대식
    • 한국분무공학회지
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    • 제21권2호
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    • pp.104-110
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    • 2016
  • Main purpose of the current paper is to show results of time lag analysis using phase information of flame transfer function in order to predict combustion instabilities in a gas turbine combustor. The flame transfer function (FTF) is modeled using a commercial Computational Fluid Dynamics (CFD) code (Fluent). Comparisons of the modeled flame shapes with the measured ones were made using the optimized heat transfer conditions and combustion models. The FTF modeling results show a quite good agreement with the measurement data in predicting the phase delay (i.e. time lag). Time lag analysis results using the phase of FTF shows better combustion instability prediction accuracy than using time lag calculated from the steady state flame length.

Analysis of Rotationally Cooled Vibronic Emission Spectra ($1^2A_2→1^2B_2$) of m-Xylyl Radical

  • 최익순;이상국
    • Bulletin of the Korean Chemical Society
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    • 제17권8호
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    • pp.749-753
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    • 1996
  • The rotationally cooled but electronically excited m-xylyl radical has been generated in a jet from the gas mixture of precursor m-xylene and buffer gas He by a technique of corona excited supersonic expansion. The visible vibronic emission spectra in the transition of 12A2→12B2 of m-xylyl radical in the gas phase have been recorded using a Fourier transform spectrometer. The spectra have been analyzed for the assignments of the vibrational frequencies in the electronic ground state with combination of the torsional frequencies reported previously.

압전 수정 결정 미량 천평[PZ QCM] 바이오센서의 원리와 응용 (The Theory and Application or Piezoelectric Quartz Crystal Microbalance[PZ QCM] for Biosensor)

  • 김의락
    • KSBB Journal
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    • 제18권2호
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    • pp.79-89
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    • 2003
  • This article contains an overview of acoustic wave devices, the theory and application of piezoelectric quartz crystal microbalances(PZ QCM), clinical analysis, gas phase detection, DNA biosensors, drug analysis, food microbial analysis and environmental analysis.

입자분리기 최적 설계를 위한 다상 유동 해석 (Analysis of Gas-Solid Flow for the Optimum Design of Coal Splitter)

  • 육심균;류제욱;이익형;이상룡
    • 대한기계학회논문집B
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    • 제27권11호
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    • pp.1604-1611
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    • 2003
  • The experimental investigation of a coal splitter used in the 500㎿(e) boilers of fossil power plant is carried out to validate the design criteria. To predict air flow and the amount of particles at the exit, velocity and the weight of particles are measured on test planes using the coal splitter model with two-dimensional phase doppler particle analyzer and the glass fiber filter. It is found that the position of guide plate influences significantly both flow rates of gas and particle at the exit. Gas flow rate was a linear function of the guide plate, whereas particle flow rate was a exponential function of it.

디젤 엔진용 싸이클론 내부 수치 해석 (A Numerical Study on Axial Inlet Cyclone for Diesel Engine)

  • 김성광;손창석;김인관
    • 동력기계공학회지
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    • 제10권2호
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    • pp.16-21
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    • 2006
  • On this study, numerical analysis was performed for the 3 dimensional flow field of gas and particle phase for axial inlet cyclone, a part of dust collector. We applied FVM to visualize the gas phase. The flow was solved using ${\kappa}-{\varepsilon}$ turbulence model. The major parameters considered in this study were helical guide vane, inner diameter, length. Particle trajectory calculations were performed for the particle sizes of $5{\mu}m{\sim}75{\mu}m$. The distribution curve of particle sizes was made of Rosin-Rammler function. The simulation results show various gas flows, particle trajectories on numerical models.

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가스반응법으로 제작된 Al-ALN 복합재의 제 2상 분율과 기공에 따른 열팽창계수 예측 (Prediction of Thermal Expansion Coefficients using the Second Phase Fraction and Void of Al-AlN Composites Manufactured by Gas Reaction Method)

  • 윤주일
    • 한국기계가공학회지
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    • 제18권4호
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    • pp.41-47
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    • 2019
  • The advent of highly integrated, high-power electronics requires low a coefficient of thermal expansion performance to prevent delamination between the heat dissipation material and substrate. This paper reports a preliminary study on the manufacturing technology of gas reaction control composite material, focusing on the prediction of the thermal expansion coefficients of Al-AlN composite materials. We obtained numerical equivalent property values by using finite element analysis and compared the values with theoretical formulas. Al-AlN should become the optimal composite material when the proportion of the reinforcing phase is approximately 0.45.

희토류 및 기타 산화물 Doping 양에 따른 YSZ 기반 복합소재의 상형성 거동 분석 (Analysis of phase formation behavior of YSZ-based composites according to rare earth and other oxide doping amounts)

  • 최용석;이계원;전창우;남산;오윤석
    • 한국표면공학회지
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    • 제55권6호
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    • pp.368-375
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    • 2022
  • YSZ (Yttria Stabilized Zirconia) is used as a thermal barrier coating material for gas turbines due to its low thermal conductivity and high fracture toughness. However, the operating temperature of the gas turbine is rising according to the market demand, and the problem that the coating layer of YSZ is peeled off due to the volume change due to the phase transformation at a high temperature of 1400℃ or higher is emerging. To solve this problem, various studies have been carried out to have phase stability, low thermal conductivity, and high fracture toughness in a high temperature environment of 1400℃ or higher by doping trivalent and tetravalent oxides to YSZ. In this study, the monoclinic phase formation behavior and crystallinity were comparatively analyzed according to the total doping amount of oxides by controlling the doping amounts of Sc2O3 and Gd2O3, which are trivalent oxides, and TiO2, which are tetravalent oxides, in YSZ. Through comparative analysis of monoclinic phase formation and crystallinity, the thermal conductivity of the thermal barrier coating layer according to the amount of doping was predicted.