• Title/Summary/Keyword: Gas-phase

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Synthesis of $WS_2$ Solid Lubricant ($WS_2$ 고체 윤활제의 합성)

  • 신동우;윤대현;황영주;김성진;김인섭
    • Tribology and Lubricants
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    • v.13 no.4
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    • pp.60-65
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    • 1997
  • The tungsten disulfide $(WS_2)$ solid lubricant was synthesized by two different reaction processes, i.e., the reaction between $CS_2$ gas phase and solid $WO_3$powder, and the vapour phase transport method of tungsten and sulfur in a high vacuum. The chemical and physical characteristics of synthesized $WS_2$powder were analyzed in terms of the average particle size, morphology, crystalline phase etc. in comparison with those of commercial $WS_2$powder. The solid $WO_3$ powder with the average size of 0.2 ${\mu}{\textrm}{m}$ was reacted with $CS_2$gas flowed with$N_2$or 96%$N_2{\times}4%H_2$forming gas for 36 h and 24 h at 90$0^{\circ}C$ respectively. $WS_2$ crystalline phase was then formed through the intermediate phase of .$W_{20}O_{58}$ In the case of vapour phase transport method, the 3.5 wt% iodine was added as a vapour transport reagent into the composition of tungsten and sulfur powders maintaining a constant molar ratio of W:S=1:2.2. The mixture was then heat treated at 85$0^{\circ}C$ for 2 weeks in vacuum. The reaction product obtained showed the average size of 12 ${\mu}{\textrm}{m}$ and the hexagonal plate shape of typical solid lubricant with 2H-$WS_2$crystalline phase.

Integral Analysis of the Effects of Non-absorbable gases on the Heat Mass Transfer of Laminar Falling Film

  • Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.6
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    • pp.56-66
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    • 1998
  • The absorption process of water vapor in a liquid film is an important process in LiBr-Water absorption system. The composition of the gas phase, in which a non-absorbable gas is combined with the absorbate, influences the transport characteristics. In the present work, the absorption processes of water vapor into aqueous solutions of lithium bromide in the presence of non-absorbable gas are investigated. The continuity, momentum, energy and diffusion equations for the solution film and gas are formulated in integral forms and solved numerically. It is found that the mass transfer resistance in gas phase increases with the concentration of non-absorbable gas. However the primary resistance to mass transfer is in the liquid phase. As the concentration of non-absorbable gas in the absorbate increases, the interfacial temperature and concentration of absorbate in solution decrease, which results in the reduction of absorption rate. The reduction of mass transfer rate is found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of tube where the non-absorbable gas accumulates. At higher non-absorbable gas concentration, the decrease of absorption rate seems to be linear to the concentration of non-absorbable gas.

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Multichannel Liquid Phase Microextraction System (다채널 액상 미세 추출 시스템 설계 및 제작)

  • Zhang, XinJie;Cheng, Shuo;Piao, Xiang Fan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.10
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    • pp.1-7
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    • 2020
  • In this study, a multichannel gas-liquid microextraction system is designed by integrating the automatic elution of extraction line and multichannel gas-purging liquid phase microextraction. The system uses an injection pump and inert gas to push the extraction solvent to a sample bottle of a gas-phase color autosampler and then implements multichannel gas-liquid microextraction and gas chromatography-mass spectrometry. The system also employs a three-way integrated micro-high-temperature heater, syringe pump, and microflow controller to realize the simultaneous processing of multiple groups of samples, thus improving the sample pretreatment speed and reproducibility and reducing human error. Autoinjection experiments were implemented with polycyclic aromatic hydrocarbon standard samples. The experiments show that the average recovery rate of the system exceeds 70%, and the relative standard among the channels is less than 15%.

The Use of Gas Chromatograph for the Measurement of Engine Exhaust Gas Composition (엔진 배기가스 성분 측정 을 위한 Gas Chromatograph 의 이용)

  • 김승수;정영교
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.6
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    • pp.743-749
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    • 1985
  • In this study the usefulness of Gas Chromatograph for the measurement of engine exhaust gas composition was confirmed. It was found that the composition of standard gas which was used for the calibration of Gas Chromatograph should not be greatly different from that of exhaust gas. Although self-evident, it cannot be overemphasized that utmost attention should be paid to prevent even a minute amount of air being mixed into the gas throughout the sampling process.

Accurate and Robust Computations of Gas-Liquid Two-Phase Flows Part 1: Development of Shock-Stable Two-Phase Schemes (액체-기체 2상 유동장의 정확하고 강건한 해석 Part 1: 충격파 안정적인 2상 유동 수치기법의 개발)

  • Ihm, Seung-Won;Kim, Chong-Am
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.1
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    • pp.1-16
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    • 2009
  • In this paper, we introduce two-phase versions of RoeM and AUSMPW+ schemes. Both schemes are originally developed for the gas dynamic problems, and have shown superior accuracy, efficiency and robustness. A new shock discontinuity sensing term is derived from the mixture equation of state, which is commonly used in the RoeM and AUSMPW+ schemes for the stable numerical flux calculation. The developed two-phase versions of the schemes are applied to several liquid-gas, large property discrepancy two-phase test problems, including several shock stability test problems. The results show that both schemes maintain the merits exhibited in gas dynamic problems even in two-phase flows.

Influence of Ambient Gas Composition on the Microstructure of Plasma Nitrocarburised SCM435 steel (플라즈마 질탄화처리된 SCM435강의 미세조직에 미치는 가스 조성의 영향)

  • Lee, In-Seop
    • Korean Journal of Materials Research
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    • v.12 no.6
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    • pp.427-430
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    • 2002
  • Plasma nitrocarburizing treatment was performed for SCM 435 steel by using a plasma ion nitriding system. The effects of the variation of nitrogen and methan contents upon the hardened layer was investigated. Both the thickness of the compound layer and the amount of $\varepsilon$ phase in the compound layer increased with increasing nitrogen content. However, the thickness of the compound layer decreased due to unstable plasma for an atmosphere containing 90% $N_2$ gas content in the gas mixture. The amount of $\varepsilon$phase in the compound layer increased with increasing $CH_4$ gas content. For $CH_4$ gas content more than 2% in the gas mixture, the thickness of the compound layer decreased due to the formation of $\theta$ phase.

A Statistical Model for Predicting Incipient Point and Quantity of Gas Condensate in Gas Pipelines (가스 배관내 가스 컨덴세이트의 발생 시작점 및 발생량 예측을 위한 통계 모델 연구)

  • Chang, Seung-Yong
    • Journal of the Korean Institute of Gas
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    • v.10 no.4 s.33
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    • pp.1-5
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    • 2006
  • With the rapid increase in gas consumption, the role of pipelines as a transportation means of natural gas is increasing. In general, when natural gas is being transported in pipelines, some liquid mainly from formation of condensate is introduced and this phenomenon makes operational problems more complex in the gas industry. Thus, an appropriate method is necessary for predicting the effect of presence of gas condensate on operational efficiency. In this study, a statistical model was developed using an integrated single- and two-phase flows concept. Using this model, the effects of the incipient point of gas condensate and its quantity on outlet pressure were analyzed. Also, the effect of variations of flow regimes in two-phase region on outlet pressure after the incipient point was analyzed.

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Development of Mixed Hydrogen Gas Generator Power Conversion System (Mixed Hydrogen Gas Generator용 전력변환장치 개발)

  • Jung, Jang-Gun;Mun, Sang-Pil;Cho, Gil-Je;Kim, Chang-Il
    • Proceedings of the KIEE Conference
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    • 2007.11c
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    • pp.88-92
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    • 2007
  • In this paper, the basic experiment, electrolytic cell design and basic manufacturing have been made to interpret the characteristics of Hydrogen-Oxygen-Gas-Generator. As for the detailed matters, the data research on basic technology on Hydrogen-Oxygen-Gas and analysis on characteristics of Hydrogen-Oxygen-Gas from basic experiment. Also the experiment of characteristics and comparative evaluation between constant current source using IGBT converter from existing method and constant current source using new phase shift PWM control method converter. As results when it has injected constant DC current, we has compared Gas quantities by variable ripple frequencies using phase shift PWM control method converter. Therefore, in linear region, it has not different Gas quantities by constant DC current and by phase shift PWM control method converter. Also, it has increased Gas quantities wilder linear region when put ripple frequency at saturation region. Through, Gas quantities and input power, it has acquired higher input power per Gas quantities at put pulse curren. Therefore, when designing converter or inverter for electrolysis, which has ripple current.

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Effect of Heat Transfer and Phase Change of Coolant on the Performance of Mixed-gas Ejection System (냉각제의 분사조건 및 상변화가 혼합가스 사출시스템의 성능에 미치는 영향)

  • Kim, Hyun Muk;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.6
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    • pp.84-93
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    • 2018
  • Three-dimensional (3D) numerical simulations have been carried out to study how coolant injection conditions influence the cooling efficiency and projectile ejection performance in a mixture-gas ejection system (or gas-steam launch system). The 3D single-phase computational model was verified using a 1D model constructed with reference to the previous research and then a two-phase flow computation simulating coolant injection on to hot gas was performed using a DPM (Discrete Phase Model). As a result of varying the coolant flow rate and number of injection holes, cooling efficiency was improved when the number of injection holes were increased. In addition, the change of the coalescence frequency and spatial distribution of coolant droplets caused by the injection condition variation resulted in a change of the droplet diameter, affecting the evaporation rate of coolant. The evaporation was found to be a critical factor in the design optimization of the ejection system by suppressing the pressure drop while the temperature decreases inside the breech.

A Study on Gas Transfer of Viscous Aqueous Solutions in a Bubble Column (기포탑에서 점성수용액의 가스전달에 관한 연구)

  • 최일곤;김상렬
    • Journal of the Korean Society of Safety
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    • v.9 no.3
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    • pp.67-73
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    • 1994
  • The gas holdup and volumeteric liquid phase mass transfer coefficient with the variation of the concentration of CMC aqueous solution, gas velocity, diameter and area of the draught tube were investigated. As the results of the experiments, the gas holdup and volumetric liquid phase mass transfer coefficient decreased with decreasing the concentration of CMC aqueous solution, increased with increasing the gas velocity and increased with increasing the circulated area ratio of the draught tube.

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