• Title/Summary/Keyword: Gas-mixing

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Sensory Evaluation and Electronic Nose Analysis for the Development of Mixed Eucommia ulmoides Leaf Tea (두충혼합차 개발을 위한 관능검사 및 전자코 분석)

  • 정미숙;이미순
    • Korean journal of food and cookery science
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    • v.17 no.4
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    • pp.353-358
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    • 2001
  • The leaves of Duchung(Eucommia ulmoides), an oriental medicinal plant, have a peculiar aroma of Chinese medicine and astringent taste, which make the consumer be reluctant to Duchung leaf tea. Therefore, the purpose of this study was to develop a mild flavored Duchung leaf tea by mixing with other plants. The flavor patterns of developed tea were analyzed using an electronic nose. Polygonatum odoratum and Elsholtzia splendens were used for improving the flavor of Duchung leaf tea. The addition of 20, 30 and 40% of Polygonatum odoratum improved the overall acceptance in hedonic sensory evaluation. The flavor pattern of the tea was described by principal component analysis(PCA) and the resistance ratio(R/cub gas/R$\_$air/) of sensors. The PCA plot was also used to explain the mild flavor of the tea, which was extended from the right side(positive value of the first principal component) to the left side(negative value). Analysis by using an electronic nose with metal oxide sensors could be applied to detect whether mixed Duchung leaf tea was acceptable or not.

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Preparation of Pelletized Porous Adsorbent with Pyrolysis Temperature and Its Toluene Gas Adsorption Characteristics (열분해 조건에 따른 펠렛형 다공성 흡착재의 제조 및 톨루엔 가스 흡착 특성)

  • Kim, Do Young;Kim, Yesol;Cho, Seho;Jung, Jin-Young;Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.587-592
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    • 2013
  • In this study, we prepared pelletized porous carbon adsorbent (PCA) according to the different pyrolysis temperature using activated carbon and polyvinyl alcohol (PVA) as a binder for the removal of toluene, which is one of the representative volatile organic compounds (VOCs). We investigated physical characteristics of PCA using FE-SEM, BET, TGA and evaluated their adsorption capacity for toluene using GC. It was confirmed that the formability of pellets composed of the activated carbon, PVA and solvent of mass mixing ratio was 1 : 0.2 : 0.8 was the most outstanding. Toluene adsorption capacity was evaluated by measuring the maximum time when more than 99% of toluene adsorbed on the pellet. The specific surface area of the adsorbent pyrolyzed at $300^{\circ}C$ was measured as 4.7 times in $941.9m^2/g$ compared to that of the unpyrolyzed pellet. Micropore volume and toluene adsorption capacity of PCA increased fivefold to be 0.30 cc/g and thirteenfold to be 26 hours compared to that of the unpyrolyzed pellet, respectively. These results were attributed to the change of pore size and specific surface area due to the PVA content and the different pyrolysis temperature.

Synthesis of High Purity Multiwalled and Singlewalled Carbon Nanotubes by Arc-discharge

  • Kim, Keun-Soo;Park, Young-Soo;An, Kay-Hyeok;Jeong, Hee-Jin;Kim, Won-Seok;Choi, Young-Chul;Lee, Seung-Mi;Moon, Jeong-Mi;Chung, Dong-Chul;Bae, Dong-Jae;Lim, Seong-Chu;Lee, Young-Seak;Lee, Young-Hee
    • Carbon letters
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    • v.1 no.2
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    • pp.53-59
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    • 2000
  • The synthetic methods for high yield of multiwalled carbon nanotube (MWNT) and singlewalled carbon nanotube (SWNT) with high purity by arc discharge have been investigated. MWNTs were synthesized under different pressures of helium and the gas mixture of argon and hydrogen. Relatively high pressure of 300-400 torr was required for high yield MWNTs synthesis at low bias voltage of about 20 V and 55 A, whereas low pressure of about 100 torr was required for SWNTs. The introduction of hydrogen gases during the synthesis of MWNTs improved the yield and purity of the samples. The SWNTs were synthesized by the assistance of a small amount of mixture of transition metals, which played as a catalyst during the formation process. The purity and yield of SWNTs were higher at a lower pressure and enhanced by mixing more components of the transition metals.

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Effect of Sludge Conditioner on Dewaterability of Sludge Produced from the Anaerobic Digestion of Food Waste (음식물 쓰레기의 혐기성 소화 슬러지의 응집 및 탈수 특성에 미치는 영향)

  • Park, Jong-Bu;Choi, Sung-Su;Park, Seung-Kook;Hur, Hyung-Woo;Han, Seung-Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.3
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    • pp.104-110
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    • 2001
  • In this study, the effect of physico-chemical variables on sludge conditioning was determined to enhance dewaterability of effluent produced from the thermophilic anaerobic digestion of food waste. The gas production rate and methane content during the anaerobic digestion of food waste were $1.1m^3/kg$ VS and 63%, respectively, and the biodegradability of volatile solids was 87.5%. The concentrations of CODcr, TKN and TP of effluent from digestor were 18,500mg/L, 2,800mg/L, and 582mg/L, respectively. At the jar test to screen the flocculant for the dewatering of effluent from digestor, $FeCl_3$ and strong cationic polymer were effective on making flocs in the effluent. The condition of flocculation of effluent were 500mg/L of $FeCl_3$ and 50-100 mg/L of strong cationic polymer, respectively. As the result of measuring of dewaterability potential of effluent to determine the mixing ratio between $FeCl_3$ and polymer by capillary suction time(SCT), optimum condition was 500mg/L of $FeCl_3$ and 80mg/L of strong cationic polymer.

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Study on the Thermal Characteristics of Concrete Using Micro Form Admixture (마이크로기포제를 사용한 콘크리트의 열적 특성에 관한 연구)

  • Park, Young Shin;Kim, Jung Ho;Jeon, Hyun Kyu;Seo, Chee Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.2
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    • pp.101-109
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    • 2013
  • Recently, it is certain that the increase of heating and cooling energy consumption by radical change in climate condition has caused serious problems related to environmental and energy concerns associated with increase of fossil fuel usage and carbon dioxide production as well as global warming. So, various actions to reduce greenhouse gas exhaustion and energy consumption have been prepared by world developed countries. Our government has also been trying to seek energy control methods for houses and buildings by proclaiming political polices on low-carbon green growth and construction and performance standards for environment-friendly housing. The energy consumption by buildings approximately reaches 25% of total korea energy consumption, and the increasing rate of energy consumption by buildings is stiffer than the rate by the other industries. The greatest part in the buildings of the energy consumption is building facade. While lots of research projects for reducing energy consumption of the facade have been conducted, but a few research projects on concrete comprising more than 70% of outsider of buildings has been tried. This research presents here a study to improve the insulation property of structural concrete formed by micro form admixture (MFA) with experimentally reviewing the physical, mechanical and thermal characteristics of the concrete. As the results of this experiment, in the case of concrete mixed with MFA, slump loss has been improved. As the mixing ratio of MFA increases, the compressive strength is decreased and thermal conductivity is increased. Also it was found that water-cement ratio increases, the compressive strength is decreased and thermal conductivity is increased. but, there was not big influence by the change of fine aggregate ratio.

Surface reaction of $HfO_2$ etched in inductively coupled $BCl_3$ plasma ($BCl_3$ 유도결합 플라즈마를 이용하여 식각된 $HfO_2$ 박막의 표면 반응 연구)

  • Kim, Dong-Pyo;Um, Doo-Seunng;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.477-477
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    • 2008
  • For more than three decades, the gate dielectrics in CMOS devices are $SiO_2$ because of its blocking properties of current in insulated gate FET channels. As the dimensions of feature size have been scaled down (width and the thickness is reduced down to 50 urn and 2 urn or less), gate leakage current is increased and reliability of $SiO_2$ is reduced. Many metal oxides such as $TiO_2$, $Ta_2O_4$, $SrTiO_3$, $Al_2O_3$, $HfO_2$ and $ZrO_2$ have been challenged for memory devices. These materials posses relatively high dielectric constant, but $HfO_2$ and $Al_2O_3$ did not provide sufficient advantages over $SiO_2$ or $Si_3N_4$ because of reaction with Si substrate. Recently, $HfO_2$ have been attracted attention because Hf forms the most stable oxide with the highest heat of formation. In addition, Hf can reduce the native oxide layer by creating $HfO_2$. However, new gate oxide candidates must satisfy a standard CMOS process. In order to fabricate high density memories with small feature size, the plasma etch process should be developed by well understanding and optimizing plasma behaviors. Therefore, it is necessary that the etch behavior of $HfO_2$ and plasma parameters are systematically investigated as functions of process parameters including gas mixing ratio, rf power, pressure and temperature to determine the mechanism of plasma induced damage. However, there is few studies on the the etch mechanism and the surface reactions in $BCl_3$ based plasma to etch $HfO_2$ thin films. In this work, the samples of $HfO_2$ were prepared on Si wafer with using atomic layer deposition. In our previous work, the maximum etch rate of $BCl_3$/Ar were obtained 20% $BCl_3$/ 80% Ar. Over 20% $BCl_3$ addition, the etch rate of $HfO_2$ decreased. The etching rate of $HfO_2$ and selectivity of $HfO_2$ to Si were investigated with using in inductively coupled plasma etching system (ICP) and $BCl_3/Cl_2$/Ar plasma. The change of volume densities of radical and atoms were monitored with using optical emission spectroscopy analysis (OES). The variations of components of etched surfaces for $HfO_2$ was investigated with using x-ray photo electron spectroscopy (XPS). In order to investigate the accumulation of etch by products during etch process, the exposed surface of $HfO_2$ in $BCl_3/Cl_2$/Ar plasma was compared with surface of as-doped $HfO_2$ and all the surfaces of samples were examined with field emission scanning electron microscopy and atomic force microscope (AFM).

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A preliminary study of watertightness and salt water resistance of spray-applied membrane (뿜어붙임멤브레인의 방수성능 및 염수저항성의 기초평가)

  • Choi, Soon-Wook;Kang, Tae-Ho;Chang, Soo-Ho;Lee, Cheol-Ho;Kim, Jintae;Choi, Myung-Sik
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.2
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    • pp.283-299
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    • 2017
  • The leakage of tunnel causes the long-term durability of the structures such as concrete lining to deteriorate. The cause of durability degradation can be various substances contained in groundwater such as chloride, sulphate, water, and gas. In this study, a series of test were carried out to determine the watertightness performance and the resistance to salt water of the spray-applied membrane used as non-structural rock support or as a waterproof material for tunnels. As a result, it was found that the penetration of water could occur in a specimen, and the reason was that the internal pores generated by the mixing of the liquid polymer and the powder material and the internal pores were connected by the water pressure. The tensile strength of the test specimens immersed in distilled water and saline water was found to be reduced to less than half of the tensile strength in normal condition. In addition, The elongation was measured to be higher in distilled water than in salt water. However, this result will require further investigation.

Preparation and characterization of Ga-doped TiO2 nanofibers by electrospinning (전기방사를 이용한 Ga이 첨가된 나노섬유의 제작 및 특성평가)

  • Song, Chan-Geun;Kang, Won Ho;Yoon, Jong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.6
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    • pp.274-278
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    • 2012
  • $TiO_2$ can be used optically and is applied on many areas such as gas sensor, solar cell and photocatalysis. Electrospun nanofibers have received great interest for development and utilization in some novel applications, such as chemical sensors, dye-sensitized solar cell and photo catalysis. In this study, pure $TiO_2$ and Ga-doped $TiO_2$ nanofibers synthesized by a modified electrospinning method. The Ga doped $TiO_2$ solution is prepared by mixing poly vinyl pyrrolidone, ethyl alcohol, and titanium (IV) isopropoxide. By electrospinning these sols, nanofibers were fabricated. These fibers are heat-treated at $800^{\circ}C$ in air. The prepared pure $TiO_2$ and Ga-doped $TiO_2$ nanofibers samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy.

A Pilot Study on Emission Analysis of Air Pollutants Produced from Portable Recycling of Asphalt Concrete (간이이동법에 의한 폐아스콘 재생시 대기오염물의 배출분석에 대한 실험적 연구)

  • Lee, Byeong-Kyu;Kim, Haeng-Ah;Jeong, Ui-Ryang;Duong, Trang;Chae, Po-Gi;Park, Kyung-Won
    • Journal of Environmental Science International
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    • v.16 no.3
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    • pp.385-392
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    • 2007
  • Currently, portable equipment for recycling of waste asphalt concrete (ASCON) has been used. However, any air pollution control devices are not attached in the simple portable one. Thus, a lot of air pollutants have been produced from recycling processes of waste ASCON which resulted from aging of paved roads or repavement of roads. This study deals with a preliminary result of concentration analysis of air pollutants obtained from a pilot and a real recycling processes of waste ASCON using simple portable recycling equipment. Air pollutants were taken from 4 steps of the pilot recycling process including an initial heating by liquid petroleum gas (LPG), intermediate heating and melting (H&M) process, final H&M process, and pavement processes using recycled ASCON at the recycling site. Also, air pollutants were taken front 4 steps of the real recycling processes including an initial H&M, final H&M and mixing, loading of recycled ASCON to dump trucks, and at the recycling site after leaving the loaded dump trucks for real pavement sites. The air pollutants measured in this study include volatile organic compounds (VOCs), aldehydes, particulate matter (PM: PM1, PM2.5, PM7, PM10, TSP (total suspended particulate)). The identified concentrations of VOCs increased with increasing time or degree for H&M of waste ASCON. In particular, very high concentrations of the VOCs at the status of complete melting, which is exposed to the air, of the waste ASCON just before paving tv the recycled ASCON at the recycling site. Also, considerable amount of VOCs were identified from the recycling equipment after the dump trucks leaded by recycled ASCON leaved the recycling site for the pavement sites. The relative level of formaldehyde exceeded 80% of the aldehydes Identified in the recycling processes. This is because the waste ASCON is exposed to direct flame of LPG during H&M processes. The PM concentrations measured in the winter recycling processes, such as the loading and rotation processes of waste ASCON into/in the recycling equipment for H&M, were much higher than those in the summer ones. In particular, the concentrations of coarse particles such as PM7 and PM10 during the winter recycling were very high as compared those during the summer one.

Numerical Sudy on Bubbling Fluidized Bed Reactor for Fast Pyrolysis of Waste Lignocelluosic Biomass (폐목질계 바이오매스의 급속열분해 기포유동층 반응기에 대한 수치해석적 연구)

  • Lee, Ji Eun;Choi, Hang Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.10
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    • pp.710-716
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    • 2013
  • New and renewable energy sources have drawn attention because of climate change. Many studies have been carried out in waste-to-energy field. Fast pyrolysis of waste lignocelluosic biomass is one of the waste-to-energy technologies. Bubbling fluidized bed (BFB) reactor is widely used for fast pyrolysis of the biomass. In BFB pyrolyzer, bubble behavior influences on the chemical reaction. Accordingly, in the present study, hydrodynamic characteristics and fast pyrolysis reaction of waste lignocellulosic biomass occurring in a BFB pyrolyzer are scrutinized. The computational fluid dynamics (CFD) simulation of the fast pyrolysis reactor is carried out by using Eulerian-Granular approach. And two-stage semi-global kinetics is applied for modeling the fast pyrolysis reaction of waste lignocellulosic biomass. To summarize, generation and ascendant motion of bubbles in the bed affect particle behavior. Thus biomass particles are well mixed with hot sand and consequent rapid heat transfer occurs from sand to biomass particles. As a result, primary reaction is observed throughout the bed. And reaction rate of tar formation is the highest. Consequently, tar accounts for 66wt.% of the product gas. However, secondary reaction occurs mostly in the freeboard. Therefore, it is considered that bubble behavior and particle motions hardly influences on the secondary reaction.