• 한국생물공학회:학술대회논문집
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• 2001.11a
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• pp.537-540
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• 2001

A parallel TBF system that is consisted of two TBFs was developed f ‘ or the long-term treatment of gas-phase trichloroethylene (TCE). Each TBF was operated for TCE degradation or reactivation in a parallel mode, and the effect of switching time and operation variables between the two reactors was investigated. Within 12 hr after switching from TCE degradation to reactivation mode, the MO activity increased up to the initial level. More than 50 % of TCE was degraded for feed concentrations ranging from 5 to 17 ppmv, and completely 100 % removed at concentration of less than 5 ppmv, while TCE removal decreased severely over 28 ppmv. In various empty bed retention times (EBRTs), ranging 상 om 5.2 to 10.7 min, the optimal EBRT was 10.7 min that TCE conversion achieved more than 50 %. For the inlet loading below 23.4 mg TCE/L/day, TCE was entirely removed. The maximal TCE elimination capacity in this system was about 66.63 mg TCE/L/day. During the continuous treatment of TCE over 3 months, TCE removal efficiency was maintained at the range of about 50 %. In these results, the parallel TBF system can be available for the continuously TCE biodegrading operation.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.1
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• pp.101-112
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• 2003

Biological methods are frequently used for treatment of contaminated air, containing volatile organic compounds and odor compounds in low concentrations and high flow rate of air streams. For more than 20 years. biofilter has been recognized as a cost effective technology for the purification of contaminated air. Most commercial applications before 1990 were for control of odors. In the past decades major progress has been accomplished in the development of vapor phase bioreactor. in particular biotrickling filers. Biotrickling filters are more complex than biofilters. but are usually more effective, especially for the treatment of compounds which are difficult to degrade or compounds that generate acidic by-products. While the level of understanding of biotrickling filtration process for VOCs still remains limited. the evidence success of biotreatment of VOC in air resulted in pursuing active research. This paper presents fundamental and practical aspert of VOCs treatment from air in biotrickling filter. Special emphasis is given to the operating parameters and the factors influencing performance for biotrickling filter.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.4
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• pp.379-388
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• 2006

Two mesophilic trickling bed bioreactors filled with two different types of media, hydrophilic- and hydrophobic-cubes, were designed and conducted for hydrogen production under the anaerobic fermentation of sucrose. Each bioreactor consisted of the column packed with polymeric cubes and inoculated with heat-treated sludge obtained from anaerobic digestion tank. A defined medium containing sucrose was fed by the different hydraulic retention time(HRT), and recycle rate. Hydrogen concentrations in gas-phase were constant, averaging 40% of biogas throughout the operation. Hydrogen production rate was increased till $10.5\;L{\cdot}h^{-1}{\cdot}L^{-1}$ of bioreactor when influent sucrose concentrations and recycle rates were varied. At the same time, the hydrogen production rate with hydrophobic media application was higher than its hydrophilic media application. No methane was detected when the reactor was under a normal operation. The major fermentation by-products in the liquid effluent of the both trickling biofilters were acetate, butyrate and lactate. In order to run in the long term operation of both reactor filled with hydrophilic and hydrophobic media, biofilm accumulation on hydrophilic media and biogas produced should be controlled through some process such as periodical backwashing or gas-purging. Four sample were collected from each reactor on the opposite hydrogen production rate, and their bacterial communities were compared by terminal restriction fragment length polymorphism (T-RFLP) analysis of PCR products generated using bacterial 16s rRNA gene primers (8f and 926r). It was expressed a marked difference in bacterial communities of both reactors. The trickling bed bioreactor with hydrophobic media demonstrates the feasibility of the process to produce hydrogen gas. A likely application of this reactor technology can be hydrogen gas recovery from pre-treatment of high carbohydrate-containing wastewaters.

• KSBB Journal
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• v.16 no.6
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• pp.527-532
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• 2001

Trichlooethylene (TCE) has become a widespread contaminant in air, soil, and underground water due to extensive industrial used and improper disposals. Since TCE is a suspected carcinogen and constitutes public health concerns, many treatment systems have been investigated to remove this hazardous waste. One of the most premising reactor systems for the treatment of TCE is trickling biofilter (TBF), in which monooxygenase (MO), the corresponding enzyme for initiating primary substrate oxidation, fortuitously degrades TCE via cometabolism. TCE, however, is not easily treated by simple TBF. This is mainly due to the toxicities of TCE and its degradation products to microbial film in TBF. In this paper, recent progresses on the development of bioreactor system for the treatment of TCE, especially gas-phase TCE, are reviewed. The potentials of novel biofilm reactor systems were also discussed for the long-term continuous treatment of TCE.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.7
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• pp.820-825
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• 2007

Earthworm casting was the natural fertilizer that contained high concentrations of nutrients such as nitrogen, phosphate and potassium and of over $10^8$ CFU/ml of microorganisms. Greater than 80% of feed was excreted through the fermentation by the intestinal enzyme, after worm had eaten feeds such as fallen leaves and rotten roots under the ground. Also, the soil structure of casting was known to be very efficient in the aspects of the porosity, the water permeability, and deodorizing activities. In this research, the biofilter packed with a biomedia made of casting and waste polyurethane foam, a binder, which helped to improve the durability and perpetuity of casting, was investigated to degrade malodorous hydrogen sulfide gas. The biomedia had no need of extra supply of nutrients and of microbial inoculations. On the beginning of the operations, it showed 100% removal of hydrogen sulfide gas without lag phase. At SV of 50 $h^{-1}$, hydrogen sulfide gas from the outlet of the biofilter was not detected, when inlet concentration increased to 450 ppmv. After that, removal efficiency decreased as increasing inlet hydrogen sulfide concentration. Hydrogen sulfide removal was maintained at almost 93% until inlet concentration was increased up to 950 ppmv, at which the elimination capacity of $H_2S$ was 61.2 g $S{\cdot}m^{-3}{\cdot}h^{-1}$. Maximum elimination capacity guaranteing 90% removal was 61.2, 65.9, 84.7, 89.4 g $S{\cdot}m^{-3}{\cdot}h^{-1}$ at SV ranging from 50 $h^{-1}$ to 300 $h^{-1}$, but was 59.3 g $S{\cdot}m^{-3}{\cdot}h^{-1}$ at SV of 400 $h^{-1}$. The results calculated from Michaelis-Menten equation revealed that $V_m$ increased from 66.04, 88.96, 117.35, 224.15, to 227.54 g $S{\cdot}m^{-3}{\cdot}h^{-1}$ with increasing space velocity in the range of 50 $h^{-1}$ to 400 $h^{-1}$. However, saturation constant$(K_s)$ decreased from 79.97 ppmv to 64.95 and 65.37 ppmv, and then increased to 127.72 and 157.43 ppmv.

• Applied Chemistry for Engineering
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• v.16 no.4
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• pp.474-484
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• 2005

Biological treatment is a promising alternative to conventional air pollution control methods. Bioreactors for air pollution control have found most of their success in the treatment of dilute and high flow waste air streams containing volatile organic compounds and odor compounds. They offer several advantages over traditional technologies such as incineration or adsorption. These include lower treatment costs, absence of formation of secondary pollutants, no spent chemicals, low energy demand and low temperature treatment. The most widely used bioreactor for air pollution control is biofilter, but it has several limitations. In the past years major progress has been accomplished in the development of vapor phase bioreactor, in particular biotrickling filters. Biotrickling filters are more complex than biofilters, but are usually more effective, especially for the treatment of compounds which are difficult to degrade or compounds that generate acidic by-products. While the level of understanding of biotrickling filtration process for VOCs still remains limited, the evident success of biotreatment of VOC in air stimulated the pursue of acitve research. This paper presents fundamental and theoretical/practical aspect of air pollution control in biotrickling filter. Special emphasis is given to the operating parameters and the factors influencing performance for air pollution control in biotrickling filter.