• Title/Summary/Keyword: Gas removal

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Influence of Nickel Electroplating on Hydrogen Chloride Removal of Activated Carbon Fibers

  • Park, Soo-Jin;Jin, Sung-Yeol;Ryu, Seung-Kon
    • Carbon letters
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    • v.5 no.4
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    • pp.186-190
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    • 2004
  • In this work, a nickel metal (Ni) electroplating on the activated carbon fiber (Ni/ACFs) surfaces was carried out to remove the toxic hydrogen chloride (HCl) gas. The surface properties of the treated ACFs were determined by using nitrogen adsorption isotherms at 77 K, SEM, and X-ray diffraction (XRD) measurements. HCl removal efficiency was confirmed by a gas-detecting tube technique. As a result, the nickel metal contents on the ACF surfaces were increased with increasing the plating time. And, it was found that the specific surface area or the micropore volume of the ACFs studied was slightly decreased as increasing the plating time. Whereas, it was revealed that the HCl removal efficiency containing nickel metal showed higher efficiency values than that of untreated ACFs. These results indicated that the presence of nickel metal on the ACF surfaces played an important role in improving the HCl removal over the Ni/ACFs, due to the catalytic reactions between nickel and chlorine.

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Removal of Hydrogen Sulfide and Methylmercaptan Using Thiobacillus in a Three Phase Fluidized Bed Bioreactor

  • KIM, KYUNG-RAN;KWANG-JOONG OH;KYUNG-YONG PARK;DONGUK KIM
    • Journal of Microbiology and Biotechnology
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    • v.9 no.3
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    • pp.265-270
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    • 1999
  • A three phase fluidized bed bioreactor immobilized with Thiobacillus sp. IW was tested to remove hydrogen sulfide and methylmercaptan with high loading rate. In a single gas treatment, the bioreactor removed 92- 98% of hydrogen sulfide with loading rate of 15- 66 g/l/h and removed 87-98% of methylmercaptan with loading rate of 14-60 gl/sup -1/h/sup -1/. In the mixed gas treatment, the removal efficiencies of hydrogen sulfide and methylmercaptan maintained at 89-99% for various inlet loading rates and were not affected by the inlet loading ratio of both gases in low loading rates. When the inlet concentration of methylmercaptan increased 3.8 times and was maintained for 30 h to observe the response of the bioreactor to sudden environmental change, the removal efficiency of methylmercaptan was maintained at an average of 91%.

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Removal of NOx by Pulsed Streamer discharge (펄스 스트리머 방전을 이용한 NOx 제거)

  • 고희석;박재윤;김건호
    • Electrical & Electronic Materials
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    • v.10 no.8
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    • pp.807-811
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    • 1997
  • In this paper we have investigated the removal characteristics of NOx by pulsed corona discharge with a multi-pointplane electrode where a magnetic field is applied in the discharge region. The efficiency of NOx removal was measured and analyzed as a function of pulse frequency gas flow rate NOx initial concentration magnetic flux density. In this result the highest removal efficiency of NOx was obtained at the following operating conditions; the frequency =400[Hz] gas flow =1[$\ell$/min] initial concentration= 400[ppm] and magnetic flux density=0.36[T].

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Efficiency Prediction of the Particle Removal Efficiency of Multi Inner Stage(MIS) Cyclone by Computational Fluid Dynamics(CFD) Analysis and Experimental Verification (CFD 해석을 이용한 Multi Inner Stage Cyclone 내부의 미세입자제거 효율 예측 및 실험적 검증)

  • Kim, Hye-Min;Kwon, Sung-An;Lee, Sang-Jun
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2012.07a
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    • pp.243-246
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    • 2012
  • A new multi inner stage(MIS) cyclone was designed to remove the acidic gas and minute particles of harmful materials produced from electronic industry. To characterize gas flow in MIS cyclone, pressure and velocity distribution were calculated by means of computational fluid dynamics(CFD) commercial program. Also, the flow locus of particles and particle removal efficiency were analyzed by Lagrangian method. When outlet pressure condition was -1,000 Pa, the efficiency was the best in this study. Based on the CFD simulation result, the pressure loss and destruction removal efficiency was measured through MIS cyclone experiment.

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An Experiment on Particle Collection and Gas Removal in a 2-Stage Electrostatic Wet Scrubber (2단 정전식 세정집진기의 집진 및 가스제거 특성)

  • Yeo, Kuk-Hyun;Yoo, Kyung-Hoon;Son, Seung-Woo;Kim, Yoon-Shin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.9
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    • pp.745-752
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    • 2006
  • DOS and NaCl aerosol particles were used to determine collection efficiencies of a 2-stage electrostatic wet scrubber with respect to particle size. The DOS and NaCl aerosols have geometric mean diameters of 0.1-3.0 urn, geometric standard deviations of $1.1{\sim}1.8$ and total number concentrations of $450{\sim}2,400\;particles/cm^3$. The tested operating variables for the electrostatic wet scrubber included air velocity and water injection rate. It was shown from the experimental results that particle collection efficiencies increased in the submicron particle size range when different polarities were applied on the water nozzle and corona wire, respectively. This increase in the collection efficiency is attributed to strong electrostatic attraction between the negative water droplets and positive submicron particles. The collection efficiencies also increased when water injection rate was increased or air velocity was decreased. Meanwhile, the pressure drop across the wet scrubber decreased by 90% compared with the existing mechanical wet scrubber. Finally, ammonia gas was used to determine gas removal efficiencies. It was observed that the gas removal efficiencies increased when the air velocity was decreased or the water injection rate was increased.

Simultaneous Removal Characteristics of NOx, SOx from Combustion Gases using Pulse Corona induced Plasma Chemical Processing (PPCP에 의한 연소가스 중 NOx, SOx 동시제거 특성)

  • Park, Jae-Yoon;Koh, Yong-Sul;Jung, Jang-Gun;Kim, Jung-Dal
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.211-216
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    • 2000
  • In this paper, experimental investigations were carried out to remove NOx, SOx simultaneously from a simulated combustion flue gas [$NO(0.02%)-SO_2(0.08%)-CO_2-Air-N_2$] by using a pulse corona induced plasma chemical processing. Discharge domain of wire-cylindrical plasma reactor was separated from a gas flow duct to avoid unstable discharge by aerosol particle deposited on discharge electrode and grounded electrode. The NOx, SOx removal was experimentally investigated by a reaction induced to ammonium nitrate, ammonium sulfate using a low price of aqueous NaOH solution and a small quantity of ammonia. Volume percentage of aqueous NaOH solution used was 20% and $N_2$ flow rate was $2.5{\ell}/min$ for bubbling aqueous NaOH solution. Ammonia gas(l4.82%) balanced by argon was diluted by air and was introduced to a main simulated flue gas duct through $NH_3$ injection system which was in downstream of reactor. The $NH_3$ molecular ratio(MR) was determined based on [$NH_3$] and [$NO+SO_2$]. MR is 1.5. The NOx removal rates increased in the order of DC, AC and pulse, but SOx removal rates was not significantly effected by source of electricity. The NOx removal rate slightly decreased with increasing initial concentration. but SOx removal rate was not significantly affected by initial concentration. The NOx, SOx removal rates decreased with increasing gas flow rate.

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Removal Characteristics of Ethyl Acetate and 2-Butanol by a Biofilter Packed with Jeju Scoria

  • KAM SANG-KYU;KANG KYUNG-HO;LEE MIN-GYU
    • Journal of Microbiology and Biotechnology
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    • v.15 no.5
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    • pp.977-983
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    • 2005
  • The removal characteristics of ethyl acetate and 2-butanol were investigated in a bench-scale down-flow biofilter packed with Jeju scoria medium. Various inlet concentrations and gas flow rates were tested. The adaptation times of microorganisms to the change of the influent concentration of ethyl acetate and 2-butanol gas were found to be about 3 days. At the inlet concentration of 300 ppmv and empty bed contact time (EBCT) of 15 see, the removal efficiencies of the biofilter for ethyl acetate and 2-butanol were above $99.9\%$. The maximum removal capacity of the biofilter for ethyl acetate was $316-318\;g/m^3/h$ and that for 2-butanol was $245-251\;g/m^3/h$. Overall, the removal capacity of the biofilter for ethyl acetate was $50-70\;g/m^3/h$ larger than that for 2-butanol. During the operation of 65 days, the pressure drop through the biofilter column was maintained below $13\;mmH_{2}O/m$. Although the pH in the drain water decreased from 7.2 to 5.0, the pH drop did not affect the removal of the gases. From the above results, the biofilter using Jeju scoria as a packing material seemed to very effectively treat waste gases such as ethyl acetate and 2-butanol.

Evaporation Rate of Lead in Molten Copper Alloy by Gas Injection (가스취입에 의한 용융 동 합금 중 납의 증발속도)

  • Kim, Hang-Su;Jeong, Seong-Yeop;Jeong, U-Gwang;Yun, Ui-Han;Son, Ho-Sang
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.68-74
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    • 2002
  • The lead has to be removed for the recycling of copper alloy. The lead cannot be removed from the copper alloy by oxidation. It can be removed by the evaporation because of its high vapor pressure. However, rare information is found on removal of lead from copper alloy. The purpose of present work is to provide a fundamental knowledges on the removal of lead from the copper alloy by evaporation. Gas injection was made in molten copper alloy, and the evaporation rate of lead was measured. The influence of Ar gas flow rata(2~4 L/min), initial contents of lead(2~4wt%Pb), temperature(1200~140$0^{\circ}C$) was investigated based on the thermodynamic and the kinetics. The rate constant is increased with increasing flow rate of Ar and temperature. Though amount of lead removed is increased with higher initial lead concentration, the rate constant is not changed significantly. The activation energy is estimated from the temperature dependence of the rate constant. Also removal of lead from the copper by adding chloride was made for the comparison.

A Study on the Mixed-Food Wastewater Treatment in an Anaerobic Packed Bed Reactor and Sludge Bed Reactor (혐기성 고정상반응기와 슬러지 Bed반응기에서 혼합-식품폐수처리에 관한 연구)

  • 안재동;김재우;장인용
    • Journal of Environmental Health Sciences
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    • v.19 no.4
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    • pp.38-43
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    • 1993
  • The characteristics of food wastewater treatment in an anaerobic packed bed reactor (APBR) with polyurethane as a packing material and sludge bed reactor (ASBR) was studied. The reactor of 9cm-ID, 150cm-height was fed in a continuous mode from bottom of reactor. For the purpose of constant temperature of reactor, water jacket was installed. The used packing materials was polyurethane sponge foam. Methane which was produced by decomposed organics collected at the top of the reactor for using as a fuel. The substrates used were synthetic, mixed and food wastewater. For the acclimatization of microorganisms, mixed wastewater was used. The major analyses were gas production, COD, pH and volatile acids. Based upon the completed works, the results are as follows: When food wastewater was fed the quantity of produced gas was less than that of synthetic wastewater, but food process saw higher methane content than synthetic process. As well as COD removal efficiency of food process reached at about 85%. In aspect of effluent volatile acid, food process showed low concentration of below 500 mg/l, therefore anaerobic reaction stabled. Conclusively food wastewater used can be digested by anaerobic treatment, especially anaerobic packed bed reactor showed 82% of COD removal, 75% of methane content, 10 l of gas production, and anaerobic sludge bed reactor did 79% of COD removal, 75% of methane content, 81 of gas production at 4 kgCOD/m$^3$day, 36$\circ$C.

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Annual Greenhouse Gas Removal Estimates of Grassland Soil in Korea

  • Lee, Sang Hack;Park, Hyung Soo;Kim, Young-Jin;Kim, Won Ho;Sung, Jung Jong
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.35 no.3
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    • pp.251-256
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    • 2015
  • The study was conducted to determine greenhouse gas (GHG) inventories in grasslands. After 'Low Carbon Green Growth' was declared a national vision on 2008, Medium-term greenhouse gas reduction was anticipated for 30% reduction compared to Business As Usual (BAU) by 2020. To achieve the reduction targets and prepare to enforce emissions trading (2015), national GHG inventories were measured based on the 1996 Intergovernmental Panel on Climate Change Guidelines (IPCC GL). The national Inventory Report (NIR) of Korea is published every year. Grassland sector measurement was officially added in 2014. GHG removal of grassland soil was measured from 1990 to 2012. Grassland area data of Korea was used for farmland area data in the "Cadastral Statistical Annual Report (1976~2012)". Annual grassland area corresponding to the soil classification was used "Soil classification and commentary in Korea (2011)". Grassland area was divided into 'Grassland remaining Grassland' and 'Land converted to Grassland'. The accumulated variation coefficient was assumed to be the same without time series changes in grassland remaining grassland. Therefore, GHG removal of soil carbon was calculated as zero (0) in grassland remaining grassland. Since the grassland area increases constantly, the grassland soil sinks constantly . However, the land converted to grassland area continued to decrease and GHG removal of soil carbon was reduced. In 2012 (127.35Gg $CO_2$), this removal decreased by 76% compared to 1990 (535.71 Gg $CO_2$). GHG sinks are only grasslands and woodlands. The GHG removaled in grasslands was very small, accounting for 0.2% of the total. However, the study provides value by identifying grasslands as GHG sinks along with forests.