• 대한환경공학회지
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• 제31권9호
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• pp.793-802
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• 2009

매립가스의 자원화를 저해하는 전처리 대상물질 중 하나인 유기규소화합물(실록산)에 대한 흡착제의 제거특성을 확인하기 위하여 실제 매립가스를 대상으로 야자계 활성탄, 석탄계 활성탄, 실리카겔, 탈황제, 슬러지탄화물, molecular sieve 13X의 여섯 가지 상용 흡착제 등을 사용한 흡착실험을 수행하였다. 흡착제별 실록산 제거특성을 확인한 결과, 야자계 활성탄은 흡착된 L2성분의 급격한 유출이 확인되었으나 전체적인 실록산 제거효율과 흡착특성을 고려할 때 가장 우수한 흡착제로 나타났다. 그러나 실록산의 제거효과가 있는 것으로 알려져 있는 실리카겔의 경우에는 매립가스 중 D4와 D5 성분을 효과적으로 제거하였으나 L2성분은 흡착되지 않는 것으로 나타나 일부 실록산 성분의 제거효과만이 확인되었다. 한편, 야자계 활성탄을 직렬배열하였을 때, 처리된 매립가스의 실록산 함유정도와 농도변동의 주요인자인 L2성분을 비롯한 실록산 성분의 안정적인 제거가 가능한 것으로 나타났다. 또한, 실제 매립가스를 구성하고 있는 매우 다양한 성분들의 특성과 상호작용으로 흡착제의 실록산 제거특성에 영향을 미치는 것으로 나타나 효율적인 매립가스 자원화를 위해서는 흡착제와 대상물질 사이의 흡착특성과 함께 매립가스에 포함된 처리대상물질의 배출특성에 따른 전처리가 이루어져야 함을 확인할 수 있었다.

• 유기물자원화
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• 제9권3호
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• pp.70-76
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• 2001

바이오필터를 적절하게 설계하고 처리효율을 향상시키기 위해서는 바이오필터에서의 오염물질에 관한 동력학적 연구가 선행되어야 한다. 본 연구는 가솔린 휘발가스의 바이오필터 처리시 분해특성을 동력학적으로 평가하고자 수행되었다. 바이오필터 충전물질로는 퇴비를 사용하였으며, TPH 가스유입농도는 약 $300mg/m^3$에서 $7,000mg/m^3$로 하였다. 가스유입속도는 6m/hr와 15m/hr로 하였다. 6m/hr의 속도로 가스를 주입할 경우 $3,000mg/m^3$ 이하의 농도에서는 약 60%가 유입부분인 하층 25cm깊이에서 제거되었다. 가솔린 휘발가스의 제거특성은 1차 반응모델로 표현하기에 적합하였다. 농도와 가스유입속도별로 1차 반응속도상수(k)를 비교한 결과 전체적으로 6m/hr에서의 k값이 15m/hr일 때보다 높게 나타났다. $3,000mg/m^3$ 이상의 고농도에서는 6m/hr일 때의 k값(0.09/min)이 15m/hr일 때보다 2배 이상 높았다. 가스유입속도와 유입농도 그리고 1차반응속도상수 등을 검토한 결과 가솔린 휘발가스를 80% 이상제거하기 위해서는 100cm 충전높이에서 농도를 약 $2,000mg/m^3$ 이하로 주입하되 6m/hr의 가스유입속도를 유지시켜 주는 것이 필요하였다. 바이오필터 운전조건 중 가스속도를 통제하는 것이 가스농도를 통제하는 것보다 더 중요하다.

• 한국대기환경학회지
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• 제24권4호
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• pp.455-469
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• 2008

VOCs (Volatile organic compounds) are known as one of the harmful chemicals, causing cancer and global warming. Therefore, the proper control, removal, and reduction of the emission of VOCs are important tasks for the environmental protection. Among the method of VOCs removal activated carbon bed is the most efficient and economical method. In this study, the adsorption performance of toluene gas was investigated using various activated carbons. To find out the adsorption efficiency, the H/D (Height/Diameter) of the activated carbon and GHSV (Gas Hourly Space Velocity) of the toluene gas were manipulated with various conditions. The effect of the temperature, humidity and toluene-MEK-IPA mixed gas on adsorption were also investigated. As a result, a high adsorption performance was found when GHSV is lower at room temperature and low humidity. It was also found that the adsorption efficiency of toluene-MEK-IPA mixed gas system was lower than that of toluene gas system.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 E
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• pp.1806-1808
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• 1998

Tests of pilot-scale plasma DeSOx-DeNOx system using pulsed streamer corona were carried out. The system consists of the reactor with wire-plate electrodes the $30kW_{max}$. MPC type pulse generator, and $1MW_{th}$ pulverized coal combustor as a flue gas source. $NH_3$ and $C_2H_4$ were used to enhance the removal rate. The experimental result on the removal efficiency of SOx/NOx and on the effect of the additives was presented in this paper.

• Nuclear Engineering and Technology
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• 제38권2호
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• pp.129-138
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• 2006

The Gas-cooled Fast Reactor (GFR) is one of the six reactor concepts selected within the framework of the Generation IV initiative and is the reference concept for the Commissariat $\grave{a}$ l'Energie Atomique $(CEA^1)$. Two reactor unit sizes have been considered: 600 MWth and 2400 MWth. As far as thermal-hydraulics is concerned, reactor decay heat removal (DHR) proves to be a major issue. The CEA has conducted exploratory design studies to address this issue and a reference solution for the 600MWth reactor has been recommended.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.457-460
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• 2007

석탄가스화 기술은 석탄을 고온/고압 조건에서 가스화 반응시켜 CO와 $H_2$가 주성분인 합성가스(syngas)로 전환시키는 기술이다. 그러나 가스화 반응으로 인해 합성가스 내에는 불순물인 $H_2S$, COS, $NH_3$ 등의 오염 물질이 발생하게 되며, 가스터빈의 부식, 촉매의 피독, 전극의 성능 저하 현상 등을 일으켜 효율을 저하시키게 된다. 이에 본 연구에서는 FeMgO 촉매를 제거용매로 사용하여 $H_2S$를 효과적으로 제거하기 위하여 Lab-scale 탈황 설비를 제작하였으며, 석탄 가스화 운전에 연계하여 합성가스 내 포함된 산성가스 정제 특성에 관한 연구를 진행하였다.

• 한국안전학회지
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• 제1권1호
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• pp.27-32
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• 1986

To remove sulfur dioxide from flue gas by the method of metal oxide, copper powder of average diameter $2.4\mu\textrm{m}$and $51\mu\textrm{m}$ were used in a fixed bed reactor over a, temperature range of $300^{\circ}C-500^{\circ}C$. Copper oxide reacts with sulfur dioxide producing cupric sulfate and it can be regenerated from the latter by using hydrogen or methane. Experimental results showed that the reaction rate was increased by the increase of reaction temperature in the range of $300^{\circ}C-422^{\circ}C$ and the removal efficiency of sulfur dioxide was high in case of small size copper particle. However the removal efficiency was decreased at higher temperature due to decomposition of cupric sulfate. The rate controlling step of this reaction was chemical reaction and deactivating catalysts model can be applied to this reaction. The rate constants for this reaction and deactivation are as follows ： k＝8,367exp(-10,298/RT) Kd＝2.23exp(-8,485/RT)

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2002년도 생물공학의 동향 (X)
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• pp.423-426
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• 2002

A novel process for $H_2S$ gas treatment has been introduced, based on the combined action of a chemical absorption step and a biological step involving the biocatalytic activity of the bacterium Thiobacillus ferrooxidans. The aim of this study is the development of a process for $H_2S$ elimination from gas streams based on that chemical/biological method. The immobilized biomass reactor/chemical adsorption system is suitable for application of the removal of $H_2S$. A double stage reactor was used for the experimental work. The removal efficiencies of over 99% were observed in the range of inlet $H_2S$ concentration from 200 to 1,000ppm. The novel process showed the stable elimination efficiencies of over 95% under the retention time range from 20 to 40sec at the 1,000ppm of $H_2S$ inlet concentration.

• 한국대기환경학회지
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• 제8권4호
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• pp.262-268
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• 1992

The trend of international concerns on environmental conservation and domestic demand of ambient air quality improvement, specially on sulfur dioxide level has resulted in the establishment of mid-term strategy of environmental improvement and stepwise strengthening of emission regulations in this decade in Korea. Development of flue gas desulfurization(FGD) process is becoming an essential task to be accomplished especially for the power plants and large industrial facilities. This study is an initial stage researc focusing on the mass transfer principles in wet type FGD process and the effects of operating variables of a jet bubbling scrubber utilizing limestone slurry on sulfur dioxide removal efficiency. Experimental results showed this type of scrubbing system has some advantages in terms of mass transfer mechanism and removal efficiency. More rigorous research is needed for the reaction system and the comparison with existing FGD processess for the possible development of a process which is compatative in view of installation cost and treatment of by-products.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 E
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• pp.2308-2310
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• 1999

The effect of magnetic field on NOx removal characteristics from a combustion flue gas has been experimentally investigated for a DC corona discharge reactor with a multipoint plate geometry in our Lab. Combustion flue gas removal efficiency of this type was much higher than that of the other types. In this paper, needle-plate geometry discharge system with applied magnetic field at a right angle to the electric field was made. Input power source was used negative DC. The corona discharge characteristics for this system was investigated and compared with the corona characteristics for the corona discharge system without magnetic field.