• Clean Technology
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• v.23 no.2
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• pp.140-147
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• 2017

In this study, we performed numerical simulation for the catalyst regeneration process of diesel desulfurization reactor. We analyzed the changes in regeneration process according to purge gas flow rate, catalyst permeability, reactor size, and heat loss of reactor. We have found that the regeneration process is very much affected by temperature changes whereas it is hardly affected by catalyst permeability and porosity. We also estimated the regeneration time according to purge gas flow rate and initial temperatures and have found that increasing purge gas temperature is more effect for fast regeneration. The present results can be utilized to design a regeneration process of diesel desulfurization reactor for a fuel cell used in ships. Furthermore, the present work also can be used to design low sulfur diesel supply in oil refineries and therefore contribute to the development of clean petrochemical technology.

• Applied Biological Chemistry
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• v.40 no.2
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• pp.144-147
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• 1997

Different isolation methods for the volatile components of Anise(Pimpinella anisum L.) are compared in terms of the difference of components obtained with each analytical procedure. These methods include headspace(purge & trap) sampling procedure, simultaneous distillation extraction(SDE), steam distillation and solvent extraction. Total 43 components were identified by? comparing gas chromatography retention time and mass spectral data. Different isolation techniques result in compositionally different isolates. The headspace(purge & trap) sampling procedure was found to be the best method of choice for a qualitative analysis of the volatile components.

• Food Science of Animal Resources
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• v.25 no.1
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• pp.78-83
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• 2005

Purge & Trap method was applied to perform more simple and rapid detection for analysis of volatile flavor compounds in milk. Maximal sampling of 30 mL milk for glass flask sparger was treated by He gas purging for 2 hours. Reported major volatile compounds were detected by GC-MS after 2 hours absorption and desorbed from Purge & Trap equipped with Tenax trap. Volatile flavor compounds were analyzed by Purge & Trap and GC-MS to investigate the changes of flavor components in milk between raw and deodorized milk. Fourteen volatile compounds including acetaldehyde, ethanol, 2-propanone, dimethyl sulfide, isobutanal, 3-methyl 2-butanone, 2-butanone, 3-methyl butanal, pentanal, 3-hydroxy-2-butanone, methyl disulfide, hexanal, and 2 others were detected. Six compounds such as ethanol, dimethyl sulfide, pentanal, 3-hydroxy-2-butanone, and methyl disulfide were completely eliminated after deodorization treatment. Four compounds such as 3-methyl 2-butanone, 2-butanone, 3-methyl butanal, and an unknown compound 81 (M/sup +/) were also decreased after raw milk was deodorized. The other four compounds such as acetaldehyde, 2-propanone, hexanal, and an unknown compound (M/sup +/) were not decreased.

• The Korean Journal of Food And Nutrition
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• v.17 no.3
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• pp.260-265
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• 2004

Volatile components of pine needle(Pinus densiflora S.) were isolated by purge & trap headspace technique and analyzed by gas chromatography-mass spectrometry(GC-MS). And then volatile components were extracted for 2 hr and 20 hr at the two different temperature settings: room temperature and 60$^{\circ}C$. A total of 61 volatile components were identified by the four different conditions. These compounds are classified into six categories in terms of chemical functionality: 35 hydrocarbons, 16 alcohols, 4 carbonyls, 2 esters, 1 acid and 3 ethers. The major components were ${\alpha}$-pinene(1.5～15.7%), ${\beta}$-myrcene(13.2～15.6%), ${\beta}$-phellandrene(l2.0～16.0%) and cis-3-hexenol(4.0～18.3%). In the comparison of the four extraction conditions, longer extraction can be effective to extract components that have a high boiling point, but proved useless in obtaining low boiling point components. As a result of these experiments under the four different conditions, the 20 hr extraction at room temperature appeared to be the most optimized condition for the analysis of volatile compounds by using the purge & trap headspace technique.

• Analytical Science and Technology
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• v.10 no.5
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• pp.332-342
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• 1997

Fifteen volatile organic pollutants were spiked in blank water at the concentration of $20{\mu}g/L$ and analyzed with Purge and Trap and GC/MS. As a result, the overall mean recovery of 100% was obtained with a mean relative standard deviation of 3.6%. The method detection limits were in the range of $1.9{\sim}3.3{\mu}g/L$. In the wastewater analysis of Banwol dyeing comlex, 15 organic compounds were identified and three of these were quantified. Among the compounds identified, only trichloroethylene and tetrachloroethylene are regulated in wastewater by the Korea Ministry of Environment. But, the concentration of these two compounds were below the government allowance level.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.2
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• pp.136-147
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• 2015

Dead-ended operation of Proton Exchange Membrane Fuel Cell(PEMFC) provides the simplification of fuel cell systems to reduce fuel consumption and weight of fuel cell. However, the water accumulation within the channel prohibits a uniform supply of fuel. Optimization of the purge strategy is required to increase the fuel cell efficiency since fuel and water are removed during the purge process. In this study, we investigated the average voltage output which depends on two interrelated conditions, namely, the supply gas pressure, purging valve open time. In addition, flow visualization was performed to better understand the water build-up on the anode side and cathode side of PEMFC in terms of a variety of the current density. We analyzed the correlation between the purge condition and water flooding.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.05a
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• pp.135-140
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• 2006

In the experimental study of $N_2$ purge cold flow test of impinging(FOOF) injector for determining of instability region, the whistling sound which has a specific frequency is generated. The frequency of whistling is proportional to the gas flow velocity in part of the oxidizer orifice and due to the coupling of the vibrating gas column and the natural frequency of pipe-orifice shape, the discontinuous jumping phenomena arises. The whistling phenomena have no effect on the combustion instability. Compared the damping factor of 1T1L mode with the hot fire test, the instability region of $N_2$ purge cold flow test is very much like that. It means that flow instability by impinging or mixing of jet is the main reason of combustion instability of impinging injector(FOOF) in the hot firing test.

• 한국가스학회:학술대회논문집
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• 1999.09a
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• pp.179-184
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• 1999

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.74-77
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• 2009

Ignition performance tests were performed to develop a catalytic ignitor which used hydrogen peroxide and kerosene. Ignition characteristics were investigated by exit area of the catalytic bed, shape of kerosene injector and lead time of purge gas. The results showed that exit area of catalytic bed must be enough for non chocking condition and kerosene must be sprayed with swirl in the middle of catalytic bed. Also in case without preheating of catalytic bed, hydrogen peroxide must be leaded by 3sec, and purge gas must be supplied simultaneously or lately with kerosene.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.196.1-196.1
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• 2013

반도체의 device design rule이 shrink 됨에 따라 공정이 난이도가 높아지고 이에 따른 관리가 어려워지고 있다. 특히 미세 particle에 대한 제어의 필요성은 보다 커졌다. 진공 chamber 발생하는 미세 particle의 주요 원인으로는 공정 중 발생한 polymer, chamber 내 부품의 식각 및 스퍼터링에 의한 부산물 등이 있다. Plasma 공정 도중 발생한 particle은 plasma 내 전자에 의해 대전되어 음의 전하량을 가지게 된다. 음의 전하량을 가진 particle은 plasma와 wafer의 경계면에서 형성되는 sheath 때문에 wafer에 도달하지 못하고 plasma 내에 부유하게 된다. 이러한 particle은 plasma가 꺼지게 되면 sheath가 사라지면서 wafer에 도달하게 되고 wafer의 오염을 유발하게 되고 생산 수율을 저하시키는 요인이 된다. 이러한 이유로 최근 plasma 공정에서는 공정 중 발생하는 부유성 particle에 대한 관리가 중요해졌다. 이를 관리하기 위해 plasma를 끄기 전 부유성 particle을 제거하는 방안을 고안하고 평가를 진행하였다. 공정이 끝나고 plasma가 꺼지기 전 plasma를 유지하여 부유성 particle이 wafer에 도달하지 못하는 상태에서 gas purge를 실시한다. 이러한 과정 후 plasma를 끄게 되면 부유성 particle이 wafer에 도달하는 것을 감소시키게 된다. 이번 평가를 통해 부유성 particle에 대해서 대략 20%의 감소 효과를 볼 수 있었다. 이를 토대로 향후 조건 최적화 후 적용 시 particle 감소뿐 만 아니라 수율 향상에도 기여할 수 있을 것이라 기대된다.