• Title/Summary/Keyword: Gas exchange process

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A Study on the Adsorption Characteristics of Nitrogen and Oxygen on Ion Exchanged Zeolite Adsorbents (이온교환된 제올라이트 흡착제의 질소 및 산소 흡착 특성 연구)

  • Jeong, Heon-Do;Kim, Dong-Sik;Kim, Kweon-Ill
    • Applied Chemistry for Engineering
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    • v.16 no.1
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    • pp.123-130
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    • 2005
  • Zeolite X adsorbents with large surface area were prepared for using oxygen PSA adsorbent. Selective adsorption performance of nitrogen on the synthesized zeolite X adsorbent was improved by the cation exchange of adsorbent. The zeolite X which had over $650m^2/g$ surface area was synthesized at the conditions of $SiO_2\;:\;Na_2O\;:\;H_2O\;:\;Al_2O_3$ = 2.5 : 3.5 : 150 : 1 mole ratio, $98^{\circ}C$ temperature and 18 h synthesized time in 50 L reactor. The metal ions Li, Ag, Ca, Br, Sr, etc. were investigated for ion exchange with zeolite X. Ag ion was showed the highest ion exchange rate among these metal ions and all metal ions were exchanged with Na ion at equivalent rate. Compared with the NaX adsorbent, the ion exchanged zeolite X adsorbent remarkably improved its adsorption performance of nitrogen at the conditions of $10{\sim}40^{\circ}C$ temperature and 0~9 atm pressure. At an equilibrium pressure under 0.5 atm, adsorption performance of nitrogen on the ion exchanged zeolite adsorbent increased in the order of Ag > Li > Ca > Sr> Ba > K, whereas at an equilibrium pressure over 1 atm showed in the order of Li > Ag > Ca > Sr > Ba > K. Nitrogen/oxygen separation factor of Li ion exchanged zeolite X adsorbent was 13.023 at the partial pressure of nitrogen/oxygen gas mixture similar to air and $20^{\circ}C$ adsorption temperature.

Stock Investment of Agriculture Companies in the Vietnam Stock Exchange Market: An AHP Integrated with GRA-TOPSIS-MOORA Approaches

  • NGUYEN, Phi-Hung;TSAI, Jung-Fa;KUMAR G, Venkata Ajay;HU, Yi-Chung
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.7
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    • pp.113-121
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    • 2020
  • Multi-criteria stock selection is a critical issue for effective investment since the improper stock investment might cause many problems affecting investors negatively. Investors need a range of financial indicators while they are choosing the optimal set of stocks to invest. This study aims to rank the stock of agriculture companies indexed on the Vietnam Stock Exchange Market. The data of 13 agriculture companies during the 2016-2019 periods was analyzed by analytical hierarchy process (AHP) integrated with grey relational analysis (GRA), multi-objective optimization ratio analysis (MOORA), and technique for order performance by similarity to ideal solution (TOPSIS). The AHP method is employed to determine the weights of the proposed financial ratios, and GRA, TOPSIS, and MOORA approaches are used to obtain final ranking. The results indicated that HSL is the top stock with the highest rank and GRA, MOORA, and TOPSIS rankings have strong correlation values between 0.78-1. The findings suggest that the integrated model could be implemented effectively to specific analysis of industries such as oil and gas, textiles, food, and electronics in future research. Further, other techniques like COPRAS, KEMIRA, and EDAS could be employed to evaluate the financial performance of other companies to solve investment problems.

A Study on Heat Exchange Efficiency of EGR Cooler for Diesel Engine to Meet Euro-5 Emission Regulation (Euro-5 대응 디젤엔진용 EGR 쿨러의 열교환 효율 연구)

  • Lee, Joon;Han, Chang-Suk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.183-188
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    • 2007
  • Recently, diesel engine has been frequently applied to RV, SUV and light duty truck due to the good fuel economy and high thermal efficiency. $NO_x$ and PM, environmental pollution materials are basically produced in diesel combustion process. The most important target in diesel engine research is the development of system to reduce the emissions of $NO_x$ and PM. Cooled EGR system is an effective method for the reduction of $NO_x$ emission and PM emission from a diesel engine and EGR cooler is the key component of the system. This study investigates the EGR cooler of oval gas tubes compared with the EGR cooler of shell & tubes to verify the heat exchange efficiency of cooler by means of engine dynamometer tests, rig performance tests and numerical analyses.

Characteristics of Heat Stable Salts Treatment Using Anion Exchange Resins in CO2 Absorption Process (음이온교환수지를 이용한 CO2 흡수 공정시 발생하는 열안정성염 처리 특성)

  • Park, Kyung-Bin;Cho, Jun-Hyoung;Jeon, Soo-Bin;Lim, You-Young;OH, Kwang-Joong
    • Clean Technology
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    • v.21 no.1
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    • pp.22-32
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    • 2015
  • In this study, we studied the characteristics of ion exchange for treatment of HSS (heat stable salts) which cause performance reduction in CO2 gas capture amine solution using anion exchange resins. The optimum HSS removal efficiency, 96.1% was obtained when using strong base anion exchange resin SAR10 at dosage 0.05 g/mL, 316 K, pH 12 and the best resin regeneration efficiency, 78.8% was obtained using NaOH solution of 3 M at 316 K. The adsorption data were described well by the Freundlich model and the sorption intensity(n) was 2.0951 lying within the range of favorable adsorption. The adsorption selectivity coefficients were increased by increasing valences and size of ion and desorption selectivity coefficients showed a contradictory tendency to adsorption selectivity coefficients. By continuous HSS removal experiments, 13.3 BV of HSS contaminated solution was effectively treated and the optimum NaOH solution consumption was 5.2 BV to regenerate resins.

A Study on the Pressure Variation of Intake Pipe and the Volumetric Efficiency in a Multi-Cylinder Engine (다실린더기관 흡기관내의 압력변동과 체적효율에 관한 연구)

  • 서정일;조진호;김형섭;김병주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.1
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    • pp.179-188
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    • 1990
  • The characteristic of volumetric efficiency considering gas exchange process in a reciprocating engine is presented in this paper. The characteristic method is used for solving gas exchange problems of engine system in theoretical studies. The validity of the simulation is investigated by a comparison with the results obtained by the experiment which have been performed on the practical 4-cycle, 4-cylinder gasoline engine. The relationship between the volumetric efficiency and the intake pressure variation according to configuration of intake pipe, position of branch point, valve timing, compression ratio is clarified through simulation and experiment. The results predicted by the simulation are found to be in approximate agreement with those obtained by the experiment.

A Study on Sensitivity Analysis and Uncertainty Analysis for Continuous Stirred Tank Reactors (연속교반탱크 반응기에 대한 민감도 및 불확실성 분석에 관한 연구)

  • Kim In-Won;Jin Sang-Hwa;Kim In-Tea;Song Hee-Oeul;Yeo Yeong-Koo
    • Journal of the Korean Institute of Gas
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    • v.5 no.4 s.16
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    • pp.70-78
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    • 2001
  • In order to find out which equipment failures were mostly contributed to the rupture of a continuous stirred tank reactor, the sensitivity analysis was carried out. The uncertainty of likelihood of the rupture of reactor was studied by the uncertainty analysis. And the cost effectiveness analysis resulted in the recommendation of the exchange with a better reliable unit if you want to maintain the process efficiently from the view point of cost. The uncertainty analysis showed that the likelihood of catastrophic rupture of the reactor was distributed from $8.09{\times}10^{-04}$ to $5.50{\times}10^{-02}/year$. As a result of cost-effectiveness analysis, it was proposed to exchange the voting logic unit for a better safer system.

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A Study on Synthesis of CaCO3 & MgO/Mg(OH)2 from Dolomite Using the Strong Acidic Cation Exchange Resin (강산성 양이온 교환수지를 통한 백운석으로부터 CaCO3 및 MgO/Mg(OH)2 합성에 관한 연구)

  • Hwang, Dae Ju;Yu, Young Hwan
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.812-825
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    • 2019
  • Two dolomite samples mined from the different mines were calcined using a batch-type microwave kiln ($950/60min^{\circ}C$) to produce $CaO{\cdot}MgO$. The hydration of the $CaO{\cdot}MgO$ samples shows different reactivity. MgO was separated by reacting with a strong acid cation exchange resin using the reactivity of the hydration properties of light dolomite ($CaO{\cdot}MgO$). Calcium ($Ca-(R-SO_3)_2$) was separated from the prepared $CaO{\cdot}MgO$ by the cation exchange resin ($CaO{\cdot}MgO:R-SO_3H=1:12mass%$). High purity MgO (higher than 94 mass %) with unburned $CaCO_3$ (1~2 mass %) was obtained by the separation process. The separated MgO was heated at $950^{\circ}C$ for 60 minutes to afford high purity MgO with MgO content higher than 96%. And High-grade $CaCO_3$ was prepared from the reaction with calcium adsorbed resin ($Ca-(R-SO_3)_2$) and NaOH, $CO_2$ gas.

Characteristics of NOx Reduction on NSR(NOx Storage and Reduction) Catalyst Supported by Ni, Ru-ZSM-5 Additives (Ni, Ru-ZSM-5를 첨가한 NSR 촉매의 NOx 정화 특성)

  • Choi, Byung-Chul;Lee, Choon-Hee;Jeong, Jong-Woo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.105-111
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    • 2007
  • In this study, we investigated the conversion performance of de-NOx catalyst for lean-burn natural gas engine. As a de-NOx catalyst, NOx storage reduction catalyst was composed of Pt, Pd and Rh with washcoat including Ba and Ni, Ru-ZSM-5. Ni, Ru-ZSM-5, which was regarded as a NOx direct decomposition catalyst, was made up of ion exchanged ZSM-5 by 5wt.% Ni or Ru. The performance of de-NOx catalyst was evaluated by NOx storage capacity and catalytic reduction in air/fuel, $\lambda=1.6$. The catalytic reaction was also observed when the added fuel was supplied to fuel rich atmosphere by fuel spike period of 5 seconds. The NOx conversion of the catalysts with Ni-ZSM-5 or Ru-ZSM-5 was mainly caused by the effect of NOx adsorption of Ba rather than the catalytic reduction of Ni, Ru-ZSM-5. Ni, Ru-ZSM-5 catalysts can not use for the NSR catalyst because they have quick process in thermal deactivation.

Lean burn Combustion Characteristics of Direct Injection Gasoline Engine with Swirl Control Valve (스월 제어 밸브를 적용한 직접분사식 가솔린 엔진의 희박연소 특성)

  • Lee, Min-Ho;Moon, Hak-Hoon;Cha, Kyung-Ok
    • Journal of ILASS-Korea
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    • v.9 no.2
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    • pp.9-17
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    • 2004
  • The performance characteristics of lean burn system in gasoline engine are mainly affected by the air-fuel mixture in cylinder, gas exchange process of manifold system, exhaust emission of engine, and the electronic engine control system. In order to obtain the effect of performance factors on the optimum conditions of lean burn engine, this study deal with the behavior of mixture formation, gas flow characteristics of air, flow and evaporation analysis of spray droplet in cylinder, vaporization and burning characteristics of lean mixture in the engine, and the control performance of electronic engine control system. The optimum flow conditions were investigated with the swirl and tumble flows in the combustion chamber with swirl control valve. The performance characteristics and optimum condition of flow field in intake system were analyzed by the investigation of inlet flow of air and combustion stabilization on cylinder.

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Estimation of Fuel Rate on the Galactic Disk from High Velocity Cloud (HVC) Infall

  • Sung, Kwang Hyun;Kwak, Kyujin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.50.2-50.2
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    • 2016
  • Continuous accretion of metal-poor gas can explain the discrepancy between the number of observed G-dwarfs and the number predicted by the "simple model" of galactic evolution. The maximum accretion rate estimated based upon approaching high velocity clouds (HVCs) can be up to ${\sim}0.4M_{\odot}{\cdot}yr^{-1}$ which is comparable with the accretion rate required by many chemical evolution models that is at least ${\sim}0.45M_{\odot}{\cdot}yr^{-1}$. However, it is not clear to what extent the exchange of gas between the disk and the cloud can occur when an HVC collides with the galactic disk. Therefore, we examined a series of HVC-Disk collision simulations using the FLASH 2.5 hydrodynamics simulation code. The outcomes of our simulations show that an HVC will more likely take away substances from the galactic disk rather than adding new material to the disk. We define this as an HVC having a "negative fuel rate". Further results in our study also indicate that the process and amount of fuel rate change can have various forms depending on the density, radius and velocity of an approaching HVC. The simulations in our study covers HVCs with a neutral hydrogen volume density from $1.0{\times}10^{-2}cm^{-3}$ to $41.0cm^{-3}$, radius of 200 pc to 1000 pc and velocity in the range between $40km{\cdot}s^{-1}$ and $100km{\cdot}s^{-1}$.

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