• 제목/요약/키워드: Gas Sampling System

검색결과 119건 처리시간 0.026초

공기 중 휘발성 유기화합물의 측정을 위한 열탈착-분석시스템의 구성 및 평가 (Composition and Evaluation of the Thermal Desorption-Gas Chromatographic System for the Measurement of Volatile Organic Compounds in Air)

  • 이수형;송희남;김희갑
    • Environmental Analysis Health and Toxicology
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    • 제17권1호
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    • pp.63-71
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    • 2002
  • The thermal desorption-gas chromatographic (TD-GC) system has been constructed for the measurement of volatile organic compounds. The thermal desortion unit is composed of four major parts: 1) the control part; 2) the thermal desorption part; 3) the focusing part; and 4) the injection part. The peltier element was introduced to the focusing part for the temperature of the focusing tube to reach-35$^{\circ}C$. The system was tested for the linearity of the calibration curves and reproducibility of instrumental analyses using some disinfection by-products (DBPs) and BTXs (benzene, toluene and p-xylene). The coefficients of determination (r$^2$) for all the calibration curves made were higher than 0.998, and the coefficients of variation (CV) for triplicate measurements were all within 10%. The system also has been tested for field applicability. The analysis of field samples showed that there was no breakthrough problem in the sampling system and that the system could be applied to field measurements.

에틸렌 난류확산 화염에 관한 실험적 연구 (Experimental Study on Turbulent Ethylene Diffusion Flame)

  • 양고수;김용문
    • 한국연소학회지
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    • 제4권2호
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    • pp.23-33
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    • 1999
  • A turbulent non-premixed ethylene flame, which was set up in a vertical wind tunnel, was examined to understand the effect of turbulent mixing on formations of soot and gaseous species in the flames. Temperature and velocity profiles were measured using uncoated thermocouples and LDV system. Gaseous samples were withdrawn by using a water cooled stainless iso-kinetic gas sampling probe. The samples for inorganic compounds and light hydrocarbons were collected with sampling bottles and were analyzed by a gas chromatography. The samples for aromatic hydrocarbons were collected on a sorbent tube and were analyzed on a GC/MS system. Some of main results were followed. CO and $CO_2$ were measured relatively in early part of flame and the concentration of CO was greater than that of $CO_2$ all over the early flame region due to the scavenging of the oxidizing species OH by soot particles. Aromatic hydrocarbons were measured at x/D=122 along the radial direction and main important species were benzene, xylene, toluene, styrene, indene, naphthalene. The peak points of these compounds occurred at r/D=0.8 apart from the center of flame, around in which the concentration of $C_2H_2$ decayed relatively rapidly from the maximum value.

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Modelling and Simulation for PIG Flow Control in Natural Gas Pipeline

  • Nguyen, Tan-Tien;Yoo, Hui-Ryong;Park, Yong-Woo;Kim, Sang-Bong
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2000년도 제15차 학술회의논문집
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    • pp.448-448
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    • 2000
  • This paper deals with dynamic behaviour analysis for pipeline inspection gauge (PIG) flow control in natural gas pipeline. The dynamic behaviour of the PIG is depending on the different Pressure between the rear and nose parts, which is generated by injected gas flow behind PIG's tail and expelled gas flow in front of its nose. To analyze the dynamic behaviour characteristics such as gas flow in pipeline, and the PIG's position and velocity, mathematical model is derived as two types of a nonlinear hyperbolic partial differential equation for unsteady flow analysis of the PIG driving and expelled gas, and nonhomogeneous differential equation for dynamic analysis of PIG. The nonlinear equation is solved by method of characteristics (MOC) with the regular rectangular grid under appropriate initial and boundary conditions. The Runge-Kuta method is used when we solve the steady flow equations to get initial flow values and the dynamic equation of PIG. The gas upstream and downstream of PIG are divided into a number of elements of equal length. The sampling time and distance are chosen under Courant-Friedrich-Lewy (CFL) restriction. The simulation is performed with a pipeline segment in the Korea Gas Corporation (KOGAS) low pressure system, Ueijungboo-Sangye line. The simulation results show us that the derived mathematical model and the proposed computational scheme are effective for estimating the position and velocity of PIG with different operational conditions of pipeline.

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LULUCF 부문 산림 온실가스 인벤토리 구축을 위한 Sampling과 Wall-to-Wall 방법론 비교 (Comparison of Sampling and Wall-to-Wall Methodologies for Reporting the GHG Inventory of the LULUCF Sector in Korea)

  • 박은빈;송철호;함보영;김지원;이종열;최솔이;이우균
    • 한국기후변화학회지
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    • 제9권4호
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    • pp.385-398
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    • 2018
  • Although the importance of developing reliable and systematic GHG inventory has increased, the GIS/RS-based national scale LULUCF (Land Use, Land-Use Change and Forestry) sector analysis is insufficient in the context of the Paris Agreement. In this study, the change in $CO_2$ storage of forest land due to land use change is estimated using two GIS/RS methodologies, Sampling and Wall-to-Wall methods, from 2000 to 2010. Particularly, various imagery with sampling data and land cover maps are used for Sampling and Wall-to-Wall methods, respectively. This land use matrix of these methodologies and the national cadastral statistics are classified by six land-use categories (Forest land, Cropland, Grassland, Wetlands, Settlements, and Other land). The difference of area between the result of Sampling methods and the cadastral statistics decreases as the sample plot distance decreases. However, the difference is not significant under a 2 km sample plot. In the 2000s, the Wall-to-Wall method showed similar results to sampling under a 2 km distance except for the Settlement category. With the Wall-to-Wall method, $CO_2$ storage is higher than that of the Sampling method. Accordingly, the Wall-to-Wall method would be more advantageous than the Sampling method in the presence of sufficient spatial data for GHG inventory assessment. These results can contribute to establish an annual report system of national greenhouse gas inventory in the LULUCF sector.

광산화-활성탄 복합공정에 의한 B.T.X. 분해에 관한 연구 (A Study on the removal of B.T.X by UV Photooxidation-Activated Carbon)

  • 정창훈;배해룡
    • 한국환경과학회지
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    • 제13권1호
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    • pp.41-45
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    • 2004
  • In this study, The decomposition of gas-phase Benzene and Toluene, Xylene in air streams by direct UV Photolysis, UV/TiO$_2$ and UV/TiO$_2$/A.C process was studied. The experiments were carried out under various UV light intensities and initial concentrations of B.T.X to investigate and compare the removal efficiency of the pollutant. B.T.X was determined by GC-FID of gas samples taken from the a glass sampling bulb which was located at reactor inlet and outlet by gas-tight syringe. From this study, the results indicate that UV/TiO$_2$/A.C system (photooxidation-photocatalytic oxidation-adsorption process) is ideal for treatment of B.T.X from the small workplace. Although the results needs more verifications, the methodology seems to be reasonable and can be applied for various workplace (laundry, gas station et al.).

Modeling and Simulation for PIG Flow Control in Natural Gas Pipeline

  • Nguyen, Tan-Tien;Kim, Sang-Bong;Yoo, Hui-Ryong;Park, Yong-Woo
    • Journal of Mechanical Science and Technology
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    • 제15권8호
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    • pp.1165-1173
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    • 2001
  • This paper deals with dynamic analysis of Pipeline Inspection Gauge (PIG) flow control in natural gas pipelines. The dynamic behaviour of PIG depends on the pressure differential generated by injected gas flow behind the tail of the PIG and expelled gas flow in front of its nose. To analyze dynamic behaviour characteristics (e.g. gas flow, the PIG position and velocity) mathematical models are derived. Tow types of nonlinear hyperbolic partial differential equations are developed for unsteady flow analysis of the PIG driving and expelled gas. Also, a non-homogeneous differential equation for dynamic analysis of the PIG is given. The nonlinear equations are solved by method of characteristics (MOC) with a regular rectangular grid under appropriate initial and boundary conditions. Runge-Kutta method is used for solving the steady flow equations to get the initial flow values and for solving the dynamic equation of the PIG. The upstream and downstream regions are divided into a number of elements of equal length. The sampling time and distance are chosen under Courant-Friedrich-Lewy (CFL) restriction. Simulation is performed with a pipeline segment in the Korea gas corporation (KOGAS) low pressure system. Ueijungboo-Sangye line. The simulation results show that the derived mathematical models and the proposed computational scheme are effective for estimating the position and velocity of the PIG with a given operational condition of pipeline.

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시험연소결과에 근거한 플라즈바 아크방식 유리화 시험 설비의 제염성능 평가(I) - 배기가스중의 유해중금속, 방사성핵종 모의물질 및 방사성핵종 제염특성 - (Decontamination Performance Assessment for the Plasma Arc Vitrification pilot plant on the basis of Trial Burn Results(I) - Decontamination Characteristics for Hazardous Metal, Radioactive surrogate and Radioactive Tracer in Off-gas)

  • 채경선;박윤환;민병연;장재옥;박준용;정원익;문병식
    • Journal of Radiation Protection and Research
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    • 제25권2호
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    • pp.99-107
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    • 2000
  • 플라즈마 아크 용융방식 유리화 시험설비의 계통내 기체 및 최종배출구 전단의 배기체를 분석함으로써 배기체중에 포함된 분석용 첨가물의 거동 및 배기가스 처리장치의 제염성능을 평가하였다. 중금속 물질(Pb, Cd, Hg), 방사성 모의물질(Co, Cs) 그리고 방사성핵종($^{60}Co,\;^{137}Cs$)을 분석용 첨가물로 사용한 실험결과로부터 첨가물질의 거동에 따른 유리화 설비 배기체처리시스템의 제염특성 및 제염제수를 구하였다.

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천연가스의 열용량을 측정하기 위한 촉매가스센서의 특징 (Characterization of A Catalystic Gas Sensor for Measuring Heat Content of Natural Gas)

  • 이기용
    • 한국가스학회지
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    • 제2권1호
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    • pp.1-6
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    • 1998
  • 전력을 적재 소모하는 (300 mW 이하) 촉매가스센서가 개발되었고, 천연가스에 열용량을 측정하기 위해 컴퓨터로 작동되는 샘플링 시스템에 사용되었다. 가스의 열용량은 촉매자스센서가 감지되는 연소가스에 노출되었을 때 발생된 에너지에 비례된다. 36.30 - 39.88 $MJ/m^3$ 범위의 정격 열용량을 갖는 천연가스의 열용량은 약 $1\%$ 에러 내에서 측정되었다. 각 가스들은 센서의 온도에 대하여 약간씩 다른 감응곡선을 갖고 있다. 따라서 한 온도에서 모든 감응이 같을 수는 없다. 작동 온도는 측정장치의 전 성능에 영향을 미치기 때문에 교정과정에서 최적의 작동 온도를 찾는 것은 중요하다.

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A New Technique for Burst Cartridge Detection

  • Hyun, Kyung-Ho
    • Nuclear Engineering and Technology
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    • 제1권1호
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    • pp.5-16
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    • 1969
  • 음전극을 가진 구형 가스 채집 전리함을 사용한 가스냉각 발전로 핵연료 피복파열에 관한 검출기술의 새로운 설계에 대한 연구이다. 설계를 위한 이론적인 계산결과에 의하면 이 설계된 시스템은 실지응용이 가능하고 1 $\textrm{cm}^2$ 크기의 핵연료 피복파열을 쉽게 검출할 수 있다는 것이 입증되었다.

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Fluorescence Characteristic Spectra of Domestic Fuel Products through Laser Induced Fluorescence Detection

  • Wu, Ting-Nien;Chang, Shui-Ping;Tsai, Wen-Hsien;Lin, Cian-Yi
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권5호
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    • pp.18-25
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    • 2014
  • Traditional investigation procedures of soil and groundwater contamination are followed by soil gas sampling, soil sampling, groundwater sampling, establishment of monitoring wells, and groundwater monitoring. It often takes several weeks to obtain the analysis reports, and sometimes, it needs supplemental sampling and analysis to delineate the polluted area. Laser induced fluorescence (LIF) system is designed for the detection of free-phase petroleum pollutants, and it is suitable for on-site real-time site investigation when coupling with a direct push testing tool. Petroleum products always contain polycyclic aromatic hydrocarbon (PAH) compounds possessing fluorescence characteristics that make them detectable through LIF detection. In this study, LIF spectroscopy of 5 major fuel products was conducted to establish the databank of LIF fluorescence characteristic spectra, including gasoline, diesel, jet fuel, marine fuel and low-sulfur fuel. Multivariate statistical tools were also applied to distinguish LIF fluorescence characteristic spectra among the mixtures of selected fuel products. This study successfully demonstrated the feasibility of identifying fuel species based on LIF characteristic fluorescence spectra, also LIF seemed to be uncovered its powerful ability of tracing underground petroleum leakages.