• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.9
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• pp.773-778
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• 2001

In this dissertation the results of the combined experimental and theoretical studies designed to understand and predict the spatial growth and transport coefficients for electrons in SF$_{6}$ and SF$_{6}$-Ar mixtures have described. The ionization and attachment coefficients in pure SF$_{6}$ and SF$_{6}$-Ar mixtures have been calculated over the range of 10$_{6}$ molecule and for Ar atom proposed by other authors. The transport coefficients for electrons in (0.2%)SF$_{6}$-Ar and (0.5%)SF$_{6}$-Ar mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained in this work will provide valuable information on the fundamental haviors of electrons in weakly ionized gases and the role of electron attachment in the choice of better gases and unitary gas dielectrics or electro negative components in dielectric gas mixtures. gas mixtures.

• Proceedings of the KIEE Conference
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• 2000.07e
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• pp.17-21
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• 2000

A Study on the electron energy distribution function in $SF_6+Ar$ mixtures gas used by MCS-BE algorithm, the electron swam parameters in the 0.5% and 0.2% $SF_6+Ar$ mixtures are measured by time of flight method over the E/N(Td) range from 30 to 300(Td). A two-term approximation of the Boltzmann equation analysis and Monte Carlo simulation have been also used to study electron transport coefficients. The electron energy distribution function has been analysed in $SF_6$ gas and $SF_6+Ar$ mixtures at E/N : 200(Td) for a case of the equilibrium region in the mean electron energy. The measured results and the calculated results have been compared each other.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.279-283
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• 1998

The electron swarm parameters in the$CF_4$(O.l%, 5%)+Ar mixtures are measured by time of flight method over the E/N(Td) range from 10 to 300LTdl. A two-term approximation of the Boltzmann equation analysis and Monte Carlo simulation have been also used to study electron transport coefficients. We have calculated W, NDL, NDT, $\alpha$ and the limiting breakdown electric field to gas mixtures ratio in pure $CF_4$ gas and$CF_4+Ar$ mixtures. The measured results and the calculated results have been compared each other paper.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.15 no.5
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• pp.20-27
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• 2001

In this paper, the AC breakdown characteristics of pure Ar and $N_2$gas with gas pressure range of 58.8~137.3[kPa] under uniform and non-uniform fields were investigated, and the measured values were compared with those in Ar/$N_2$gas mixtures with pressure varying. Summarizing the experimental results, the breakdown voltages of pure $N_2$gas, under uniform and non-uniform fields, were increased about 4.8 and 1.1 times than those of pure Ar gas, and the AC breakdown voltage increased with the pressure increasing. The breakdown voltages of Ar/$N_2$ gas mixtures were decreased with decreasing the mixture ratio of $N_2$gas. In case of Ar(85%)/$N_2$(15%) and Ar(70%)/$N_2$(30%) gas mixtures comparing to the pure Ar gas, the breakdown voltages under uniform field were increased about 1.5 and 2.1 times, and under non-uniform field were increased about 1.1 and 1.3 times at the pressure of 101.3[kPa]. Also, corona inception voltage of Ar(70%)/$N_2$(30%) gas mixtures under non-uniform field were increased about 1.5 times than those of pure Ar gas.

• The Journal of Engineering Research
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• v.6 no.2
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• pp.85-98
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• 2004

The adsorption equilibrium data for the binary gas mixture system from the pure gas adsorption data of carbon dioxide and ethylene on ZSM-5 prepared were predicted. The binary gas mixture adsorption data have been examined against predicted values by two models-the vacancy solution model(VSM) and the statistical thermodynamic model(STM), using parameters obtained from the single component isotherm. The binary gas mixture data for the carbon dioxide-ethylene system were obtained for cation exchanged forms of ZSM-5 for the gas phase carbon dioxide mole fraction of 0.752 at $37^{\circ}C$ and 1 atm. The experimental adsorption phase diagrams were obtained for carbon dioxide-ethylene on sodium form ZSM-5 synthesized. The single component adsorption isotherms for carbon dioxide and ethylene were also obtained for this zeolite. The single component data were used to obtain parameters derived in two models. These parameters were, in turn, used to predict the binary mixture isotherms for this zeolite. Both the vacancy solution and the statistical thermodynamic models give satisfactory predictions of adsorption phase diagrams for the binary gas mixtures of carbon dioxide and ethylene on sodium exchanged ZSM-5. Also the correlation between the experimental data and the predicted values is generally in good agreement. The system appears to show ideal behavior with a relatively constant separation factor. The slight increase in adsorption capacity with an increase in ionic radius is due, in part, to the higher polarizability associated with larger cations.

• Journal of the Korean Society of Safety
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• v.12 no.3
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• pp.106-113
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• 1997

The thermal characteristics of two binary mixtures by sodium azide/manganese dioxide and ferric oxide, two ternary mixtures by sodium azide/silicon dioxide/manganese dioxide and ferric oxide were studied to obtain the basic data of gas-generating agents for air bags. The thermal reaction for all mixtures started at about $420^{\circ}C$, but the temperature at which the reaction rate reached a maximum was different with the states of samples. According to reaction results, nitrogen, nitrogen oxide and nitrogen dioxide were detected by GC-MS and so many kinds of new chemicals from sodium azide and metal oxide mixtures by XRD. NMS is considered as most stable and reasonable mixture for this types of gas-generating agents.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.2 s.245
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• pp.101-109
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• 2006

The narrow band-averaged transmissivity of $CO_2-H_2O$ mixtures is expressed by multiplying the transmissivities of $CO_2\;and\;H_2O$. Applying the multiplication property of narrow band transmissivities for gas mixtures of $CO_2-H_2O$ of the narrow band based WSGGM (weighted sum of gray gases model), the number of gray gases, required for accurate representation of the absorption characteristics by using the narrow band based WSGGM, is significantly increased. To reduce the computational loads by reducing the number of gray gases, we propose a gray gas regrouping process where the gray gases used for .the WSGGM are regrouped into a specified number of groups according to the magnitudes of absorption coefficients. To evaluate the proposed WSGGM for gas mixtures, the radiative transfer problems through 3-dimensional gas media are considered. The radiative source terms and the radiative heat fluxes obtained by using the proposed method are fairly well compared to previous results obtained by using the SNB model and other models. The regrouping technique results in an excellent computational efficiency with minor loss of accuracy.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.284-289
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• 2003

The narrow band-averaged transmissivity of $CO_2-H_2O$ mixtures is expressed by multiplying the transmissivities of $CO_2$ and $H_2O$. Applying the multiplication property of narrow band transmissivities for gas mixtures of $CO_2-H_2O$, the number of gray gases, required for accurate representation of the absorption characteristics by using the narrow band based WSGGM, is significantly increased. To reduce the computational loads by reducing the number of gray gases, we propose a gray gas regrouping process where the gray gases used for the WSGGM are regrouped into a specified number of groups according to the magnitudes of absorption coefficients. To evaluate the proposed WSGGM for gas mixtures, the radiative transfer problems through three-dimensional gas media are considered. The radiative source terms and the radiative heat fluxes obtained by using the proposed method are fairly well compared to those obtained by using the SNB model. The regrouping technique results in an excellent computational efficiency with minor loss of accuracy.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07b
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• pp.1102-1105
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• 2003

Energy distribution function for electrons in $SF_6$-Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range $30{\sim}300[Td]$ by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2(%) and 0.5(%) $SF_6$-Ar mixtures were measured by time-of-flight(TOF) method, The results show that the deduced electron drift velocities, Electrons Drift Velocities for a rang of E/N values. As a consequence, it was known that the spatial growth rates and the dielectric behaviors in $SF_6$-Ar mixtures are strongly dependent on the addition rate of $SF_6$ gas but the transport coefficients of electrons are insensitive to the addition rate of $SF_6$ gas. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

• Proceedings of the KIEE Conference
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• 2005.10b
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• pp.130-132
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• 2005

This paper presents two ART-based neural networks for the identification of gas mixtures subject to the drift. A fuzzy ARTMAP neural network is used for classifying $H_2S$, $NH_3$ and their mixture gases including a reference gas. The other fuzzy ART neural network is utilized to detect the drift of a tin oxide gas sensor by tracking a cluster center of the reference gas. After detecting the drift, the previous cluster center of each gas is updated as much as the drift of the reference gas. By the simulations, the proposed method is shown to compensate the drift on-line without making many categories of target gases compared with the previous studies.