• Title/Summary/Keyword: Gas Diffusion Medium

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Pore-network Study of Liquid Water Transport through Multiple Gas Diffusion Medium in PEMFCs (고분자 연료전지의 다공성층 내에서의 액상수분 이동에 관한 공극-네트워크 해석 연구)

  • Kang, Jung-Ho;Lee, Sang-Gun;Nam, Jin-Hyun;Kim, Charn-Jung
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.46-53
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    • 2011
  • Water is continuously produced in polymer electrolyte membrane fuel cell (PEMFC), and is transported and exhausted through polymer electrolyte membrane (PEM), catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL). The low operation temperatures of PEMFC lead to the condensation of water, and the condensed water hinders the transport of reactants in porous layers (MPL and GDL). Thus, water flooding is currently one of hot issues that should be solved to achieve higher performance of PEMFC. This research aims to study liquid water transport in porous layers of PEMFC by using pore-network model, while the microscale pore structure and hydrophilic/hydrophobic surface properties of GDL and MPL were fully considered.

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Development of System for Measuring Evaporation Rate through Porous Medium in Fuel Cells (연료전지 다공성막을 통한 수분증발량의 정량적 측정에 관한 실험적 연구)

  • Kim, Jong-Rok;Kim, Moo-Hwan;Son, Sang-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.6
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    • pp.579-582
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    • 2012
  • Removing residual water in a fuel cell is a critical operational process for managing its performance and controlling its lifetime. Understanding the mechanism of water transport in fuel cells is essential for the design of the water removal process. In this study, an experimental method for measuring the water evaporation rate through a gas diffusion layer, which is a porous medium, under steady-state conditions was developed. Experimental bench tests were conducted to apply the developed method. Then, the effects of various parameters of the drying gas and the gas diffusion layer were experimentally measured. The water evaporation rate increased as the humidity of the drying gas decreased and the flow rate of the drying gas increased. In addition, a thinner gas diffusion layer yielded a higher water evaporation rate.

A Inquiry of Tracer Gas for Analysis of Dispersion and Prediction of Infection Possibility according to Airborne Viral Contaminants (건축공간에서 공기 감염균 확산을 해석하기 위한 추적가스 고찰과 농도에 따른 감염 위험성 예측 연구)

  • Lim, Tae-Seob;Kang, Seung-Mo;Kim, Byung-Seon
    • Korean Institute of Interior Design Journal
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    • v.18 no.3
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    • pp.102-113
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    • 2009
  • The SARS virus began to appear and spread in North America and Southeast Asia in the early 2000' s, infecting and harming many people. In the process of examining the causes for the virus, studies on the airborne SARS virus and the way it spread were carried out mainly in the medical field. In the field of architecture, studies were done on the diffusion of air pollutants in buildings using gases such as $CO_2$, $N_2O$, or $SF_6$, but research on virus diffusion was limited. There were also explanations of only the diffusion process without accurate information and discussion on virus characteristics. The aim of this study is to analyze the physical characteristics of airborne virus, consider the possibility of using coupled analysis model and tracer gas for analyzing virus diffusion in building space and, based on reports of how the infection spread in a hospital where SARS patients were discovered, analyze infection risk using tracer gas density and also diffusion patterns according to the location, shape, and volume of supply diffusers and exhaust grilles. This paper can provide standards and logical principles for evaluating various alternatives for making decisions on vertical or horizontal ward placement, air supply and exhaust installation and air volumes in medium or high story medical facilities.

A Study on the Effect of the $CO_2$ Gas on the Growth Mechanism of the Nitrocarburized Layer (연질화층의 성장기구에 미치는 $CO_2$가스의 영향에 관한 연구)

  • Lee, Gu-Hyeon
    • 연구논문집
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    • s.25
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    • pp.175-184
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    • 1995
  • Mechanical properties of the gas nitrocarburized product depend on the surface compound layer and the diffusion zone formed. The compound layer improves the wear resistance, and the corrosion resistance. Though phase composition, pore layer and growth rate of the compound layer varies according to the treatment time, temperature and the kind of the steel substrate, they are strongly influenced by the environmental gas composition. In the current study, the growth behavior of the compound layer and diffusion zone of the carbon steel and the alloy steel upon nitrocarburizing treatment at $570^{\circ}C$, and the phase composition and the variation in the growth rate of the compound layer according to the variation of the gas environment which was the medium of the nitriding and carburizing reaction were investigated.

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Study of the Characteristics of Smoke Spread by an Installing Smoke Barrier in Medium Length Road Tunnel (중규모 도로터널의 제연경계벽 설치에 따른 연기확산특성)

  • Baek, Doo-San;Lee, Seung-Chul
    • Fire Science and Engineering
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    • v.30 no.5
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    • pp.9-17
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    • 2016
  • In the case of a medium length road tunnel, the installation of a smoke control facility is not mandatory so users can suffer considerable injuries if a fire breaks out. Therefore, this study analyzed the high-temperature air and toxic gas generated by fire proliferating with time when a smoke barrier is not installed and when the installation interval is 100, 150, 200, and 250 m through 3-dimensional numerical analysis, evacuation simulation, and Quantitative Risk Assessment Methodology targeting the medium length road tunnel. As a result, the diffusion of the high-temperature air and toxic gas occurring from the a fire was delayed when the smoke barrier was installed in a medium length road tunnel compared to that when it was not installed. In addition, when the installation interval of a smoke barrier was 100m and the numerical analysis target was 100m, the diffusion of high-temperature air and toxic gas generated by the fire was delayed more than in the other cases, which was most suitable for tunnel users to evacuate.

Percolation Approach to the Morphology of Rigid-Flexible Block Copolymer on Gas Permeability

  • 박호범;하성룡;이영무
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.69-70
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    • 1997
  • Polyimides and related polymers, when synthesized from aromatic monomers, have generally rigid chain structures resulting in a low gas permeability. The rigidity of polymer chains reduces the segmental motion of chains and works as a good barrier against gas transport. To overcome the limit of use as materials of gas separation membranes due to low gas permeability, block copolymers with the incorporation of flexible segments like siloxane linkage and ether linkage have been studied. These block copolymers have microphase-separated structures composed of microdomains of flexible poly(dimethylsiloxane) or polyether segments and of rigid polyimides segments. In case of rigid-flexible block copolymers, the characteristics of both phases for gas permeation are of great difference. The permeation of gas molecules occurs favorably through microdomains of flexible segments, whereas those of rigid segments hinder the permeation of gas molecules. Accordingly the increase of content of flexible segments in a rigid polymer matrix will increase the gas permeability of the membrane linearly. However, this prediction does not satisfy enough many experimental results and in particular the drastic increase of the permeability is observed in a certain volume fraction. It was proposed that the gas transport mechanism is dominated by diffusion rather than gas solubility in a certain content of flexible phase if solution-diffusion mechanism is adopted. However, the transition from solubility-dependent to diffusion-dependent cannot be explained by the understanding of mechanism itself. Therefore, we consider an effective chemical path which permeable phase can form in a microheterogenous medium, and percolation concept is introduced to describe the permeability transition at near threshold where for the first time a percolation path occurs. The volume fraction of both phases is defined as V$_{\alpha}$ and V$_{\beta}$ in block copolymers, and the volume of $\beta$ phase in the threshold forming geometrically a traversing channel is defined as V$_{\betac}$. The formation mechanism of shortest chemical channel is schematically depicted in Fig. 1.

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Generation of Microcellular Foams in Viscoelastic Polymer Solutions (점탄성 폴리머 용액에서의 초미세 폼의 생성)

  • Kang, Sung- Lin;Kim, Ki-Young;Kwak, Ho-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.6
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    • pp.726-733
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    • 2004
  • The growth of the critical size bubble by diffusion process in viscoelastic medium was treated by an integral method for the concentration boundary layer adjacent to the bubble wall. In this study, we obtained a set of the first order time dependent equations to obtain bubble radius and gas pressure inside the bubble simultaneously. The calculated final cell sizes depending on the initial saturation pressure are in close agreement with the observed ones. The governing equations developed in this study may be used in polymer processing of microcellular foams.

Generation of Microcellular Foams in Viscoelastic Polymer Solutions (점탄성 폴리머 용액에서의 초미세 폼의 생성)

  • Kang, Sung-Lin;Kim, Ki-Young;Kwak, Ho-Young
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.174-179
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    • 2004
  • The growth of the critical size bubble by diffusion process in viscoelastic medium was treated by an integral method for the concentration boundary layer adjacent to the bubble wall. In this study, we obtained a set of the first order time dependent equations to obtain bubble radius and gas pressure inside the bubble simultaneously. The calculated final cell sizes depending on the initial saturation pressure are in close agreement with the observed ones. The governing equations developed in this study may be used in polymer processing of microcellular foams.

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Analysis of Insulating Characteristics of Cl2-He Mixture Gases in Gas Discharges

  • Tuan, Do Anh
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1734-1737
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    • 2015
  • Insulating characteristics of Cl2-He mixture gases in gas discharges were analysed to evaluate ability of these gases for using in medium voltage and many industries. These are electron transport coefficients, which are the electron drift velocity, density-normalized longitudinal diffusion coefficient, and density-normalized effective ionization coefficient, in Cl2-He mixtures. A two-term approximation of the Boltzmann equation was used to calculate the electron transport coefficients for the first time over a wide range of E/N (ratio of the electric field E to the neutral number density N). The limiting field strength values of E/N, (E/N)lim, for these binary gas mixtures were also derived and compared with those of the pure SF6 gas.

How Supernovae Ejecta Is Transported In A Galaxy: DependenceOn Hydrodynamic Schemes In Numerical Simulations

  • Shin, Eun-jin;Kim, Ji-hoon
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.48.4-48.4
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    • 2019
  • We studied the metal-distribution of isolated Milky-way mass galaxy using various hydrodynamic solvers and investigated the difference of the result between AMR and SPH codes. In particle-based codes, physical quantities like mass or metallicity defined in each particle are conserved unless being injected explicitly by the effect of the supernova, whereas in the Eulerian codes the diffusion is simply accomplished by hydro-equation. Therefore, without including explicit physics of diffusion on the SPH- codes, the metal mixing in the galaxy or CGM only can be accomplished by the direct motion of the particles, however, the standard-SPH codes depress the instability of the turbulent fluid mixing. In this work, we simulated under common initial conditions, common gas-physics like cooling-heating models, and star-formation feedback using ENZO(AMR) GIZMO and GADGET-2 codes. We additionally included a metal-diffusion algorithm on the SPH-codes, which follows the subgrid-turbulent mixing model investigated by Shen et al. (2010) and compared the effect of the metal-outflow on the halo region of the galaxy in different hydro-solvers. We also found that for the implementation of the diffusion scheme in the SPH-codes, the existence of a sufficient number of the gas-particles, which is the carrier of the metals, is necessary. So we tested a new initial condition for proper implementation of the diffusion scheme on the SPH simulations. By comparing the metal-contamination of the circumgalactic medium with different hydrodynamics models, we quantify the diffusion strength of AMR codes using diffusion parameterization of the SPH codes and also suggest the calibration solutions in the different behavior of codes in metal-outflow.

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