• 한국토양환경학회지
• /
• 제3권1호
• /
• pp.3-9
• /
• 1998

본 연구는 휘발성 유기 화합물로 오염된 가솔린 지역에서 soil-gas의 분석결과로부터 오염도를 유추하는 기법에 대하여 서술 하였다. Soil-gas의 채취방법으로는 펌프를 이용한 1)grab sampling법과 흡착제 trap을 사용한 2)passive sampling법이 있다. Grab sampling법은 특정시간에 특정장소에서의 오염도를 보여주며, 반면에 passive sampling법은 특정위치에서 시간에 따른 오염도의 변화를 보여 준다. Soil-gas의 분석은 1)PID나 FID와 같은 작은 검지기에 의해서 총괄 탄화수소량을 측정할수도 있고 2)기체농도에 따라서 색깔이 변하는 지시약이 채워진 기체검지기 튜브를 사용할수도 있으며 3)여러가지 화합물을 한 번에 분석할수 있는 이동형 GC를 사용할수도 있다. Soil-gas를 이용한 측정법은 매우 값싸며 세밀한 정밀조사를 하기 위한 전단계에서 사용할 수 있는 유용한 방법으로 추천할만하다 하겠다.

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 1999년도 추계학술발표회요약집
• /
• pp.334-334
• /
• 1999

• 한국군사과학기술학회지
• /
• 제23권3호
• /
• pp.302-309
• /
• 2020

Early-detection and monitoring of toxic chemical gas cloud with chemical detector is essential for reducing the number of casualties. Conventional method for chemical detection and reconnaissance has the limitation in approaching to chemically contaminated site and prompt understanding for the situation. Stand-off detector can detect and identify the chemical gas at a long distance but it cannot know exact distance and position. Chemical detection UAV is an emerging platform for its high mobility and operation safety. In this study, we have conducted chemical gas cloud detection with the stand-off chemical detector and the chemical detection UAV. DMMP vapor was generated in the area where the cloud can be detected through the field of view(FOV) of stand-off chemical detector. Monitoring the vapor cloud with standoff detector, the chemical detection UAV moved back and forth at the area DMMP vapor being generated to detect the chemical contamination. The hybrid detection system with standoff cloud detection and point detection by chemical sensors with UAV seems to be very efficient as a new concept of chemical detection.

• 한국방사선학회논문지
• /
• 제3권1호
• /
• pp.17-21
• /
• 2009

최근 의료진단 분야와 다른 적용분야를 위해 대면적 매트릭스 구조의 엑스선 영상이 활발하게 연구되어 오고 있다. 본 연구에서는, 의료진단을 위한 새로운 평판형 디지털 엑스선 가스 검출기를 제안하고 그에 따른 특성을 검증하고자 한다. 대기압에 반해 가스를 주입하는 어려움 때문에 챔버 형태의 구조로 만들어 질 뿐, 평판형 디지털 엑스선 가스 검출기는 아직 어디에서도 연구된 바 없다. 이에 본 연구에서는 디스플레이 패널 제작 기술을 이용하여 샘플제작을 성공하였다. 실험적인 측정을 위해 만들어진 샘플은 상판에는 유리기판위에 전극, 절연층, 산화마그네슘 보호막을 형성하였으며, 하판에는 엑스선 형광층과 전극을 형성하였다. 누설전류와 엑스선 민감도를 측정하였으며, 전기장에 대한 민감도의 선형성 측정 등의 전기적 특성평가를 실시하였다. 이에 대한 결과로 안정된 누설전류와 엑스선 민감도를 얻었다. 그리고 조사 선량에 따라 좋은 선형성을 보이는 등 넓은 진단 동적영역을 확인할 수 있었다. 이러한 결과로 평판형 엑스선 가스 검출기의 디지털 엑스선 영상 검출기로의 적용 가능성을 확인 할 수 있었다.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
• /
• pp.199-201
• /
• 2005

This paper describes a simple procedure for the quantitative analysis of 7 PCBs (polychlorinated biphenyls) in soils on the waste reclaimed land, The procedure involved sample clean up using silicagel column, acetonitrile partition and sulfuric acid procedures. The instrumental technique is applied GC/PDD(gas chromatography/pulsed discharge detector) and GC/ECD(gas chromatography/electron capture detector). Concentration of $sub-{\mu}g/g$ level was attainable with 20g soils on the waste reclaimed land.

• 한국자동차공학회논문집
• /
• 제6권1호
• /
• pp.80-89
• /
• 1998

The residual gas in an spark-ignition engine is one of important factors on emissions and performance such as combustion stability. With high residual gas fractions, flame speed and maximum combustion temperature are decreased and these are deeply related with combustion stability especially at idle and NOx emission at relatively high engine load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating parameters. In the present study, the quantitative measurement technique of residual gas fraction was studied by using Fast Response Flame Ionization Detector(FRFID). The measuring technique and model for estimation of residual gas fraction were reported in this paper. By the assuming that the raw signal from FRFID saturates with the same slope for firing and misfiring cycle, in-cylinder hydrocarbon(HC) concentration can be estimated. Residual gas fraction can be obtained from the in-cylinder HC concentration measured at firing and motoring condition. The developed measurement and calibration procedure were applied to the limited engine operating and design condition such as intake manifold pressure and valve overlap. The results show relevant trends by comparing those from previous studies.

• 한국수소및신에너지학회논문집
• /
• 제34권2호
• /
• pp.205-211
• /
• 2023

Hydrogen gas is light and diffuses very quickly. Therefore, when a leakage accident occurs, the damage is great, so a technology that can quickly measure the leakage in the air at a long distance is needed. In order to develop hydrogen gas leaked in the atmosphere in a non-contact manner, an experiment was performed to measure hydrogen gas using a lidar technology using the Raman effect. Hydrogen Raman signals were detected using a UV LED light source, which is a Raman light source, and a spectrometer in the ultraviolet region including an optical filter in the 400-430 nm band. To develop this, a Raman lidar optical structure was designed to measure the hydrogen Raman signal at a certain distance, and the hydrogen Raman spectrum was confirmed using a standard gas to evaluate the performance of this optical structure. The linearity was found to be 0.99 using hydrogen standard gas (10, 50, 100, 500, 1,000 ppm). Accordingly, a Raman lidar capable of measuring hydrogen gas rapidly diffusing in the air in an open state was developed to improve the limitations of existing hydrogen sensors.

• 한국식품과학회지
• /
• 제37권5호
• /
• pp.695-701
• /
• 2005

각각의 황 함유 화합물의 표준곡선을 그렸을 때, linear range의 범위는 $10^2$부터 $10^4$까지의 범위를 보였다. Dimethyl trisulfide가 가장 작은 limit of detection(LOD) 값과 가장 넓은 linear range $(10^4)$를 보이는 반면, methional은 가장 큰 LOD 값과 가장 좁은 linear range$(10^2)$를 가졌다. 각 황 함유 화학물의 분자구조와 PFPD의 황 함유 화합물 분석 원칙에 영향을 받는 것으로 사료된다. 서로 다른 세 종류의 fiber를 사용시, 미세 고체상 추출법(SPME)을 사용했을 때, CAR/PDMS fiber는 가장 좋은 추출 효율을 보였고, 반대로 PDMS/DVB fiber는 가장 낮은 효율을 나타내었다. SPME 방법을 사용하면, 시료에 포함되어 있는 6개의 황 함유 화합물들 중, 최대 5개까지 분석이 가능하였다. 그러나 본 실험에서 사용하지 않은 황 함유 화합물들도 다수 동정 되었는데, 이렇게 추출과정 중 artifacts로 생성된 황 함유 화합물들은 분석 시 오차를 작용할 수 있다. 고정상 기체추출법(SH)은 SPME와 비교했을 때 더 적은 수의 황 함유 화합물을 감지해냈다. SPME와 비교 시 SH의 추출 효율은 낮았지만, artifact로 생성되는 화합물의 수는 적었다.

• Environmental Analysis Health and Toxicology
• /
• 제16권3호
• /
• pp.121-126
• /
• 2001

Analytical method of benzophenone (BP) in sediment and soil was developed by gas chromatography/mass selective detector/selected ion monitoring (GC/MSD/SIM). The ultrasonic extraction of US EPA (method 3550B) method and liquid-liquid extraction for sediment and soil samples were used for the analysis of BP from sediment and soil. BP was extracted with n-hexane. Organic layer was washed with 5% sodium chloride solution. 1∼2 l of the concentrated solution of organic layer was applied to GC/MSD. The retention time of BP peak was 11.10 min. Recovery (％) of BP by ultrasonication from sediment and soil samples was 96.0∼100.6％ and 40.0∼83.0％, respectively. Recovery of BP by liquid-liquid extraction was 51∼59％ in soil samples. The detection limit of BP in sediment and soil samples were determined to 0.1 ng/g.

• KIEE International Transactions on Electrophysics and Applications
• /
• 제5C권2호
• /
• pp.72-75
• /
• 2005

In oil-filled equipment such as transformers, partial discharge or local overheating will precede a final shutdown. Accompanied with such problems is a decomposition of insulating material into gases, which are dissolved into the transformer oil. The gases dissolved in oil can be separated with some membranes based on the differences in permeability of membranes to different gases. This paper discuss the permeability characteristics of several membranes for separation hydrogen gas in oil. With result of this paper, it may become possible to detect fault-related gases from transformer oil and predict incipient failures in the