• Title/Summary/Keyword: Gas Corrosion

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Corrosion Monitoring for Protected Systems using Thin-Film Electrical Resistance (TFER) Sensor

  • Lee, Seong-Min;Li, SeonYeob;Jung, Sung-Won;Kim, YoungGeun;Song, HongSeok;Won, Deok-Soo
    • Corrosion Science and Technology
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    • v.5 no.3
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    • pp.112-116
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    • 2006
  • This study has been conducted to monitor the corrosion rate of cathodically protected structure and corrosion inhibited system using multi-line thin-film electrical resistance (TFER) sensor in various environments. The field test data of TFER sensor for the corrosion monitoring of cathodically protected underground pipeline in soil environments and of corrosion inhibited gas heaters were also presented. The sensor was found to be a powerful method to commit the sensitive pick-up of small corrosion rate which can be observed in the cathodically protected and corrosion inhibited systems.

Corrosion Rate of Buried Pipeline by Alternating Current

  • Song, H.S.;Kim, Y.G.;Lee, S.M.;Kho, Y.T.;Park, Y.S.
    • Corrosion Science and Technology
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    • v.4 no.1
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    • pp.1-7
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    • 2005
  • An alternating current (AC) corrosion on buried pipeline has been studied using coupon and ER probe. Coupons and ER probes were applied to the sites from high value of AC voltage to low value based on the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion (; below -850 mV vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relation could be obtained according to effective AC current density, in which AC corrosion rate increased linearly with effective AC current density, and its slope was 0.619 in coupon method and 0.885 in ER probes.

The effect of shielding gases on the characteristics of super duplex weld metal (슈퍼 듀플렉스 용접부에 미치는 보호가스의 영향)

  • Hong, In-Pyo;Lee, Cheol-Hwan;Kim, Yu-Gi;Kim, Dae-Sun
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.209-211
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    • 2005
  • Super duplex stainless steels have been used for offshore oil and gas piping systems which are subject to corrosion atmosphere, because they have excellent resistance to Stress Corrosion Cracking (SCC) and Pitting corrosion and high strength/weight ratio. Normally, the welding for duplex stainless steels has been peformed using GTAW with Ar shielding gas. However, in case of using Ar as shielding gas, the corrosion resistance at root weld metal will be deteriorated due to loss of nitrogen from weld deposit during welding. It is wellknown that the corrosion resistance of super duplex stainless can be restored by addition of nitrogen as shielding gas. In this study, we made super duplex welding with using several kinds of shielding and purging gases and investigated the relationship between shielding gas and corrosion resistance. Consequently, it was shown that corrosion resistance of weld deposit can be restored by addition of $N_{2}$ as shielding gas.

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Corrosion Assessment by Using Risk-Based Inspection Method for Petrochemical Plant - Practical Experience

  • Choi, Song-Chun;Song, Ki-Hun
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.119-125
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    • 2009
  • Corrosion assessment has a number of uses but the use considered here is as a precursor to Risk-Based Inspection (RBI) planning. Systematic methods consisting of technical modules of RBI program were used to assess the effect of specific corrosion mechanism on the probability of failure in equipments of petrochemical plants. Especially in part of the damage and corrosion assessment, screening step involved evaluating the combinations of process conditions and construction materials for each equipment item in order to determine which damage mechanisms are potentially active. For general internal corrosion, either API 510 or API 570 was applied as the damage rate in the calculation to determine the remaining life and inspection frequency. In some cases, a measured rate of corrosion may not be available. The technical modules of RBI program employ default values for corrosion, typically derived from published data or from experience with similar processes, for use until inspection results are available. This paper describes the case study of corrosion and damage assessment by using RBI methodology in petrochemical plant. Specifically, this paper reports the methodology and the results of its application to the petrochemical units using the $KGS-RBI^{TM}$ program, developed by the Korea Gas Safety Corporation to suit Korean situation in conformity with API 581 Codes.

Effect of the Specific Resistance of Water on Corrosion Characteristics of STS 304 for Gas Boiler (가스보일러용 STS 304의 부식특성에 미치는 용수의 비저항의 영향)

  • Lim, Uh-Joh;Kim, Hwan-Sik;Yun, Byoung-Du
    • Journal of Fisheries and Marine Sciences Education
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    • v.19 no.3
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    • pp.323-328
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    • 2007
  • This paper was studied on the effect of the specific resistance of water on corrosion characteristics of STS 304 for gas boiler. The electrochemical polarization test of STS 304 for gas boiler was carried out. And the polarization resistance, uniform corrosion, corrosion behavior by impressed potential and corrosion sensitivity of STS 304 with specific resistance were considered. The main results are as following: 1) With being low the specific resistance of water, the polarization resistance and corrosion potential of STS 304 decreases, while corrosion current density increases. 2) Under constant impressed potential, the corrosion sensitivity of STS 304 is large with being low the specific resistance due to synergy effect of Cl ion.

Corrosion Rate of Buried Pipeline by Induced Alternating Current (교류가 유도되는 매설배관에서의 교류 부식속도 측정에 관한 연구)

  • Song H. S.;Kim Y. G.;Lee S. M.;Kho Y. T.;Park Y. S.
    • 한국가스학회:학술대회논문집
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    • 2001.10a
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    • pp.45-57
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    • 2001
  • An alternating current (AC) corrosion using coupon has been studied. Coupons were applied in terms of AC voltage from high value to low value through the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion(: below -850mv vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relationship could be obtained statistically, in which AC corrosion rate increased linearly with effective AC current density and its slope was 0.619.

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Development of Corrosion Defect Assessment Method for City Gas Pipeline (도시가스배관 부식결함 평가방안 개발)

  • Kim, Cheol-Man;Kim, Woo-Sik;Han, Sang-In;Choi, Song-Chun
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.228-233
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    • 2004
  • The length of city gas pipeline is increasing with expansion of natural gas transmission rapidly. A lot of the expense was paid for repair and maintenance with increasing of pipeline length and the cost of repair and maintenance by the corrosion was the highest. It is necessary to evaluate integrity in case of thickness reduction by corrosion. There are a lot of assessment criteria for corrosion defect in foreign countries but they are not suitable for application in the country directly. In this work, we performed the burst test and the finite element analysis for city gas pipeline, KS D3507 and KS D3631 for city gas transmission, and developed the assessment method of corrosion defect, which is suitable for domestic condition.

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A Study on the Characteristics of Local Corrosion for Gas Absorption Refrigeration and Hot Water Systems in LiBr-$H_2O$ Working Fluids (LiBr작동유체 중에서 가스흡수식 냉온수기의 국부부식 특성에 관한 연구)

  • Uh- Joh Lim;Ki-Cheol Jeong;Byoung-Du Yun
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.6
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    • pp.714-720
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    • 2003
  • Due to the electric power shortage in summer season and regulation of freon refrigerant, the application of gas absorption refrigeration and hot water systems are considerably increasing trend. But, this system consists of condenser, heat exchanger, supply pipe and radiator etc. which are easily corroded by acidity and dissolved oxygen and gases. In result, this system occurs scale attachment and corrosion damage like pitting and crevice corrosion. In this study, electrochemical polarization test of heat exchanger tubing material (copper, aluminium brass, 30% cupronickel(30% Cu-Ni)) was carried out in 60% lithium bromide solution at $95^{\circ}C$. As a result of polarization test, corrosion behavior by impressed potential and local corrosion. such as galvanic corrosion, pitting corrosion behavior, of tubing materials was investigated. The main results obtained are as follows: (1) The effect of pitting and crevice corrosion control of 30% cupronickel in 60% LiBr solution at $95^{\circ}C$ is very excellent. (2) Dissimilar metal corrosion of 30% cupronickel coupling to aluminium bronze is the most sensitive. (3) Current density behavior of tube materials by impressed potential is high in order of copper > aluminium brass > 30% cupronickel.

On Corrosion Behaviors in Welded Zone of API 5L-X65 Steel for Natural Gas Transmission (천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구)

  • JO SANG-KEUN;SONG HAN-SEOP;KONG Yu-SIK;KIM YOUNG-DAI
    • Journal of Ocean Engineering and Technology
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    • v.18 no.5
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    • pp.50-56
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    • 2004
  • This study is on the constant-current stress corrosion test, related to the load stress, in both the welded and non-welded zones of high tensile strength steel that is used for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed general corrosion and narrow pitting, and the pitting was increased with load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel, used for natural gas transmission specimens, were decreased rapidly, and the average relative electrode potential was higher and the average relative current was lower in welded zone, compared to base metal. The average relative electrode potential was decreased with load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone, compared to base metal, and the corrosion rate was decreased by increasing the load stress.

Effects of Heat Treatment on Corrosion Resistance Properties of Gas Nitrided Stainless Steels (스테인레스강의 가스질화 후 내식특성에 미치는 열처리조건의 영향)

  • Kim, H.G.;Kim, Y.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.5
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    • pp.298-306
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    • 2009
  • Gas nitriding and post oxidation were performed on stainless steels and SACM 645 steel. With increasing gas nitriding time, the increasing rate of nitrided layer was most rapid on SACM 645 steel and the nitriding depth of nitrided layer was most narrow on STS 304 steel among three steels. Corrosion resistance was increased with post oxidation on stainless steels and with increasing time the effect of corrosion resistance was decreased to compare with relatively short gas nitriding time. An improvement effect of corrosion resistance was consisted of predominantly on austenitic stainless steel by post oxidation after gas nitriding among three steels and it was relatively less influenced on martensitic stainless steel.