• Title/Summary/Keyword: Gas Composition

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A Study on the Source Profile of Volatile Organic Compounds from Major Emission Sources (휘발성 유기화합물의 주요 배출원의 배출물질 구성비에 관한 연구-오존 생성 전구물질을 중심으로-)

  • 김소영;한진석;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.3
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    • pp.233-240
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    • 2001
  • The composition of volatile organic compounds (VOCs) was anlyzed for major emission sources such as vehicle exhaust, gasoline and diesel vapor, organic solvent vapor, and butane fuel gas. Low carbon-numbered hydrocarbons were found to be the dominant components of gasoline vehicle exhaust. In gasoline evaporative vapor, the predominant constituents were found to be butane and iso-pentane regardless of ambient air temperature. In case of diesel evaporative vapor was similar to those of gasoline evaporative vapor. The composition of organic solvent vapor from painting, ink and petroleum consisted mostly or aromatic compounds such as toluene and m, p, o-xylene. The hydrocarbon fraction of butane fuel gas. which is used by portable bunner, consisted mainly of propane (34%) and butane(70%).

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A Study on Correlation between A/F and ion signal in a Constant-Volume Chamber Using Spark-plug Ionization Probe Itself (정적챔버에서 스파크 플러그 이온프로브를 이용한 공연비와 이온신호와의 상관관계에 대한 연구)

  • Park, Jong-Il;Chun, Kwang-Min;Hahn, Jae-Won;Park, Chul-Woong
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.223-229
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    • 2002
  • Spark plug ionization signal could be useful in an internal combustion engine as a feedback signal for combustion diagnostics such as misfire detection, knocking detection and lambda control, but the signal has high level of cyclic fluctuation in an internal combustion engine due to residual gas, pressure, temperature, mixture composition in the spark gap. Because of this reason it is very difficult to apply ion signal to commercial engine control. In this Study, a correlation between A/F and spark plug ionization signal was studied in a constant volume chamber. Constant volume chamber with gas phase fuel(Propane) has homogeneous fuel composition , no mixture flow, same pressure and temperature on each test. The results show that mean chemi-ion signal has the highest correlation with A/F and intial pressure change has on effect on the thermal-ion signal and not on chemi-ion signal.

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A Study on Performance and Exhaust Gas Prediction in dedicated CNG Engine (CNG 전소기관의 성능 및 배출가스 예측에 관한 연구)

  • 오용석;김경배;한영출
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.4
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    • pp.178-185
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    • 1998
  • To reduce the particulate matter and nitrogen oxides from diesel engine, many studies are proceeding and being accomplished practically. In this situation CNG engine has important meaning both as a clean fuel and an alternative energy. In order to present the direction and application of CNG, we simulated various operating conditions, that is, spark timing, compression ratio and fuel composition etc. Thus we try to understand how those affect performance and exhaust characteristics. The simulation program results found that the optimum combustion start angle was 21$^{\circ}$ at 1800rpm and fuel composition affects performance and emissions, also we could understand the formation of emission as crank angle is changed.

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Comparative Chemical Composition of Domestic and Imported Chrysanthemum indicum L. Flower Oils

  • Chang, Kyung-Mi;Kim, Gun-Hee
    • Food Science and Biotechnology
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    • v.18 no.5
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    • pp.1288-1292
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    • 2009
  • Volatile flavor compounds were isolated from the flowers of Chrysanthemum indicum L. (gamguk) produced in Korea and China by the hydro distillation, and were analyzed by gas chromatography-mass spectrometry (GC/MS). The yield of oils from Korean and Chinese gamguk were 2.0 and 0.5%(v/w), respectively. Sixty-three volatile compounds of Korean gamguk representing 89.28% of the total peak area were tentatively identified, including 35 hydrocarbons, 12 alcohols, 6 ketones, 3 esters, 5 aldehydes, 1 oxide, and 1 miscellaneous component. Thirty-six volatile components of Chinese gamguk constituted 58.15% of the total volatile composition were tentatively characterized, consisting of 19 hydrocarbons, 7 alcohols, 2 ketones, 2 esters, 4 aldehydes, 1 oxide, and 1 miscellaneous component. The predominant components of Korean oil were ${\alpha}$-pinene, 1,8-cineol, and chrysanthenone. Whereas, camphor, ${\alpha}$-curcumene, and ${\beta}$-sesquiphellandrene were the main aroma compounds of Chinese gamguk.

A Study on the Detonation Characteristics of $C_2H_2$in Shock Tube (충격관을 이용한 $C_2H_2$의 폭굉특성연구)

  • 오규형
    • Journal of the Korean Society of Safety
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    • v.11 no.4
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    • pp.64-71
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    • 1996
  • Detonation phenomena of $C_2H_2$were invesgated using the various shock tube. To study the detonation characteristics according to the composition of $C_2H_2-0_2$$_2$ and $C_2H_2$-air mixtures, the composition were varied from 5 to 90% and 5 to 50% of acetylene each other. A spiral ring was installed in the shock tube to study the effect of obstacles in DDT phenomena. Detonation velocities were measured using the photodiode, and the DDT phenomena was visualized using the high speed schlieren photograph. From the experimental result, it was found that the detonation velocity was most high near the 1. 8times the stoichiometric ratio of acetylene. And from the visualization of DDT phenomena, it was found that the detonation wave was strengthened throuth the pile up of small compression wave of burned gas. And the obstacles in shock tube accelerate the detonation reaction by turblent effect of flammable gas mixture.

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Analysis of Essential Oils from Elscholtzia ciliata and the Production of Essential Oils by Tissue Culture (향유의 정유 분석 및 조직배양)

  • Chi, Hyung-Joon;Shin, Soon-Hee;Chang, Jung-In
    • Korean Journal of Pharmacognosy
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    • v.23 no.2
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    • pp.77-80
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    • 1992
  • The essential oils of Elscholtzia ciliata and the cultivated tissue have been studied. The composition and contents of essential oils were identified by gas chromatography and mass spectrometry. The main component of essential oils of E. ciliata was naginata ketone. The essential oils from the flowers, leaves and stems of E. ciliata showed similar patterns of gas chromatogram. In experimental studies on the tissue culture of callus, it has been found that NAA induced higher growth rate and higher content of essential oils than 2, 4-D. The essential oils from the cultivated callus showed different composition from that of mother plants.

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The Microstructures and Properties of Surface Layer on the Tool Steel Formed by Ion Nitriding -Effects of Process Parameter- (마이크로 펄스 플라즈마 질화에 의해 생성된 금형 공구강의 표면층에 관한 연구 -공정 변수의 영향-)

  • Lee, J.S.;Kim, H.G.;You, Y.Z.
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.1
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    • pp.8-16
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    • 2001
  • The effects of gas composition, pressure, temperature and time on the case thickness, hardness and nitride formation in the surface of tool steels(STD11 and STD61) have been studied by micro-pulse plasma nitriding. External compound layer and internal diffusion layer and the diffusion layer were observed in the nitrided case of tool steels. The relative amounts and kind of phases formed in the nitrided case changed with the change of nitriding conditions. Generally, only nitride phases such as ${\gamma}(Fe_4N)$, ${\varepsilon}(Fe_{2-3}N)$, or $Cr_{1.75}V_{0.25}N_2$ phases were detected in the compound layer, while nitride and carbide phases such as ${\varepsilon}-nitride(Fe_{2-3}N)$, $(Cr,Fe)_{\gamma}C_3$ or $Fe_3C$ were detected in the diffusion layer by XRD analysis. The thickness of compound layer increased with the increase of nitrogen content in the gas composition. Maximum case depth was obtained at gas pressure of 200Pa.

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Process Modeling of IGCC Power Plant using Open-Equation Modeling Framework (개방형 수식모델링 툴을 이용한 IGCC 플랜트 공정모사)

  • Kim, Simoon;Joo, Yongjin;Kim, Miyeong;Lee, Joongwon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.113.1-113.1
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    • 2010
  • IGCC(Integrated Coal Gasification and Combined Cycle) plants can be among the most advanced and environmental systems for electric energy generation from various feed stocks and is becoming more and more popular in new power generation fields. In this work, the performance of IGCC plants employing Shell gasification technology and a GE 7FB gas turbine engine was simulated using IPSEpro open-equation modeling environment for different operating conditions. Performance analyses and comparisons of all operating cases were performed based on the design cases. Discussions were focused on gas composition, syngas production rate and overall performance. The validation of key steady-state performance values calculated from the process models were compared with values from the provided heat and material balances for Shell coal gasification technology. The key values included in the validation included the inlet coal flow rate; the mass flow rate, heating value, and composition of major gas species (CO, H2, CH4, H2O, CO2, H2S, N2, Ar) for the syngas exiting the gasifier island; and the HP and MP steam flows exiting the gasifier island.

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The Investigation of Reaction Parameters on the Reactivity in the Preparation of SiC by SHS (자전연소합성법에 의한 SiC 분말 제조시 반응변수의 영향)

  • Shin, Chang-Yun;Won, Hyung-Il;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.427-432
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    • 2006
  • The preparation of SiC powder by SHS in the system of $SiO_2-Mg-C$ was investigated in this study. The effects of various processing parameters such as the initial pressure of inert gas in reactor, the content of Mg and C in mixture and the size of $SiO_2$ particles on the synthesis of SiC by SHS methode were investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 5 atm, and as the pressure increased, and the concentration of unreacted Mg decreased. At 50 atm of the initial inert gas pressure in reactor, the optimum composition for the preparation of pure SiC was $SiO_2+2.5Mg+1.2C$. SiC powder synthesized in this condition had a mixture of ${\alpha}-SiC\;and\;{\beta}-SiC$ with an irregular shape and the particle size of $0.5{\sim}0.8{\mu}m$.

Study on the Measurement of Emission Spectrum and Reaction Mechanism of OH Radical in the Nitrogen Corona Discharge System for Removal of $NO_x$ in Flue Gas (배연가스의 $NO_x$제거용 코로나 방전장치에서 OH 발광 스펙트럼 측정 및 관련 반응 연구)

  • Park, Chul-Woung;Hahn, Jae-Won;Shin, Dong-Nam
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.27-38
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    • 1999
  • We constructed a wire-cylinder type pulsed corona discharge system for $NO_x$ removal, which was operated in room temperature. A emission spectrometer was built with a boxcar averager and monochrometer equipped with photo-multiplier tube detector. The sensitivity of the emission spectrometer was greatly improved by synchronizing the emission spectrometer with pulsed corona discharge system using a triggered spark-gap switch. $N_2$ spectrum($c^3{\Pi}_u{\rightarrow}X^1{\Sigma}_g{^+}$) was measured in the range of 300 - 450 nm and oxidizing OH radical emission($A^2{\Sigma}^+{\rightarrow}X^2{\Pi}$) was measured in case $N_2$ was supplied with water bubbling. As wet gas composition of inlet $N_2$ supplied in the discharge system increased, the intensity of OH emission was increased and saturated at wet gas composition 50%. We also investigated additive effect of $C_2H_4,\;H_2O,\;H_2O_2$ on the intensity of OR emission and $NO/NO_2/NO_x$ reduction and analysed the related reaction mechanism in corona discharge process. $H_2O_2$ additive increased the intensity of OH emission and $NO/NO_x$ reduction.

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