• Title/Summary/Keyword: Galvanic Current

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An Electrochemical Evaluation on the Corrosion Resistance of a Al Alloy (주조용 Al합금의 내식성에 관한 전기화학적 평가)

  • Youn Dae-Hyun;Lee Myung-Hoon;Kim Ki-Joon;Moon Kyung-Man
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.5
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    • pp.495-501
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    • 2005
  • Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

Glucose Oxidation on Gold-modified Copper Electrode

  • Lim, Ji-Eun;Ahn, Sang Hyun;Pyo, Sung Gyu;Son, Hyungbin;Jang, Jong Hyun;Kim, Soo-Kil
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2685-2690
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    • 2013
  • The activities of Au-modified Cu electrodes toward glucose oxidation are evaluated according to their fabrication conditions and physico-chemical properties. The Au-modified Cu electrodes are fabricated by the galvanic displacement of Au on a Cu substrate and the characteristics of the Au particles are controlled by adjusting the displacement time. From the glucose oxidation tests, it is found that the Au modified Cu has superior activity to the pure Au or Cu film, which is evidenced by the negative shift in the oxidation potential and enhanced current density during the electrochemical oxidation. Though the activity of the Au nanoparticles is a contributing factor, the enhanced activity of the Au-modified Cu electrode is due to the increased oxidation number of Cu through the electron transfer from Cu to more electronegative Au. The depletion of electron in Cu facilitates the oxidation of glucose. The stability of the Au-modified Cu electrode was also studied by chronoamperometry.

The Effects of Transcutaneous Electrical Nerve Stimulation and Microampere Electrical Nerve Stimulation on Sympathetic Tone in Healthy Subjects (경피신경전기자극과 미세전류자극이 정상인의 교감신경 긴장도에 미치는 영향)

  • Park Rae-Joon
    • The Journal of Korean Physical Therapy
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    • v.9 no.1
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    • pp.51-57
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    • 1997
  • The purpose of this study was to determine the effect of two different forms of transcutaneous electrical nerve stimulation(TENS) and one of microcurrent high voltage pulsed galvanic current(HVPC) on sympathetic tone in healthy subjects. Fourty subjects received TENS(20) and PVPC(30) during short time(20min). Left finger tip skin temperatures were measured at four interval for each treatment : 1) before treatment, 2) after 10 minutes treatment, 3)after 20 minutes treatment, and 4) after 10 minutes rest. The results were as follows. 1) TENS treatment group increased skin temperature after treatment 20 minutes, but HVPC treatment increased akin temperature after 10 minutes and recovered normal skin temperature after 10 minutes treatment. It means that short time(20min) electrical stimulation decreased sympathetic activities. 2) Sympathetic activities of TENS stimulation were influenced by age, but HVPC were not. 3) During 10 minutes, both treatment increased sympathetic activities, but HVPC treatment reversed sympathetic activity more rapidly than TENS. 4) The changes of skin temperature means by sex, males in TENS treatment group were higher than females, but HVPC were reverted.

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A Study on the Characteristics of Local Corrosion for Gas Absorption Refrigeration and Hot Water Systems in LiBr-$H_2O$ Working Fluids (LiBr작동유체 중에서 가스흡수식 냉온수기의 국부부식 특성에 관한 연구)

  • Uh- Joh Lim;Ki-Cheol Jeong;Byoung-Du Yun
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.6
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    • pp.714-720
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    • 2003
  • Due to the electric power shortage in summer season and regulation of freon refrigerant, the application of gas absorption refrigeration and hot water systems are considerably increasing trend. But, this system consists of condenser, heat exchanger, supply pipe and radiator etc. which are easily corroded by acidity and dissolved oxygen and gases. In result, this system occurs scale attachment and corrosion damage like pitting and crevice corrosion. In this study, electrochemical polarization test of heat exchanger tubing material (copper, aluminium brass, 30% cupronickel(30% Cu-Ni)) was carried out in 60% lithium bromide solution at $95^{\circ}C$. As a result of polarization test, corrosion behavior by impressed potential and local corrosion. such as galvanic corrosion, pitting corrosion behavior, of tubing materials was investigated. The main results obtained are as follows: (1) The effect of pitting and crevice corrosion control of 30% cupronickel in 60% LiBr solution at $95^{\circ}C$ is very excellent. (2) Dissimilar metal corrosion of 30% cupronickel coupling to aluminium bronze is the most sensitive. (3) Current density behavior of tube materials by impressed potential is high in order of copper > aluminium brass > 30% cupronickel.

A Study on the Practical Cathodic Protection Design for the FRP Fishing Boat and It’s Application Scheme (FRP 어선 2종 스테인리스강 축의 음극방식을 위한 실용설계 및 적용방안 연구)

  • Gang, Dae-Seon;Kim, Gi-Jun;Lee, Myeong-Hun;Park, Jeong-Dae;Kim, Tae-Eon
    • Journal of Korea Ship Safrty Technology Authority
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    • s.21
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    • pp.66-77
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    • 2006
  • Stainless steel has been stably used closed by passivity oxidation films(Cr₂O₃) is made by neutral atmospheric environment. However, passivity oxidaton films of the surface of stainless steel occasionally comes to be destroyed in seawater which is influenced by an environment having galogen ion like Cl‾, then, localization corrosion comes to occur Stainless steel 304 for shaft system material of the small-size FRP fishing boat on seawater environments made an experiment on simulation of sacrifical anode(Al, Zn). Through these experiment and study, following results have been obtained ; According to the field inspection and corrosion simulation, the corrosion on the 2nd class stainless steel shaft(STS304) in FRP fishing boat has been verified to occur by crevice corrosion and galvanic corrosion etc., According to the comparison and analysis of Stainless steel 304 was severely corroded, but, protected shaft specimen was not totallay corroded. This result is assumed to be made by the facts that anodic reaction, Fe → fe²++ 2e¯, has been restricted by the cathodic protection current of sacrificial anode material.

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Correlation between Real-Time and Off-Time Subjective Assessments and Physiological Responses for Visual Picture Stimulus (시각자극에 대한 실시간 및 비 실시간 주관적 평가와 생리반응과의 상관관계)

  • Jeong, Sun-Cheol;Min, Byeong-Chan;Min, Byeong-Un;Kim, Sang-Gyun;O, Ji-Yeong;Kim, Yu-Na;Kim, Cheol-Jung;Park, Se-Jin
    • Journal of the Ergonomics Society of Korea
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    • v.18 no.3
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    • pp.27-39
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    • 1999
  • The purpose of this study was to approve the capability of human sensibility evaluation based on physiological responses and real-time subjective assessments. Three well-trained healthy human subjects were participated in the experiments. We measured physiological responses such as Heart Rate Variability(HRV), Galvanic Skin Response(GSR) and skin temperature under rest and visual stimulation conditions, respectively. Off-time subjective assessments were recorded before and after visual stimulations. Real-time subjective assessments were recorded during visual stimulations. The results of physiological responses and off-time and real-time subjective assessments were quantified and compared. The results showed that the correlation between physiological responses and real-time subjective assessments was high (83%) for both the positive and negative visual stimulation. The correlation between the physiological responses and off-time subjective assessments was high (83%) for the negative visual stimulation but was low (15%) for the positive visual stimulation. Although the current observation is preliminary and requires more careful experimental study, it appears that the correlation between real-time subjective assessment and physiological responses is higher than that of the off-time subjective assessment and physiological responses.

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Bidirectional Power Conversion of Isolated Switched-Capacitor Topology for Photovoltaic Differential Power Processors

  • Kim, Hyun-Woo;Park, Joung-Hu;Jeon, Hee-Jong
    • Journal of Power Electronics
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    • v.16 no.5
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    • pp.1629-1638
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    • 2016
  • Differential power processing (DPP) systems are among the most effective architectures for photovoltaic (PV) power systems because they are highly efficient as a result of their distributed local maximum power point tracking ability, which allows the fractional processing of the total generated power. However, DPP systems require a high-efficiency, high step-up/down bidirectional converter with broad operating ranges and galvanic isolation. This study proposes a single, magnetic, high-efficiency, high step-up/down bidirectional DC-DC converter. The proposed converter is composed of a bidirectional flyback and a bidirectional isolated switched-capacitor cell, which are competitively cheap. The output terminals of the flyback converter and switched-capacitor cell are connected in series to obtain the voltage step-up. In the reverse power flow, the converter reciprocally operates with high efficiency across a broad operating range because it uses hard switching instead of soft switching. The proposed topology achieves a genuine on-off interleaved energy transfer at the transformer core and windings, thus providing an excellent utilization ratio. The dynamic characteristics of the converter are analyzed for the controller design. Finally, a 240 W hardware prototype is constructed to demonstrate the operation of the bidirectional converter under a current feedback control loop. To improve the efficiency of a PV system, the maximum power point tracking method is applied to the proposed converter.

A Study on Characteristics of the Electrochemical Corrosion of Weld Zone for Refrigerating and Heating Systems Pipe (냉난방용 배관 용접부의 전기화학적 부식특성에 관한 연구)

  • Lim, Uh-Joh;Yun, Byoung-Du;Kim, Hwan-Sik
    • Journal of Fisheries and Marine Sciences Education
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    • v.19 no.1
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    • pp.84-90
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    • 2007
  • This paper was studied on the electrochemical corrosion characteristics of weld zone for refrigerating and heating systems pipe. Austenitic stainless steel is widely applied to various fields of industry, because it is good to corrosion resistance and mechanical properties. But STS 304 is reliable to sensitization by heat cycle on welding. Therefore, in this study, electrochemical polarization test of STS 304 steel pipe manufactured by arc welding in tap water was carried out. And then polarization resistance behavior, uniform and local corrosion behaviors of base metal(BM), weld metal(WM) and heat affected zone(HAZ) for STS 304 pipe were investigated. The corrosion current density of STS 304 steel pipe is high in order of BM(153nA/cm2) < WM(614nA/cm2) < HAZ ($1.675{\mu}A/cm2$). The pitting potential of HAZ(238mV/SCE) for STS 304 is lower than BM(1206mV/SCE) and WM(369mV/SCE). Therefore, the local corrosion like pitting corrosion, galvanic corrosion and crevice corrosion of HAZ for STS 304 is more sensitive than BM and WM.

Corrosion analysis of the duplex aluminum alloys (듀플렉스 알루미늄 합금의 내식성 분석)

  • Choi, In Kyu;Kim, Si Myeong;Kim, Sang Ho
    • Journal of the Korean institute of surface engineering
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    • v.48 no.5
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    • pp.227-232
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    • 2015
  • Corrosion characteristic of the duplex Al-Mg-Si alloys with low, commercial and high solute contents were studied using an anodic polarization test in 1M NaCl solution at room temperature. Polarization range condition of the experiment were form .0.3V to .1.3V with a 0.2 mV scanning speed. The exchange current density means corrosion rate of the low solute alloy was low as about $16.29{\mu}A/cm^2$, and that of the high solute alloy was high as $84.92{\mu}A/cm^2$. The difference was mainly attributed to the inter-granular precipitates $Mg_2Si$ and Si which could make a galvanic corrosion on the aluminum base. The amount of precipitates was greater in high solute alloy at mainly in grain boundary. While, the extruded alloys had better corrosion resistance than the cast alloy because the silicon precipitates become coarse during the extrusion process.

Corrosion Behavior of Bimetal Materials (Fe-Ni / Fe-Ni-Mo) for Electromagnetic Switches (전자 개폐기용 바이메탈 소재(Fe-Ni / Fe-Ni-Mo)의 부식거동)

  • Yu-Jeong An;Eun-Hye Hwang;Jae-Yeol Jeon;Sung Jin Kim
    • Corrosion Science and Technology
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    • v.22 no.6
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    • pp.478-483
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    • 2023
  • This study examined the corrosion behavior of bimetal materials composed of Fe-Ni alloy and Fe-Ni-Mo alloy, both suitable for use in electromagnetic switches. Electrochemical polarization and weight loss measurements revealed that, in contrast to Fe-Ni alloy, which exhibited pseudo-passivity behavior, Fe-Ni-Mo alloy had higher anodic current density, displaying only active dissolution and greater weight loss. This indicated a lower corrosion resistance in the Fe-Ni-Mo alloy. Equilibrium calculations for the phase fraction of precipitates suggested that the addition of 1 wt% Mo may lead to the formation of second-phase precipitates, such as Laves and M6C, in the γ matrix. These precipitates might degrade the homogeneity of the passive film formed on the surface, leading to localized attacks during the corrosion process. Therefore, considering the differences in corrosion kinetics between these bimetal materials, the early degradation caused by galvanic corrosion should be prevented by designing a new alloy, optimizing heat treatment, or implementing periodic in-service maintenance.