• Title/Summary/Keyword: Galvanic

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Corrosion Behavior Analysis of the Weld Joint between Stainless Steel and Carbon Steel (스테인리스강과 탄소강 용접부의 부식거동 해석)

  • 권재도;이우호;김길수;장순식;진영준
    • Journal of Welding and Joining
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    • v.17 no.3
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    • pp.66-70
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    • 1999
  • In order to investigate the quantitative behavior of galvanic corrosion in weld joints between stainless std이 and carbon steel, electrochemical polarization experiments were performed at pH4, pH7 and pH10 with boric acid concentration 4000ppm, and water temperature were selected as $35^{\circ}$C and $60^{\circ}$C. As the results, the galvanic corrosion phenomena of carbon steel weld material at $60^{\circ}$C was revealed $2{1\over2}$ times higher corrosion rate than that at $35^{\circ}$C condition. The corrosion rate of stainless steel was almost inedependent of the variation of pH. The significant corrosion rates of carbon steel and the weld joint of carbon-carbon steel were observed at pH 4.

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Surface-Enhanced Raman Scattering of Benzenethiol Adsorbed on Silver-Exchanged Copper Powders

  • Shin, Kuan-Soo;Ryoo, Hyun-Woo;Lee, Yoon-Mi;Kim, Kwan
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.445-449
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    • 2008
  • Micrometer-sized copper (mCu) powders are weakly surface-enhanced Raman scattering (SERS) active by the excitation at 632.8 nm, but nearly ineffective as a SERS substrate at 514.5 nm excitation. The SERS activity of mCu powders at both excitation wavelengths can be increased dramatically by a simple method of the galvanic exchange reaction with AgNO3 in aqueous medium. In this work, the SERS activity of the Ag-exchanged Cu powders (mCu@Ag) has been evaluated by taking a series of Raman spectra using benzenethiol (BT) as the probe molecule. It is clearly confirmed by field emission scanning electron microscopy and X-ray diffractometry that the SERS activity of mCu@Ag powders is, in fact, highly dependent on the extent of galvanic reaction.

The Development of the Low Power Consumption and Long Life Battery using a Galvanic Series (저전력형 반영구적인 갈바니 전원장치 개발)

  • Bae, Jeong-Hyo;Kim, Dae-Kyeong;Ha, Tae-Hyun;Lee, Hyun-Goo;Choi, Sang-Bong;Jeong, Seong-Hwan
    • Proceedings of the KIEE Conference
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    • 2000.07d
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    • pp.3201-3204
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    • 2000
  • In general, analog tester or strip chart recorder have been used to measure the corrosion potential of structures such as gas pipelines, oil pipelines, hot water pipelines, power cables etc. Recently, automatic digital data logger substitutes for these manual equipment because using these manual equipments are tedious and time consuming. However, digital data logger also has a shortcoming, that is, short measuring time because of the short lifetime of batteries. Therefore, we developed a long lifetime and low power loss battery taking advantage of galvanic series. In this paper, the results of development for power generator using two metals and DC/DC converter in order to obtain enough voltage for the operation of digital data logger. DC/DC converter operates with 0.5[V]. Its output voltage is 3.5[V] and output current is from 60[mAh] to 1,200[mAh].

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Evaluation of effect of galvanic corrosion between nickel-chromium metal and titanium on ion release and cell toxicity

  • Lee, Jung-Jin;Song, Kwang-Yeob;Ahn, Seung-Geun;Choi, Jung-Yun;Seo, Jae-Min;Park, Ju-Mi
    • The Journal of Advanced Prosthodontics
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    • v.7 no.2
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    • pp.172-177
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    • 2015
  • PURPOSE. The purpose of this study was to evaluate cell toxicity due to ion release caused by galvanic corrosion as a result of contact between base metal and titanium. MATERIALS AND METHODS. It was hypothesized that Nickel (Ni)-Chromium (Cr) alloys with different compositions possess different corrosion resistances when contacted with titanium abutment, and therefore in this study, specimens ($10{\times}10{\times}1.5mm$) were fabricated using commercial pure titanium and 3 different types of Ni-Cr alloys (T3, Tilite, Bella bond plus) commonly used for metal ceramic restorations. The specimens were divided into 6 groups according to the composition of Ni-Cr alloy and contact with titanium. The experimental groups were in direct contact with titanium and the control groups were not. After the samples were immersed in the culture medium - Dulbecco's modified Eagle's medium[DMEM] for 48 hours, the released metal ions were detected using inductively coupled plasma mass spectrometer (ICP-MS) and analyzed by the Kruskal-Wallis and Mann-Whitney test (P<.05). Mouse L-929 fibroblast cells were used for cell toxicity evaluation. The cell toxicity of specimens was measured by the 3-{4,5-dimethylthiazol-2yl}-2,5-diphenyltetrazolium bromide (MTT) test. Results of MTT assay were statistically analyzed by the two-way ANOVA test (P<.05). Post-hoc multiple comparisons were conducted using Tukey's tests. RESULTS. The amount of metal ions released by galvanic corrosion due to contact between the base metal alloy and titanium was increased in all of the specimens. In the cytotoxicity test, the two-way ANOVA showed a significant effect of the alloy type and galvanic corrosion for cytotoxicity (P<.001). The relative cell growth rate (RGR) was decreased further on the groups in contact with titanium (P<.05). CONCLUSION. The release of metal ions was increased by galvanic corrosion due to contact between base metal and titanium, and it can cause adverse effects on the tissue around the implant by inducing cytotoxicity.

Measurement of Vestibular Ocular Reflex in Normal Subjects Using Galvanic Stimulator and Videooculograph (전기자극과 VOG(Videooculograph)를 이용한 정상인의 전정 안반사 측정)

  • 김수찬;정운교;남기창;이원상;김영하;김덕원
    • Journal of Biomedical Engineering Research
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    • v.22 no.6
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    • pp.487-496
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    • 2001
  • In this study, a galvanic stimulator providing bipolar mode controlled by a PIC(peripheral interface controller) was constructed to evaluate vestibular function The maximum load and maximum current intensity of the constant current source were 3$k\Omega$ and 5mA. respectively. and it could Produce DC, sine wavers. or Pulse waves. Eve movements of 20 normal subjects by galvanic stimulation were analyzed using a commercial videooculogragh. During stimulating with DC for 30 sec. we recorded the response of eye movement with current intensity of 0.75. 1 2, and 3 mA. Nystagmus occurred to all the subjects when the galvanic stimulus intensity was larger than 2 mA. Average SPV(slow Phase eye movement velocity) and the number of nystagmus increased from 7.1 to 4.8 deg/sec and from 17 to 48, respectively, when the stimulus current increased from 0.75 to 3 mA. All the fast eye movement of the nystagmus were the direction of the negative electrode. The asymmetry which means the difference between right- and left-eye movements decreased when the stimulus intensity increased. It is expected that this study would be useful in evaluating vestibular function and in studying basic Physiology mechanism of vestibular ocular reflex by galvanic stimulus .

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A Study on Electrochemical Characteristics Aluminum Multi Matrix Compound (Al-MMC) of Neutron Absorber Material

  • Lee, Jung Hwan;Lee, Yunju;Yoo, Seung Chang;Kim, Seunghyun;Kim, Ji Hyun
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2018.11a
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    • pp.179-180
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    • 2018
  • Al - MMC, used as a neutron absorber, shows pitting corrosion and/or galvanic corrosion in 3.5wt.% NaCl solution. If pitting corrosion penetrates the core, neutron absorption performance could be affected. Galvanic corrosion was observed between Al 5052 and Al 1070, and pitting corrosion was observed around $B_4C$.

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An Electrochemical Study on the Effect of Post-Weld Heat Treatment about Corrosion Resistance Property of SS400 Steel for Ship`s Materials (선박재료용 SS400강의 내식성에 대한 용접후 열처리효과에 관한 전기화학적 연구 (II))

  • 김성종;김진경;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.5
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    • pp.58-68
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    • 2000
  • When SS400 steel was welded with low hydrogen type and ilmennite type welding, the effect of post-weld heat treatment(PWHT) was investigated with parameters such as micro vickers hardness, corrosion potential, polarization behaviors, galvanic current, Al anode generating current and Al anode weight loss etc. Hardness of each parts(HAZ, BM, WM) by PWHT in case of low hydrogen type and ilmennite type welding was lower than that of each parts by As-welded However hardness of WM area in case of low hydrogen type and ilmennite type welding was the highest among those three parts regardless of PWHT, Whereas in case of ilmennite type welding, WM area was the highest potential among these three parts on galvanic potential series with As-welded while BM area was the highest potential among these three parts by PWHT on the contrary. And in case of low hydrogen type welding, galvanic corrosion and micro cell corrosion of welding parts was decreased with PWHT. However, It was increased with PWHT in case of ilmennite type welding. Moreover Al anode generating current and anode weight loss in case of low hydrogen type was decreased by PWHT compared to As-wedled but, which was increased than that of As-welded in case of ilmennite type welding. Therefore, it is suggested that Corrosion resistance property in case of low hydrogen type welding is increased by PWHT. However its property was devreased with PWHT in case of ilmennite type welding.

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THE EFFECT OF GALVANIC CURRENT BETWEEN DENTAL RESTORATIONS ON HUMAN SALIVA (치아 수복재에 의한 갈바닉 전류가 인체 타액에 미치는 영향)

  • Kwon, Hyuk-Choon;Um, Chung-Moon;Cho, In-Sik;Ryu, Ju-Hee;Son, Ho-Hyun
    • Restorative Dentistry and Endodontics
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    • v.23 no.2
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    • pp.630-638
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    • 1998
  • The purpose of this study was to evaluate the effect of galvanic current between different metallic restorations on human saliva. The rate of salivary flow and concentrations of IgG, IgM, sIgA and lactoferrin were measured. In this study, unstimulated whole saliva collected before restoration was regarded as control group and unstimulated whole saliva collected 10 minutes, 1 day, 1 week, and 1 month after restoration were regarded as experimental groups. Following results were obtained from this study. 1. There were some differences in values of salivary flow rate between experimental groups, but the changes in values compared to those of the control group were not statistically significant(P>0.05). 2. Measurements of major antibacterial components of saliva showed that while the concentrations of IgG and IgM decreased significantly 1 week and 1 month after restoration(P<0.05), changes in values of sIgA and lactoferrin were not statistically significant(P>0.05). 3. In vitro measurements of galvanic currents decreased sharply in the first 20 seconds and thereafter decreased gradually. Galvanic current values measured in the early stages were greatly varied, but after 2 hours, the values in all groups approximated each other.

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Facile Coating of Poly(3,4-ethylenedioxythiophene) on Manganese Dioxide by Galvanic Displacement Reaction and Its Electrochemical Properties for Electrochemical Capacitors

  • Kim, Kwang-Heon;Kim, Ji-Young;Kim, Kwang-Bum
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2529-2534
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    • 2012
  • Poly(3,4-ethylenedioxythiophene) coated Manganese Dioxide (PEDOT/$MnO_2$) composite electrode was fabricated by simply immersing the $MnO_2$ electrode in an acidic aqueous solution containing 3,4-ethylenedioxythiophene (EDOT) monomers. Analysis of open-circuit potential of the $MnO_2$ electrode in the solution indicates the reduction of outer surface of $MnO_2$ to dissolved $Mn^{2+}$ ions and simultaneously oxidation of EDOT monomer to PEDOT on the $MnO_2$ surface to form a PEDOT shell via a galvanic displacement reaction. Analysis of cyclic voltammograms and specific capacitance of the PEDOT/$MnO_2$, conductive carbon added $MnO_2$ and conductive carbon added PEDOT/$MnO_2$ electrodes suggests that the conductive carbon acted mainly to provide a continuous conducting path in the electrode to improve the rate capability and the PEDOT layer on $MnO_2$ acts to increase the active reaction site of $MnO_2$.

The Hydrogen Production from the Hydrolysis of Mg-Graphite Pellet for Military Fuel Cells (군용 연료전지 적용을 위한 Mg-Graphite 펠렛의 가수분해 반응을 이용한 수소생산)

  • Park, Minsun;Yu, Minkyu;Kim, Jongsoo;Kwon, Hyuksang
    • Journal of the Korea Institute of Military Science and Technology
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    • v.18 no.2
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    • pp.160-166
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    • 2015
  • On board hydrogen generation from the hydrolysis of an active metal is very attractive due to its economical, convenient, and safe reasons. A Mg-graphite pellet has been designed as a hydrogen source for portable fuel cell. Mg (1 g) + 0.10 g graphite pellet showed an excellent hydrogen generation rate that is equivalent to 15.8 ml/g.min from its hydrolysis. The hydrogen generation rate of the pellet is significantly increased due to the galvanic corrosion by galvanic cells between Mg anode and graphite cathode in a 10.wt. % NaCl solution at a room temperature.