• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.165-168
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• 2015

To measure laminar burning velocity in methane/air/ethylene mixture flame, propagating centrally ignited spherical premixed flame to radial direction was measured by high-speed schlieren images with elevated pressure. In this study, The experimentally measured unstretched laminar burning velocities of methane was compared with GRI mech 3.0 to validate experimental data and choose the radius range, respectively. numerical prediction using the PREMIX code with GRI mech 3.0, USC mech II,, and Wang mech were evaluated through comparison with experimental burning velocity with consideration of extrapolation on linear/nonlinear model.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.1
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• pp.67-75
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• 2019

An experimental study was conducted to measure laminar burning velocity and Markstein length of SNG fuel with 3% of hydrogen contents from spherical propagating flames at normal and elevated initial pressure. These results were compared with numerical calculations by Premix code with GRI-mech 3.0, USC II and UC San Diego to provide suitable mechanism for SNG fuel. As a result of this work, it was found that the burning velocities and Markstein lengths of SNG fuel decrease with increase of initial pressure regardless of equivalence ratio. In addition, numerical calculations with GRI-mech 3.0 were coincided with experimental results.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.2
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• pp.243-250
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• 2003

The extinction behavior and the unsteady response of augmented reduced mechanism(ARM) have been investigated by adopting an OPPDIF code and a numerical solver for the flamelet equations. By comparing the performance of the ARM based on Miller and Bowman's mechanism(MB-ARM) with that of the ARM based on GRI-Mech 3.0(GRI-3.0-ARM), it is identified that the MB-ARM is more suitable for the unsteady calculation because it is relatively less stiff than GRI-3.0-ARM during an ignition process. The steady results using the MB-ARM, which is modified to predict reasonably the extinction point of experiment, are in excellent agreement with those from full mechanism. Under the sinusoidal transient disturbances of scalar dissipation rate, the unsteady responses of the flame temperature and species concentrations using a modified MB-ARM show in very close agreement with those from full mechanism. It is presumed that above modified MB-ARM is very suitable for the unsteady simulation of turbulent flames because it gives not only a low computational cost but also a good prediction performance for flame structure, extinction point and unsteady response.

• Journal of the Korean Society of Marine Environment & Safety
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• v.20 no.6
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• pp.768-773
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• 2014

In this study, experimental and numerical studies for the synthesis of carbon nanotube(CNT) in methane counterflow diffusion flame have been performed. Methane mixed with acetylene($C_2H_2$) was used as a fuel gas and ferrocene was used as a catalyst for synthesis of CNT. The major parameters was $C_2H_2$ mixing rate and mixing rates were 2 %, 6 %, and 10 %. Characteristics of CNT formation on grid were analyzed from SEM images. the chemical reaction mechanism adopted is GRI-MECH 3.0. Numerical results showed that flame temperature and CO mole fraction were increased with increasing acetylene mixing rate. Experimental results showed that the CNT synthesis in 2% acetylene mixture flame better than that of 6% and 10% acetylene mixture flames. It can be considered that 6% and 10% acetylene mixture flames generated the excessive carbon source and then it interrupted the supplement of the carbon source into ferrocene catalyst. It can be found that the supply of appropriate quantity of carbon source can make effect to synthesis of high purity of CNT.

• Journal of the Korean Society of Combustion
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• v.13 no.3
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• pp.24-32
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• 2008

Steady Laminar Flamelet Model (SLFM) calculation is performed to compare the turbulent combustion characteristics of air combustion and oxy-combustion with $CO_2$ recirculation. Radiative heat loss is considered by the optically thin limit assumption. For more realistic simulation the first-order conditional moment closure(CMC) model is applied to SANDIA PILOTED FLAME D again for the oxidants of air and mixture of $O_2$ and $CO_2$. The chemical kinetic machanism for methane is GRI Mech 3.0. Results show that oxy flames are much more stable than air flames, while comparable stability is maintained with 65% $CO_2$ recirculation. The comparable peak temperature is maintained with 80% $CO_2$ recirculation. Higher the temperature, higher the fractions of intermediate species, CO and OH, due to dissociation.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.118-125
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• 2007

The firtst-order conditional moment closure (CMC) model is applied to CH4/air swirl diffusion flame in a gas turbine model combustor. The flow and mixing fields are calculated by fast chemistry assumption with SLFM library and a beta function pdf for mixture fraction. RNG k-e model is used to consider the swirl flame in a confined wall. Reacting scalar fields are calculated by elliptic CMC formulation with chemical kinetic mechanism, GRI Mech 3.0. Validation is done against measurement data for mean flow and scalar fields in the model combustor [1]. Results show reasonable agreement with the mean mixture fraction and its variance, while temperature is overpredicted as the level of local extinction increases. The second-order CMC model is needed to consider local extinction with considerable conditional fluctuations near the nozzle.

• Journal of ILASS-Korea
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• v.23 no.4
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• pp.192-204
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• 2018

In this study, a 3D CFD analysis method for the combustion process was established for a low calorific value syngas-diesel dual-fuel engine operating under very lean fuel-air mixture condition. Also, the accuracy of computational analysis was evaluated by comparing the experimental results with the computed ones. To simulate the combustion for the dual-fuel engine, a new dual-fuel chemical kinetics set was used that was constituted by merging two verified chemical kinetic sets: n-heptane (173 species) for diesel and Gri-mech 3.0 (53 species) for syngas. For dual-fuel mode operations, the early stage of combustion was dominated by the fuel burning inside or near the spray plume. After which, the flame propagated into the syngas in the piston bowl and then proceeded toward the syngas in the squish zone. With the baseline injection system and piston shape, a significant amount of unburned syngas was discharged. To solve this problem, effects of the injection parameters and piston shape on combustion characteristics were analyzed by calculation. The change in injection variables toward increasing the spray plume volume or the penetration length were effective to cause fast burning in the vicinity of TDC by widening the spatial distribution of diesel acting as a seed of auto-ignition. As a result, the unburned syngas fraction was reduced. Changing the piston shape with the shallow depth of the piston bowl and 20% squish area ratio had a significant effect on the combustion pattern and lessened the unburned syngas fraction by half.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2003.05a
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• pp.91-93
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• 2003

A comprehensive numerical study is carried out to investigate for the understanding of the flow evolution and flame development in a supersonic combustor with normal injection of ncumally injecting hydrogen in airsupersonic flows. The formulation treats the complete conservation equations of mass, momentum, energy, and species concentration for a multi-component chemically reacting system. For the numerical simulation of supersonic combustion, multi-species Navier-Stokes equations and detailed chemistry of H2-Air is considered. It also accommodates a finite-rate chemical kinetics mechanism of hydrogen-air combustion GRI-Mech. 2.11[1], which consists of nine species and twenty-five reaction steps. Turbulence closure is achieved by means of a k-two-equation model (2). The governing equations are spatially discretized using a finite-volume approach, and temporally integrated by means of a second-order accurate implicit scheme (3-5).The supersonic combustor consists of a flat channel of 10 cm height and a fuel-injection slit of 0.1 cm width located at 10 cm downstream of the inlet. A cavity of 5 cm height and 20 cm width is installed at 15 cm downstream of the injection slit. A total of 936160 grids are used for the main-combustor flow passage, and 159161 grids for the cavity. The grids are clustered in the flow direction near the fuel injector and cavity, as well as in the vertical direction near the bottom wall. The no-slip and adiabatic conditions are assumed throughout the entire wall boundary. As a specific example, the inflow Mach number is assumed to be 3, and the temperature and pressure are 600 K and 0.1 MPa, respectively. Gaseous hydrogen at a temperature of 151.5 K is injected normal to the wall from a choked injector.A series of calculations were carried out by varying the fuel injection pressure from 0.5 to 1.5MPa. This amounts to changing the fuel mass flow rate or the overall equivalence ratio for different operating regimes. Figure 1 shows the instantaneous temperature fields in the supersonic combustor at four different conditions. The dark blue region represents the hot burned gases. At the fuel injection pressure of 0.5 MPa, the flame is stably anchored, but the flow field exhibits a high-amplitude oscillation. At the fuel injection pressure of 1.0 MPa, the Mach reflection occurs ahead of the injector. The interaction between the incoming air and the injection flow becomes much more complex, and the fuel/air mixing is strongly enhanced. The Mach reflection oscillates and results in a strong fluctuation in the combustor wall pressure. At the fuel injection pressure of 1.5MPa, the flow inside the combustor becomes nearly choked and the Mach reflection is displaced forward. The leading shock wave moves slowly toward the inlet, and eventually causes the combustor-upstart due to the thermal choking. The cavity appears to play a secondary role in driving the flow unsteadiness, in spite of its influence on the fuel/air mixing and flame evolution. Further investigation is necessary on this issue. The present study features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the previous works. In particular, the oscillatory flow characteristics are captured at a scale sufficient to identify the underlying physical mechanisms. Much of the flow unsteadiness is not related to the cavity, but rather to the intrinsic unsteadiness in the flowfield, as also shown experimentally by Ben-Yakar et al. [6], The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The work appears to be the first of its kind in the numerical study of combustion oscillations in a supersonic combustor, although a similar phenomenon was previously reported experimentally. A more comprehensive discussion will be given in the final paper presented at the colloquium.