• 태양에너지
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• 제17권3호
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• pp.67-73
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• 1997

공기는 열전도 계수가 낮으므로 밀폐공간 내에서 적당한 형태를 형성하여 자연대류 열전달을 촉진 시키다면 태양열 집열기로서 건물 난방에 이용할 수 있고, 또 자연대류가 일어나지 않도록 유동을 억제 시킨다면 매우 훌륭한 단열재로 사용할 수 있다. 따라서, 본 연구에서는 건물벽 구조에 따라 내 외벽 사이에 단순 사각 밀폐공간을 형성하여 외벽의 가열부와 내벽의 방열부의 위치를 변화시켜 가며 수치해석을 수행하여 최대 난방 및 단열효과를 얻을 수 있는 새로운 대체 건물벽 개발에 관한 기초 설계 자료를 제시하고자 한다. 연구 결과 부력에 의한 driving force를 얻기 위해서는 방열부가 가열부보다 항상 위쪽에 위치하고 크기는 전체 높이의 1/2 이하일 때 열전달이 촉진됨을 알았다.

• 터널과지하공간
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• 제5권3호
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• pp.251-265
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• 1995

One of the most important matters in stress measurement by hydraulic fracturing technique is the determination of the breakdown pressure, reopening pressure, and shut-in pressure, since these values are the basic input data for the calculation of the in-situ stress. The control of the fracture propagation is also important when the hydraulic fracturing technique is applied to the development of groundwater system, geothermal energy, oil, and natural gas. In this study, a laboratory scale hydraulic fracturing device was built and a series of model tests were conducted with cube blocks of Machon gabbro. A new method called 'flatjack method' was adopted to determine shut-in pressure. The initial stress calculated from the shut-in pressure measured by flatjack method showed much higher accuracy than the stress determined by the conventional method. The dependency of the direction of fracture propagation on the state of the initial stresses was measured by introducin g artificial slots in the borehole made by water jet system. Numerical modeling by BEM was also performed to simulate the fracture propagation process. Both results form numerical and laboratory tests showed good agreement. From this study which provides the extensive results on the determination of shut-in pressure and the control of fracture propagation which are the critical issue in the recent hydraulic fracturing, it is conclued that in-situ stress measurement and the control of fracture propagation could be achived more accurately.

• 한국물환경학회지
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• 제21권1호
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• pp.14-20
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• 2005

A feasibility study has been conducted regarding the application of waste coffee grounds as an adsorbent for the treatment of nickel ion containing wastewater. The major variables which considered to influence the adsorbability of nickel ion were its initial concentration, reaction temperature, pH, and coexisting ion. The specific surface area of coffee grounds used in the experiment was found to be ca. $39.67m^2/g$, which suggesting its potential applicability as an adsorbent due to its relatively high surface area. In the experimental conditions, more than 90% of the initial amount of nickel ion was shown to adsorb within 15 minutes and equilibrium in adsorption was attained after 3 hours. The adsorption behavior of nickel ion was well explained by Freundlich model and kinetics study showed that the adsorption reaction was second-order. Adsorption was reduced with temperature and its change of enthalpy in standard state was estimated to be -807.05 kJ/mol. Arrhenius equation was employed for the calculation of the activation energy of adsorption and nickel ion was observed to adsorb on coffee grounds exoentropically based on thermodynamic estimations. As pH rose, the adsorption of nickel ion was diminished presumably due to the formation of cuboidal complex with hydroxide ion and the coexistence of cadmium ion was found to decrease the amount of nickel ion adsorption, which was proportional to the concentration of cadmium ion.

• 한국자동차공학회논문집
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• 제2권5호
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• pp.121-134
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• 1994

Shock tube investigation of ethylene oxide-$0_{2}-N_{2}$ mixture have been performed to reveal detonation characteristics of the mixture in terms of detonation pressure and speed. Theoretical calculation of thermodynamic parameters at the Chapmann-Jouguet detonation of the mixture has been also performed. A comparision of the observed results with the calculated ones can lead us to predict the detonation parameters of ethylene oxide in an artificial air. In addition, we have observed ignition delay times of ethylene oxide mixtures. The best fit of the observed delay times to Arrhenius gas kinetic relation gives : ${\tau}=10^{-144}{e{xp}}(E_a/RT)[C_{2}H_{4}O]^{-4.8}[O_{2}]^{-12.4}[N_{2}]^{-14.1}$ $E_a=3.67kcal/mole$ The observed activation energy is markedly reduced, compared with the case of ethylene oxide diluted in Ar. It could be due to the factor that $N_2$ play a role as detonation promoter yielding very reactive NOx radicals.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3385-3390
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• 2010

$Li^+$ ion complex of azacrown ether with restricted motion of freedom and pseudo-bilateral symmetry was studied by infrared spectroscopy, which has shown simplified and broadened vibrational features. The C=O and N-H stretching bands, in particular, shows anomalous broadening nearly ${\sim}50\;cm^{-1}$. The density functional calculation at the level of BP86/6-31+$G^{**}$ shows that $Li^+$ ion is trapped and rather free to move around inside the cavity, as much as about $0.70\;{\AA}$. Through the relocation of $Li^+$ ion inside the cavity, the conformational changes would occur rapidly in its symmetry $C_1\;{\rightleftarrows}\;C_2\;{\rightleftarrows}\;C_1$$. The potential barrier was obtained to be merely ~2.2 kJ/mol for $C_1\;{\rightarrow}\;C_2$. During this conformational alteration, the amide backbone twists concurrently its dihedral angle side to side about up to ${\pm}3$ degree. Selected vibrational modes were interpreted in terms of the force constant variations of local symmetry coordinates between conformations in the framework of $C_1\;{\rightleftarrows}\;C_2\;{\rightleftarrows}\;C_1$.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.314-314
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• 2010

The design of the blanket and shield play a key role in determining the size of a reactor since it has an impact on the various reactor components. The blanket should produce enough tritium for tritium self-sufficiency and the shield should provide sufficient protection for the superconducting TF coil. Neutronic optimization of the blanket and the shield is necessary, and we coupled the system analysis with a neutronic calculation to account for the interrelation of the blanket and shield with the plasma performance of a reactor system in a self-consistent manner. By using the coupled system analysis code, the operational space for a low aspect ratio (LAR) tokamak reactor with a superconducting toroidal field (TF) coil is investigated with an spect ratio in the range of 1.5 - 2.5. The minimum major radius which satisfies all the physics and engineering requirements increases with the magnetic field at the magnetic axis. A required inboard shield thickness is mainly determined by the requirement on the protection of the TF coil against radiation damage. It is shown that to have a fusion power bigger than 3,000 MW in the LAR tokamak with a superconducting TF coil, a major radius bigger than 4.0 m is required.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 추계학술대회 논문집
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• pp.248-251
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• 2005

To investigate the degeneration process in the intervertebral disc, a three dimensional (3D) poroelastic finite-element (FE) model was developed. Disc was modeled as two different regions, such as annulus modeled with fiber reinforced 20 node poroelastic ground matrix and nucleus having large porosity. Excess Von Mises stress in the disc element assumed to be a possible source of degeneration under compressive loading condition. Recursive calculation was continued until the desired convergence was attained by changing the permeability and porosity of those elements, which could be predicted from the previous iteration. The degenerated disc model showed that relatively small compressive stresses were generated in the nucleus elements compared to normal disc. Its distribution along the sagittal plane was matched well with a previously reported experimental result. Contrasts to this result, pore pressures in the nucleus were higher than those in the normal disc. Total stress indicated similar values for two different models. This new approach using poroelastic modeling could provide the explanation of the interaction between fluid and solid matrix in the disc during the degeneration process.

• Bulletin of the Korean Chemical Society
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• 제5권2호
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• pp.55-60
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• 1984

The NMR shift arising from the electron angular momentum and electron spin dipolar-nuclear spin angular momentum interactions has been investigated for a $4d^1$system in a strong crystal field environment of tetragonal symmetry. A general formula for NMR shift is used to compute the NMR shifts along the (100), (010), (001), (110) and (111) axes. We find that from the computed results, the NMR shift along the (100) and (010) axes is consistent with each other in a strong crystal field environment of tetragonal symmetry, but the NMR shift along the (001) axis is about triply greater in magnitude than those along the (100) and (010) axes and is opposite in sign to those along (100) and (010) axes. In this work, we express the expansion coefficients $a_1^{(i)}$ and $b_1^{(i)}$ of $A_i$ and $B_i$ in terms of $g_m^{(i)}$ and $h_m^{(i)}$ and two matrices $c_{lm}$ and $d_{lm}$ of radial dependence. The NMR shift is also separated into the contributions of multipolar terms. We find that $1/R^3$ term contributes dominantly to the NMR shift along the (100), (010), (001) and (110) axes while along the (111) axis $1/R^5$ term dominantly contributes. However, the contribtions of the other terms may not be negligible.

• 한국표면공학회지
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• 제34권5호
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• pp.510-515
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• 2001

It was first time that low frequency R.F. derived plasma enhanced MOCVD with frimethylborate precursor was used to fabricate a new ternary compound $BO_{x}$ $N_{y}$ . The formation of BON molecule was resulted from nitrogen nitrifying B-O, and forming the angular molecule structure proved by XPS and FT-IR results. The relationship between hardness and film thickness was studied. An thickness-independent hardness was fond about 10 GPa. The empirical calculation of band-gap and UV test result showed that our deposited $BO_{x}$ $N_{y}$ thin film was semiconductor material with 3.4eV of wide band gap. The electrical conductivity, $4.8$\times$10^{-2}$ /($\Omega$.cm)$^{-1}$ also confirmed that $BO_{x}$ $N_{y}$ has a semiconductor property. The roughness detected from the as-grown films showed that there was no serious bombarding effect due to anion in the plasma occurring in the RF frequency derived plasma.

• Nuclear Engineering and Technology
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• 제26권3호
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• pp.411-419
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• 1994

원자력발전소 중대사고시 예상되는 수소생성과 이에 따른 수소연소로 인한 압력증가로 야기되는 격납용기의 파손화률을 몬테카를로 방법을 통하여 계산하였다. 몬테카를로 계산을 수행하기 위해서는 각각의 입력변수들에 대한 적절한 확률분포함수가 요구되는데, 통계적인 처리를 통하여 구하였다. 고리 2호기에 대한 계산을 수행하였으며, 입력변수들에 대한 민감도 분석도 실시하였다. 고리 2호기에서 수소연소로 인한 격납용기의 파손확률은 60% 이하로 계산되었으며, 민감도 분석결과 SFD가 중요한 인자이긴 하지만 다른 인자들도 무시할 수 없는 영향을 미치고 있음이 밝혀졌다.