• Title/Summary/Keyword: Functional resin

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A CASE REPORT OF PEDIATRIC PATIENT WITH ENAMEL AND DENTIN DYSPLASIA (Enamel and Dentin dysplasia를 동반한 소아환자의 치험례)

  • Yoon, Byeong-Gun;Kim, Yong-Kee
    • Journal of the korean academy of Pediatric Dentistry
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    • v.21 no.2
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    • pp.599-604
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    • 1994
  • Very few reports are available on the occurrence of abnormality of both enamel and dentin. This case has some characteristiced of both amelogenesis imperfecta and dentinogenesis imperfecta. Clinically, the enamel of primary dentition was completely absent and when the permanent teeth came to the pediatric dept. of Dankook University Dental Hopital for treatment. Fixed-removable type resin plate was delivered to increase vertical dimension and to solve esthetic and functional defects. Hypoplastic teeth were restored either stainless steel crown or composite resin restoration or both. The periodic recall check and oral hygiene education are recommended.

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Structural and Physical Properties of Sealant Paste Prepared by Silica/Polymer Composites (실리카/고분자 복합체를 이용한 실란트 페이스트의 구조 및 물리적 특성)

  • Yoon, Jong-Kuk;Park, Jung-Il;Koo, Kyung-Wan;Jang, Young-Sil
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.6
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    • pp.916-921
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    • 2012
  • Sealant paste with silica immersed in cross-linked epoxy-acrylate polymer resin was prepared by thermal and UV curing process. The curing mechanism of polymer resin resulted from 2 functional groups of epoxy and acrylic structure. The properties of microstructure, thermal conductivity and mechanical strength were investigated for its various applications. The adhesion strength is increased by increasing the thermal curing time until 15 minutes, and curing efficiency is saturated over 20 minutes. The increase rate per day of pot life and viscosity is 4.8%, indicating it has excellent storage stability. It is found that the formulation of silica pastes can be applied to heavy industries, building materials, display and various industries.

Preparation of Yacht Sail Using High Tenacity Polyester and Its Performance Evaluation (폴리에스터 고강력사를 이용한 요트용 세일의 제조 및 성능분석)

  • Son, Hyun-Sik;Sim, Seung-Bum;Min, Mun-Hong
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.54-61
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    • 2012
  • This study surveyed the preparation of 8oz coated fabric and the physical property of the coated fabric according to the treated condition for the sail yacht. And the coated fabrics were compared with the performance of overseas products for verification. Physical properties of the coated fabric treated with non-yellowing functional polyurethane resin were examined according to the treatment condition such as compression and ageing treatments. Finally, yellowing fastness to light for 60 hours was assessed. Considering the compression condition after coating, good physical property was obtained at $6kgf/cm^2$. Also, the performance of yellowing fastness was similar to performance of overseas goods.

Technology Trends for Photoresist and Research on Photo Acid Generator for Chemical Amplified Photoresist (포토 레지스트의 기술 동향과 화학 증폭형 포토레지스트에서의 광산 발생제의 연구)

  • Kim, Sung-Hoon;Kim, Sang-Tae
    • Journal of Integrative Natural Science
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    • v.2 no.4
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    • pp.252-264
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    • 2009
  • Lithographic data obtained from PHS(polyhydroxy styrene) having various functionalities were investigated by using a photoacid generator based on diazo and onium type. Chemically amplified photoresist based on the KrF type photoresist was developed by using a photoacid generator and multi-functional resin. Thermal stability for the photoacid generator showed that the increase of loading amount of photoacid generator resulted in the decrease of glass transintion temperature (Tg). The photoacid generators having methyl, ethyl, or propyl group in their cationic structure produced T-top structure in pattern profile due to the effect of acid diffusion during the generation of acid in the resist. The increase of carbon chain length in the anionic structure of photoacid generators resulted in lower pattern resolution due to the interruption of acid diffusion.

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Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin - (II) The Effects of Terpene Resin - (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능향상 - (II) 테르펜수지의 영향 -)

  • Chung, Kyung-Ho;Hong, Young-Keun;Chun, Young-Sik
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.226-231
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    • 1998
  • Hot melt adhesive which is solventless type has been widely used due to the possibility of automated adhesion process. The main purpose of this study is the development of polyamide based hot melt adhesive to improve the property of conventional ethylene-vinyl acetate hot melt adhesive, which has an inherent problem against heat resistance. In this study, it was found that the terpolymers of nylon 6, nylon 66, and nylon 12(CM831, 843P types) instead of nylon homopolymer were suitable base resins for hot melt adhesive, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. According to the results, the optimum adhesion property could be obtained by the using 75/25~50/50 weight radio of CM831/843P resin as a base resin. Terpene resin was used as tackifier to improve adhesion and wetting properties. The best result can be obtained with the 10 wt.% addition of terpene resin. The terpene resin acted as proper tackifier in this system which decreased the melt temperature and viscosity, but increased the mechanical strength of adhesive itself. Also, the rheological property of the adhesive changed from typical non-Newtonian behavior to Newtonian behavior as terpene resin was added.

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The Biological Functionality of Electro-Galvanized Steels Coated with a Hybrid Composite Containing Pyrethroid

  • Jo, Du-Hwan;Kim, Myung-Soo;Kim, Jong-Sang;Oh, Hyun-Woo
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.74-80
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    • 2018
  • The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

The Study of Water Stability of MDF Cement Composite by Addition of Silane Coupling Agent (Silane Coupling Agent 첨가에 의한 MDF Cement Composite의 수분안정성 연구)

  • 노준석;김진태;박춘근;오복진;최상홀
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.421-428
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    • 1998
  • The effect of silane coupling agents on the water stability of HAC/PVA based MDF cement composites which were modified with urethane and epoxy resin were studied as a function of the functional groups and addition amount of silane coupling agent. According to the composition of polymer matrix the silanes with different functional groups showed the different effectiveness. In case of the only PVA matrix the silane with vinyl functional group was more effective than other silanes. When the epoxy resin was added the silane of epoxy-methodxy group enhanced the flexural strength of dry and wet state more than other. In case of urethane-added MDF cement the silane of diamine group was effective and enhanced the water sta-bility fo MDF cement composite more and more as the addition amount of silane increased, Especially in case of warm-presed composite the effect of silane was enhanced By addition of 2wt% of silane with 야-amine group the flexural strength of urethane-added composites were enhanced by 20% more in dry state 40-70% in wet state in accord with the porosity analysis. The flexural strength of the poxy resin-added MDF cement composite was increased by addition of 1wt% and 2wt% silane of epoxy-methoxy group However the addition of 4wt% of silane decreased the flexural strength of dry and wet state by formation of closed pore in the polymer matrix.

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Synthesis of tung oil-based thermoset resin and its thermal·mechanical properties (Tung oil을 이용한 바이오 기반 열경화성 수지 합성 및 이의 열적·물리적 특성 연구)

  • Kim, Han-Eol;Lee, Jong-eun;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.24-30
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    • 2018
  • Various investigations of vegetable oil extracted from natural resources are underway because of their low cost and environmental value. On the other hand, the double bonds in vegetable oil should be substituted to other high reactive functional groups due to their low reactivity for synthesizing bio-polymeric materials. ${\alpha}$-eleostearic acid, which consists of a conjugated triene, is the main component of tung oil, and the conjugated triene allows tung oil to have higher reactivity than other vegetable oils. In this study, tung oil was copolymerized with styrene and divinylbenzene to make a thermoset resin without any substitution of functional groups. The thermal and mechanical properties were measured to examine the effects of the composition of each monomer on the synthesized thermoset resin. The results showed that the products have only one Tg, which means the synthesized thermoset resins are homogeneous at the molecular level. The mechanical properties show that tung oil acts as a soft segment in the copolymer and makes a more elastic product. On the other hand, divinylbenzene acts as a hard segment and makes a more brittle product.

Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin -(I) Physical Properties of Adhesives- (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능 향상 -(I) 접착제의 물성-)

  • Chun, Young-Sik;Hong, Young-Keun;Chung, Kyung-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.194-202
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    • 1996
  • Hot melt adhesive based on the polyamide resin was studied to improve the conventional hot melt adhesives such as ethylene-vinyl acetate which have inherent problems against creep and heat resistance. It was found that the terpolymer of nylons6, nylon66, and nylon12 or the nylon blend instead of nylon homopolymer was suitable base resin for hot melt adhesives, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. Also, the rheological properties of the polyamide based hot melt adhesive could be controlled by the incorporation of terpene resin, butyl benzyl phthalate, and paraffin wax. The results of melt viscosities and tensile properties of adhesive itself indicated that the optimum adhesion properties could be obtained through the blending of CM831/843P resins with weight ratio 75/25~50/50. The adhesion between steel and steel was tested by using lap shear geometry. It was found that the surface roughness of steel affected the adhesion strength.

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Adsorption characterisctics of mixed resins for perchlorate ion (혼합수지를 이용한 과염소산 이온의 흡착 특성)

  • Park, Su-Min;Jeon, Byong-Hun;Jeong, Hyuk;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.23 no.5
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    • pp.429-436
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    • 2010
  • The present research evaluates the efficiency of mixed resins between anion exchange resin and active carbon. We expected synergic effect from advantages of both adsorbents. Especially, this research focused on the removal of high cencentrated perchlorate ion from demilitarization solution. The total amount of the adsorbed perchlorate ion is increased considerably with mixed resins between mono functional anion exchange resin and granular active carbon from a single adsorbent. Results demonstated that this process not only improve the efficiency of adsorbing perchlorate, but save the time, space and cost for treating perchlotrate waste solution, because of reducing organic contaminant removing process. The interference effects from coexisting anions are not significant and can successfully applied to real demilitarization sample.