• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.598-598
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• 2013

The short lifetime of Proton Exchange Membrane Fuel Cell (PEMFC) is the one of the main problems to be solved for commercializing. Especially, the weak adhesion between metal nanoparticles and supports deteriorate the performances of nanocatalysts, therefore, it is considered to be a major failure mechanism. Using force-distance spectroscopy of atomic force microscopy (AFM), we characterized the adhesion between Pt nanoparticles and carbon supports that is crucially related to the durability for membrane fuel cell (MFC) electrode. In our study, force distance curves measured with Pt coated AFM cantilever, mimicking the behavior of corresponding nanoparticles on carbon supports, leads to the adhesion between metal nanoparticles and carbon supports. We found that theadhesion between Pt and HNO3-treated carbon is enhanced by a factor of 4, compared to Pt and bare carbon support, that is consistent with the macroscopic durability test of PEMFC. The higher adhesion between Pt and HNO3-treated carbon can be explained in light of the stronger chemical interaction by C/O functional groups.

• 센서학회지
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• 제31권4호
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• pp.218-227
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• 2022

Triboelectric nanogenerators (TENGs), a new green energy, that have various potential applications, such as energy harvesters and self-powered sensors. The output performance of TENGs has been improving rapidly, and their output power significantly increased since they were first reported owing to improved triboelectrification materials and interfacial material engineering. Because the operation of a TENG is based on contact electrification in which electric charges are exchanged at the interface between two materials, its output can be increased by increasing the contact area and charge density. Material surface modification with microstructures or nanostructures has increased the output performance of TENGs significantly because not only does the sharp micro/nano morphology increases the contact area during friction, but it also increases the charge density. Chemical treatment in which ions or functional groups are added has also been used to improve the performance of TENGS by modifying the work functions, charge densities, and dielectric constants of the triboelectric materials. In addition, ultrahigh output power from TENGs without using new materials or treatments has been obtained in many studies in which special structures were designed to control the current release or to collect the charge current directly. In this review, we discuss physical and chemical treatments, bulk modifications, and interfacial engineering for enhancing TENG performance by improving contact electrification and electrostatic induction.

• 한국의류학회지
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• 제30권6호
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• pp.870-879
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• 2006

In this study, the difference in the mechanical properties of silver and cotton weft knitted fabrics was studied. Six silver fabrics for the summer ladies' knit outwear were knitted varying knit structure and fabric density. Two commercial cotton knitted fabrics were selected to compare the properties. subjective sensation of hand of the fabrics was also studied. Mechanical properties of the fabric samples were measured by KES-FB system. From these, primary hand values(HV) were evaluated by the conversion equation (KW-403-KTU) and the total hand value(THV) was carried out according to the KW-304 Summer. The result of the research show that silver weft knitted fabrics had lower LT, RT, G, 2HG and higher EM, W, LC, WC, RC than cotton weft knitted fabrics. The use of silver yam contributed to increase in surface roughness of knitted fabrics. As the silver knitted fabrics became thicker compressional energy increased. The use of silver yarns contributed to much better fabric handle compared with the use of cotton yam only. It appeared that coefficient of friction of tuck stitch was larger than that of plain and interlock stitch. KOSHI and FUKURAMI values of the tuck samples were significantly higher than those values of the plain and interlock samples, while SHARI values were low in general. The total hand value of tuck stitch was higher than those of interlock and plain stitch.

• 한국재료학회지
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• 제19권8호
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• pp.437-442
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• 2009

This paper describes an improved strategy for controlling the adhesion force using both the antiadhesion and adhesion layers for a successful large-area transfer process. An MPTMS (3-mercaptopropyltrimethoxysilane) monolayer as an adhesion layer for Au/Pd thin films was deposited on Si substrates by vapor self assembly monolayer (VSAM) method. Contact angle, surface energy, film thickness, friction force, and roughness were considered for finding the optimized conditions. The sputtered Au/Pd ($\sim$17 nm) layer on the PDMS stamp without the anti-adhesion layer showed poor transfer results due to the high adhesion between sputtered Au/Pd and PDMS. In order to reduce the adhesion between Au/Pd and PDMS, an anti-adhesion monolayer was coated on the PDMS stamp using FOTS (perfluorooctyltrichlorosilane) after $O_2$ plasma treatment. The transfer process with the anti-adhesion layer gave good transfer results over a large area (20 mm $\times$ 20 mm) without pattern loss or distortion. To investigate the applied pressure effect, the PDMS stamp was sandwiched after 90$^{\circ}$ rotation on the MPTMS-coated patterned Si substrate with 1-${\mu}m$ depth. The sputtered Au/Pd was transferred onto the contact area, making square metal patterns on the top of the patterned Si structures. Applying low pressure helped to remove voids and to make conformal contact; however, high pressure yielded irregular transfer results due to PDMS stamp deformation. One of key parameters to success of this transfer process is the controllability of the adhesion force between the stamp and the target substrate. This technique offers high reliability during the transfer process, which suggests a potential building method for future functional structures.

• Journal of the Korean Wood Science and Technology
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• 제50권3호
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• pp.149-158
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• 2022

To realize the infinite possibilities of materials derived from wood, it is necessary to overcome the weak moisture stability of wood. Thus, the development of an eco-friendly hydrophobic coating agent is essential, and of these, woody biomass-based materials are strongly attractive as coatings. In this study, eco-friendly hydrophobic wood coatings were prepared using carnauba wax purified from palm leaves and sprouts, and kraft lignin. The physicochemical properties of the carnauba wax/lignin blends according to the ratio of carnauba wax and lignin were observed by morphology and functional group change. In addition, the coating performance of carnauba wax/lignin blend coatings was confirmed by measuring the contact angle change. It was found that the addition of lignin could accelerate the atomization of wax particles, and that micro-roughness can be realized when applied to the actual wood surface, to ensure that the coating effect over time lasts longer. In addition, it was confirmed that the addition of lignin increases the hydrogen-bond-based interaction with the wood of the coating, thereby providing better coating stability and increasing the durability of the coating solvent under friction. The carnauba wax/lignin paint developed in this way is eco-friendly because all components are made of wood-based raw materials and have an excellent affinity with wood surfaces. Therefore, it is expected to be applicable to the coating process of wood-plastic composites and timber composites.

• 한국산학기술학회논문지
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• 제22권1호
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• pp.1-8
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• 2021

본 연구에서는 도로 포장 유지관리에 필요한 핵심정보를 생산해 낼 수 있는 저비용·고효율 포장상태 모니터링 기술을 개발하고자 하였다. 특히 시각정보와 고가 센서에 의존하는 기존 장비의 단점을 보완하기 위해 소음과 인공지능 기반의 포장상태등급 평가시스템을 고안하였다. 시스템 개발을 위한 아이디어 정립부터 기능 정의, 정보흐름 및 아키텍쳐 설계 과정을 거쳤으며, 생산된 프로토타입에 대한 성능 검증과 활용 전주기에 대한 실증 평가를 수행하였다. 그 결과, 높은 수준의 인공지능 평가 신뢰도가 확보되었으며, 하드웨어와 소프트웨어적 요소 외에도 시스템 활용에 관한 짜임새 있는 가이드라인이 개발되었다. 또한 현장평가 과정을 통해 비전문가도 쉽고 빠른 조사와 분석이 가능하고, 직관적인 시각적 정보 제공을 통해 관리자의 업무 지원이 가능함도 확인하였다. 반면에 학습에 고려되지 않은 외부 조건에 대한 선행 판별 기술, 시스템 간소화, 가변 주행속도 대응 기술 등 기술의 완성도 제고도 필요함을 알 수 있었다. 본 연구를 시작으로 1960년대 이후 반세기 이상 지속되어온 포장상태 모니터링 기술의 새로운 패러다임이 제시되길 기대한다.