• Carbon letters
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• 제1권3_4호
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• pp.138-142
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• 2001

The effect of electrochemical surface treatments in KOH chemical solution on microstructures of carbon blacks was investigated in terms of surface functional values and XRD measurements. And their mechanical interfacial properties of the carbon blacks/rubber composites were studied by the composite tearing energy ($G_{IIIC}$). It was found that the development of basic-surface functional groups lead to the significant physical changes of carbon blacks, such as, decrease of the interlayer spacing ($d_{002}$), increase of the crystalline size along c-axis ($L_c$), and increase of degree of crystalline (${\chi}_c$). This treatment is possibly suitable for carbon blacks to be incorporated in a hydrocarbon rubber matrix, resulting in improving the hardness and tearing energy of the resulting composites.

• Steel and Composite Structures
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• 제20권5호
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• pp.1119-1131
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• 2016

As a first attempt, an inverse hybrid numerical method for small scale parameter estimation of functionally graded (FG) nanobeams using measured frequencies is presented. The governing equations are obtained with the Eringen's nonlocal elasticity assumptions and the first-order shear deformation theory (FSDT). The equations are discretized by using the differential quadrature method (DQM). The discretized equations are transferred from temporal domain to frequency domain and frequencies of the nanobeam are obtained. By applying random error to these frequencies, measured frequencies are generated. The measured frequencies are considered as input data and inversely, the small scale parameter of the beam is obtained by minimizing a defined functional. The functional is defined as root mean square error between the measured frequencies and calculated frequencies by the DQM. Then, the conjugate gradient (CG) optimization method is employed to minimize the functional and the small scale parameter is obtained. Efficiency, convergence and accuracy of the presented hybrid method for small scale parameter estimation of the beams for different applied random error, boundary conditions, length-to-thickness ratio and volume fraction coefficients are demonstrated.

• Progress in Superconductivity
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• 제1권1호
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• pp.47-50
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• 1999

An Ag/Ni bi-layer sheet was fabricated by the combination of powder metallurgy, diffusion bonding, cold rolling and texture annealing processes. After heat treating the cold rolled thin Ag/Ni bi-layer sheet at $900^{\circ}C$ for 4h, the excellent cube texture was developed on nickel surface. Qualitative chemical analysis using EPMA showed that inter diffusions of Ni and Ag in Ag/Ni bi-layer composite were negligible. It showed that Ag can be used as a chemical barrier for Ni and vice versa.

• Bulletin of the Korean Chemical Society
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• 제33권1호
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• pp.159-166
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• 2012

We have introduced the Pickering emulsion systems to generate novel confining geometries for the selforganization of monodisperse polymer microspheres using nanoparticle-stabilized emulsion droplets encapsulating the building block particles. Then, through the slow evaporation of emulsion phases by heating, these microspheres were packed into regular polyhedral colloidal clusters covered with nanoparticle-stabilizers made of silica. Furthermore, polymer composite colloidal clusters were burnt out leaving nonspherical hollow micro-particles, in which the configurations of the cluster structure were preserved during calcination. The selfassembled porous architectures in this study will be potentially useful in various applications such as novel building block particles or supporting materials for catalysis or gas adsorption.

• Archives of Plastic Surgery
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• 제43권1호
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• pp.3-9
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• 2016

The reconstruction of the mandible is a complex procedure because various cosmetic as well as functional challenges must be addressed, including mastication and oral competence. Many surgical techniques have been described to address these challenges, including non-vascularized bone grafts, vascularized bone grafts, and approaches related to tissue engineering. This review summarizes different modifications of the free vascularized fibula graft, which, since its introduction by Hidalgo in 1989, has become the first option for mandibular reconstruction. The fibula free flap can undergo various modifications according to the individual requirements of a particular reconstruction. Osteocutaneous flaps can be harvested for reconstruction of composite defects. 'Double-barreling' of the fibula can, for instance, enable enhanced aesthetic and functional results, as well as immediate one-stage osseointegrated dental implantation. Recently described preoperative virtual surgery planning to facilitate neomandible remodeling could guarantee good results. To conclude, the free fibula bone graft can currently be regarded as the "gold standard" for mandibular reconstruction in case of composite (inside and outside) oral cavity defects as well as a way of enabling the performance of one-stage dental implantation.

• Membrane and Water Treatment
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• 제1권3호
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• pp.193-206
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• 2010

Organic fouling and biofouling pose a significant challenge to the membrane filtration process. Photocatalysis-membrane hybrid system is a novel idea for reducing these membranes fouling however, when $TiO_2 photocatalyst nanoparticles are used in suspension, catalyst recovery is not only imposes an extra step on the process but also significantly contributes to increased membrane resistance and reduced permeate flux. In this study, $TiO_2$ photocatalyst has been immobilized by coating on the microfiltration (MF) membrane surface to minimize organic and microbial fouling. Nano-sized $TiO_2$ was first synthesized by a sol-gel method. The synthesized $TiO_2$ was coated on a Poly Vinyl Difluoride (PVDF) membrane (MF) surface using spray coating and dip coating techniques to obtain hybrid functional composite membrane. The characteristics of the synthesized photocatalyst and a functional composite membrane were studied using numerous instruments in terms of physical, chemical and electrical properties. In comparison to the clean PVDF membrane, the $TiO_2$ coated MF membrane was found more effective in removing methylene blue (20%) and E-coli (99%).

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.476-476
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• 2011

Introduction of CNTs into a metal matrix has been considered to improve the mechanical properties of the metal matrix. However, the binding energy between metals and pristine CNTs wall is known to be so small that the interfacial slip between CNTs and the matrix occurs at a relatively low external stress. The interfacial strength between CNT and metal matrix is thus one of the key factors for successful development of the CNT/metal composites. Defective or functionalized CNT has been considered to enhance the interfacial strength of nanocomposites. In the present work, we design the various realistic hybrid structures of the single wall CNT/Cu complexes and characterize the interaction between single wall CNTs and Cu nano-particle and Cu13 cluster using first principle calculations. The characteristics of functionalized CNTs with various surface functional groups, such as -COOH, -OH, and -O interacting with Cu are investigated. We found that the binding energy can be enhanced by the surface functional group including oxygen since the oxygen atom can mediate and reinforce the interaction between carbon and Cu. These results strongly support the recent experimental work which suggested the oxygen on the interface playing an important role in the excellent mechanical properties of the CNT/Cu composite.

• KDI Journal of Economic Policy
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• 제28권1호
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• pp.49-93
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• 2006

본 연구는 은행과 보험 간의 겸업이 은행의 안정성과 효율성에 어떠한 영향을 미치는가를 실증분석하고 있다. 실증분석은 국내 모든 은행과 보험회사의 2000년부터 2004년까지의 5개년 자료를 가지고 Z-score 및 복합함수형태 (composite functional form) 모형을 사용하여 진행하였다. 안정성 분석결과는, 은행이 보험업을 겸영할 경우 겸업비중이 확대될수록 안전성은 저하됨을 보여주고 있다. 효율성 분석에서는, 전체 은행의 경우 은행이 보험업무의 겸업비중을 확대함에 따라 비용효율성은 감소하지만, 수익효율성은 증가하며, 결과적으로 이익효율성은 증대되는 것으로 나타났다.

• Structural Engineering and Mechanics
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• 제55권2호
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• pp.435-459
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• 2015

Parametric resonance of shear deformable composite skew plates subjected to non-uniform (parabolic) and linearly varying periodic edge loading is studied for different boundary conditions. The skew plate structural model is based on higher order shear deformation theory (HSDT), which accurately predicts the numerical results for thick skew plate. The total energy functional is derived for the skew plates from total potential energy and kinetic energy of the plate. The strain energy which is the part of total potential energy contains membrane energy, bending energy, additional bending energy due to additional change in curvature and shear energy due to shear deformation, respectively. The total energy functional is solved using Rayleigh-Ritz method in conjunction with boundary characteristics orthonormal polynomials (BCOPs) functions. The orthonormal polynomials are generated for unit square domain using Gram-Schmidt orthogonalization process. Bolotin method is followed to obtain the boundaries of parametric resonance region with higher order approximation. These boundaries are traced by the periodic solution of Mathieu-Hill equations with period T and 2T. Effect of various parameters like skew angle, span-to-thickness ratio, aspect ratio, boundary conditions, static load factor on parametric resonance of skew plate have been investigated. The investigation also includes influence of different types of linearly varying loading and parabolically varying bi-axial loading.

• Carbon letters
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• 제21권
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• pp.1-7
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• 2017

The effects of ammonia-treated graphene oxide (GO) on composites based on epoxy resin were investigated. Ammonia solutions of different concentrations (14-28%) were used to modify GO. Nitrogen functional groups were introduced on the GO surfaces without significant structural changes. The ammonia-treated GO-based epoxy composites exhibited interesting changes in their mechanical properties related to the presence of nitrogen functional groups, particularly amine ($C-NH_2$) groups on the GO surfaces. The highest tensile and impact strength values were 42.1 MPa and 12.3 J/m, respectively, which were observed in an epoxy composite prepared with GO treated with a 28% ammonia solution. This improved tensile strength was 2.2 and 1.3 times higher than those of the neat epoxy and the non-treated GO-based epoxy composite, respectively. The amine groups on the GO ensure its participation in the cross-linking reaction of the epoxy resin under amine curing agent condition and enhance its interfacial bonding with the epoxy resin.