• Title/Summary/Keyword: Functional Layer

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Interaction of Di-Methylaluminum Groups with Hydroxyl Groups on a Fully Hydroxyl-Terminated Si (001) Surface

  • Kim, Dae-Hee;Kim, Dae-Hyun;Kim, Yeong-Cheol;Seo, Hwa-Il
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.1
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    • pp.11-14
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    • 2010
  • The interaction of -$Al(CH_3)_2$ with -OH on a fully OH-terminated Si (001) surface was studied using density functional theory. Two sites for $Al(CH_3)_3$ to react with the -OH on the surface were identified. The $-Al(CH_3)_2$ product energetically favored the dimer-row site rather than the inter-row site because the Al atom of $-Al(CH_3)_2$ at the dimer-row site was attracted by the lone pair electrons of the O atom in the neighboring -OH. The energy barrier for the transfer of the $-Al(CH_3)_2$ between the two sites was 0.11 eV, and therefore, the $-Al(CH_3)_2$ at the inter-row site can easily transfer to the dimer-row site at room temperature.

Design of the Coated Layer Suitable with Conductive Ink for RFID(II) - Effect of coating color components on the surface resistance of conductivity ink - (RFID용 전도성 잉크에 적합한 도공층 설계 (제1보) -도공액 성분에 따른 전도성잉크의 표면저항의 변화-)

  • Jung, Hae-Sung;Kim, Chang-Geun;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.1
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    • pp.17-22
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    • 2011
  • The conventional coated paper has many functional problems for printed RFID tag. This study was carried out in order to evaluate the effect of coating color components on conductivity of printed coated paper. It has been well known that the efficiency of printed RFID tag is influenced by surface properties of substrate. The required properties for suitable substrate of printed RFID tag are high smoothness and waterproof property. In this study high grammage base paper surface sized with PVA was used. Coated paper was manufactured with five different formulations. Types of coating pigments and dosage of latex were varied. It was obtained high smoothness and also less binder demand with clay than GCC. On the other hand, suitable surface resistance and smoothness of coated paper for RFID tag was obtained with 20% of latex. Besides it shows the possibility of using coated paper for printed RFID tag.

Analysis for Filling Stage of Injection Molding Considering Compressibility and Phase Change (압축성과 상변화를 고려한 사출성형의 충전과정 해석)

  • Lee, Sang-Chan;Park, Chang-Eon;Yang, Dong-Yeol
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.12
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    • pp.60-65
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    • 2001
  • To simulate the real molding conditions, the effects of phase change and compressibility of the resin were considered in the present investigation. A modified Cross model with either an Arrhenius-type or WLF-type functional form was used for modeling viscosity of the resin. A double-domain Tait equation of state was employed to describe the compressibility of the resin during molding. The energy balance equation including latent-heat dissipation fur semi-crystalline materials was solved in order to predict the solidified layer and temperature profile. Injection molding experiments were carried out using polypropylene(PP) in the present study. Based on the comparison between experiments and simulations, it was found out the predicted pressure distributions and melt front propagations were accurate. Thus it was concluded that the program developed in this study was proved to be useful in simulations of injection molding process.

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Lamin A/C and Polymeric Actin in Genome Organization

  • Ondrej, Vladan;Lukasova, Emilie;Krejci, Jana;Matula, Pavel;Kozubek, Stanislav
    • Molecules and Cells
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    • v.26 no.4
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    • pp.356-361
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    • 2008
  • In this work, we have studied the structural and functional linkage between lamin A/C, nuclear actin, and organization of chromosome territories (CTs) in mammary carcinoma MCF-7 cells. Selective down-regulation of lamin A/C expression led to disruption of the lamin A/C perinuclear layer and disorganization of lamin-bound emerin complexes at the inner nuclear membrane. The silencing of lamin A/C expression resulted in a decrease in the volume and surface area of chromosome territories, especially in chromosomes with high heterochromatin content. Inhibition of actin polymerization led to relaxation of the structure of chromosome territories, and an increase in the volumes and surface areas of the chromosome territories of human chromosomes 1, 2 and 13. The results show an important role of polymeric actin in the organization of the nuclei and the chromosome territories.

Microstructure Analysis of Ni-P-rGO Electroless Composite Plating Layer for PEM Fuel Cell Separator (고분자전해질 연료전지 분리판을 위한 Ni-P-rGO 무전해 복합도금층의 미세조직 분석)

  • Kim, Yeonjae;Kim, Jungsoo;Jang, Jaeho;Park, Won-Wook;Nam, Dae-Geun
    • Journal of the Korean institute of surface engineering
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    • v.48 no.5
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    • pp.199-204
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    • 2015
  • Recently, fuel cell is a good alternative for energy source. Separator is a important component for fuel cell. In this study, The surface of separator was modified for corrosion resistance and electric conductivity. Reduced graphene oxide (rGO) was made by Staudenmaier's method. Nickel, phosphorus and rGO were coated on 6061 aluminum alloy as a separator of proton exchange membrane fuel cell by composite electroless plating. Scanning electron microscope, energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy were used to examine the morphology of Ni-P-rGO. Surface images were shown that the rGO was dispersed on the surface of Ni-P electroless plating, and nickel was combined with the un-reduced oxygen functional group of rGO.

Recent Progress in New Functional Coating Technology (신기능성 표면처리강판 제조기술의 최근 진보)

  • Kim, Tae-Yeop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.37-37
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    • 2012
  • The coated steels, mainly with zinc by either hot-dip galvanizing or electroplating, are widely used for panels of automotive, electrical appliances and construction, whose size of world market have reached 130 million tons in 2008. Current issues for the coated steels can be integrated in terms of high functionality, low cost, environment-friend and available resource. The best solution can be provided if thin layer coating with higher quality is produced by an eco-friendly process, and PVD, physical vapor deposition, can be an alternative practice to existing coating processes. PVD technologies have been very common ones in electronic and semiconductor industries, but recognized as non-profitable processes for the coated steels due to low process speed and lack of continuous operation skills. Systematic researches from 1990s in Europe, even though discouraged by a shutdown of the first Japanese PVD coating plant in 1999, have realized several continuous PVD coating plants, and also enhanced launching of developments in steel industries. To be successful with PVD coating technologies over existing ones, productivity to meet economics should be created from a highly sophisticated process. Some PVD technologies fit for the high-speed process will be introduced together with experiences from industrial applications.

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ACL Reconstruction - Remnant Preserving Technique - (전방십자인대 재건술 - 잔류조직 보존술식 -)

  • Lee, Byung-Ill;Chun, Dong-Il
    • Journal of the Korean Arthroscopy Society
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    • v.13 no.2
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    • pp.97-104
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    • 2009
  • Optimal treatment of the torn anterior cruciate ligament (ACL) remains controversial. The complexity of surgically reproducing the natural biomechanical and anatomical function of the ACL has led to a diversity of reconstructive procedures. Controversy continues to exist regarding the best reconstructive procedure for the ACL deficient knee, but currently, there is no ideal method. Because of the increased frequency of ACL injury and the functional impairment resulting from that, the role of mechanoreceptors in the ACL recently has attracted considerable attention. Proper reconstruction of the ruptured ACL does not always have good results. Success after operation may depend not only on the mechanical stability but also on the quality of recovery of proprioception. It is well known that most ACL are ruptured in proximal half and most mechanoreceptors have been reported to be located in the subsynovial layer and near the tibial insertion of the ACL. Expected roles of tibial remnant is to enhance the revascularization and cellular proliferation of the graft, to preserve proprioceptive function, and to be able to acquire anatomical placement of the graft without roof impingement. The remnant of the ruptured ACL has been removed to clearly visualize the ACL footprint or decrease the risk of impingement and Cyclops lesion in most current techniques for ACL reconstruction. Therefore it seems reasonable to assume that preserving the tibial remnant as much as possible as a source of reinnervation, if technically possible without causing impingement, would be of potential benefit to the patient. In addition, it will facilitate the vascular ingrowth and ligamentization of the grafted ACL.

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Molecular dynamics studies of interaction between hydrogenand carbon nano-carriers

  • Wang, Yun-Che;Wu, Chun-Yi;Chen, Chi;Yang, Ding-Shen
    • Coupled systems mechanics
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    • v.3 no.4
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    • pp.329-344
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    • 2014
  • In this work, quantum molecular dynamics simulations (QMD) are preformed to study the hydrogen molecules in three types of carbon nanostructures, $C_{60}$ fullerene, (5,5) and (9,0) carbon nanotubes and graphene layers. Interactions between hydrogen and the nanostructures is of importance to understand hydrogen storage for the development of hydrogen economy. The QMD method overcomes the difficulties with empirical interatomic potentials to model the interaction among hydrogen and carbon atoms in the confined geometry. In QMD, the interatomic forces are calculated by solving the Schrodinger's equation with the density functional theory (DFT) formulation, and the positions of the atomic nucleus are calculated with the Newton's second law in accordance with the Born-Oppenheimer approximation. It is found that the number of hydrogen atoms that is less than 58 can be stored in the $C_{60}$ fullerene. With larger carbon fullerenes, more hydrogen may be stored. For hydrogen molecules passing though the fullerene, a particular orientation is required to obtain least energy barrier. For carbon nanotubes and graphene, adsorption may adhere hydrogen atoms to carbon atoms. In addition, hydrogen molecules can also be stored inside the nanotubes or between the adjacent layers in graphite, multi-layer graphene.

Bacterial community analysis of stabilized soils in proximity to an exhausted mine

  • Park, Jae Eun;Lee, Byung-Tae;Kim, Byung-Yong;Son, Ahjeong
    • Environmental Engineering Research
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    • v.23 no.4
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    • pp.420-429
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    • 2018
  • Soil stabilization is a soil remediation technique that reduces the mobility of heavy metals in soils. Although it is a well-established technique, it is nonetheless essential to perform a follow-up chemical assessment via a leaching test to evaluate the immobilization of heavy metals in the soil matrix. Unfortunately, a standard chemical assessment is not sufficient for evaluation of the biological functional state of stabilized soils slated for agricultural use. Therefore, it is useful to employ a pyrosequencing-based microbial community analysis for the purpose. In this study, a recently stabilized site in the proximity of an exhausted mine was analyzed for bacterial diversity, richness, and relative abundance as well as the effect of environmental factors. Based on the Shannon and Chao1 indices and rarefaction curves, the results showed that the stabilized layer exhibited lower bacterial diversity than control soils. The prevalence of dominant bacterial populations was examined in a hierarchical manner. Relatively high abundances of Proteobacteria and Methylobacter tundripaludum were observed in the stabilized soil. In particular, there was substantial abundance of the Methylobacter genus, which is known for its association with heavy metal contamination. The study demonstrated the efficacy of (micro)biological assessment for aiding in the understanding and post-management of stabilized soils.

Analysis on an improved resistance tuning type multi-frequency piezoelectric spherical transducer

  • Qin, Lei;Wang, Jianjun;Liu, Donghuan;Tang, Lihua;Song, Gangbing
    • Smart Structures and Systems
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    • v.24 no.4
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    • pp.435-446
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    • 2019
  • The existing piezoelectric spherical transducers with fixed prescribed dynamic characteristics limit their application in scenarios with multi-frequency or frequency variation requirement. To address this issue, this work proposes an improved design of piezoelectric spherical transducers using the resistance tuning method. Two piezoceramic shells are the functional elements with one for actuation and the other for tuning through the variation of load resistance. The theoretical model of the proposed design is given based on our previous work. The effects of the resistance, the middle surface radius and the thickness of the epoxy adhesive layer on the dynamic characteristics of the transducer are explored by numerical analysis. The numerical results show that the multi-frequency characteristics of the transducer can be obtained by tuning the resistance, and its electromechanical coupling coefficient can be optimized by a matching resistance. The proposed design and derived theoretical solution are validated by comparing with the literature given special examples as well as an experimental study. The present study demonstrates the feasibility of using the proposed design to realize the multi-frequency characteristics, which is helpful to improve the performance of piezoelectric spherical transducers used in underwater acoustic detection, hydrophones, and the spherical smart aggregate (SSA) used in civil structural health monitoring, enhancing their operation at the multiple working frequencies to meet different application requirements.