• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.3
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• pp.243-248
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• 2013

Internal combustion engines typically expel 30%-40% of the energy supplied by fuel to the environment through their exhaust system. Therefore, further significant improvements in the thermal efficiency of IC engines are possible by recovering the waste heat from the engine exhaust gas. With this fact in mind, a numerical simulation was carried out to investigate the potential of using thermoelectric generation with an internal combustion engine for waste heat recovery. Physical parameters such as the exhaust temperature and mass flow rate were evaluated in the exhaust system, and the optimum location for inserting a thermoelectric generator (TEG) into the system was determined. The TEG will be located in the exhaust system and will use the energy flow between the warmer exhaust gas and the external environment. The optimum position of the temperature distribution and the TEG performance were predicted through numerical analysis. The experimental results obtained showed that the power output significantly increases with the temperature difference between the cold and hot sides of the TEG.

• Journal of Advanced Marine Engineering and Technology
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• v.35 no.4
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• pp.414-420
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• 2011

Thermal stress analysis of a planar anode-supported SOFC considering electrochemical reactions has been performed under operating conditions where average current density varies from 0 to 2000 $A/m^2$. For the case of the 2000 $A/m^2$ operating condition, Structural stress analysis based on the temperature distributions obtained from the CFD analysis of the unit cell has also been done. From this one way Fluid-Structure Interaction(FSI) analysis, Maximum Von-Mises stress under negligible temperature gradient fields occurs when cell components are perfectly bonded. The maximum stress of the electrolyte, cathode and anode in a unit cell SOFC is 262.58MPa, 28.55MPa and 15.1MPa respectively. The maximum thermal stress is critically dependent on static friction coefficient.

• Bulletin of the Korean Chemical Society
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• v.19 no.6
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• pp.661-666
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• 1998

Active reaction sites and electrochemical O2 reduction kinetics on La_{1-x}Sr_xMnO_{3+{\delta}} (x=0.1-0.4)/YSZ (yttria-stabilized zirconia) electrodes are investigated in the temperature range of 700-900 ℃ at $Po_2=10^{-3}$-0.21 atm. Results of the steady-state polarization measurements, which are formulated into the Butler-Volmer formalism to extract transfer coefficient values, lead us to conclude that the two-electron charge transfer step to atomically adsorbed oxygen is rate-limiting. The same conclusion is drawn from the $Po_2$-dependent ac impedance measurements, where the exponent m in the relationship of $I_o$ (exchange current density) ∝ $P_{o_{2}}^m$ is analyzed. Chemical analysis is performed on the quenched Mn perovskites to estimate their oxygen stoichiometry factors (δ) at the operating temperature (700-900 ℃). Here, the observed δ turns out to become smaller as both the Sr-doping contents (x) and the measured temperature increase. A comparison between the 8 values and cathodic activity of Mn perovskites reveals that the cathodic transfer coefficients $({\alpha}_c)$ for oxygen reduction reaction are inversely proportional to δ whereas the anodic ones $({\alpha}_a)$ show the opposite trend, reflecting that the surface oxygen vacancies on Mn perovskites actively participate in the $O_2$ reduction reaction. Among the samples of x= 0.1-0.4, the manganite with x=0.4 exhibits the smallest 8 value (even negative), and consistently this electrode shows the highest ${\alpha}_c$ and the best cathodic activity for the oxygen reduction reaction.

• KEPCO Journal on Electric Power and Energy
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• v.7 no.1
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• pp.161-165
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• 2021

In general, SOFCs mainly use Ni-YSZ cermet, a mixture of Ni and YSZ, as an anode material, which is stable in a high-temperature reducing atmosphere. However, when SOFCs have operated at a high temperature for a long time, the structural change of Ni occurs and it results in the problem of reducing durability and efficiency. Accordingly, a development of a new anode material that can replace existing nickel and exhibits similar performance is in progress. In this study, SrTiO₃, which is a perovskite-based mixed conductor and one of the candidate materials, was used. In order to increase the electrical conduction properties, Y_0.08Sr_0.92Fe_0.3Ti_0.7O₃, doped with 0.08 mol of Y³⁺ in Sr-site and 0.03 mol of transition metal Fe³⁺ in Ti-site, was synthesized and its chemical diffusion coefficient and reaction constant were measured. Its electrical conductivity changes were also observed while changing the oxygen partial pressure at a constant temperature. The performance as a candidate electrode material was verified by predicting the defect area through the electrical conductivity pattern according to the oxygen partial pressure.

• Journal of Energy Engineering
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• v.11 no.2
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• pp.90-98
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• 2002

The effects of swirl and combustion parameters on the performance and emission in a turbo-charged D.I. diesel engine of the displacement 9.4L were studied experimentally in this paper. Generally the swirl in the combustion process of diesel engine promotes mixing of the injection fuel and the intake air. It is a major factor to improve the engine performance because the fuel consumption and NO$_{x}$ is trade-off according to the high temperature and high pressure of combustion gas in a turbocharged D.I. diesel engine, it's necessary to thinking over the intake and exhaust system, the design of combustion bowl and so on. In order to choose a turbocharger of appropriate capacity. As a result of steady flow test, when the swirl ratio is increased, the mean flow coefficient is decreased, whereas the gulf factor is increased. Also, through engine test its can be expected to meet performance and emissions by optimizing the main parameter's; the swirl ratio is 2.43, injection timing is BTDC 13$^{\circ}$ CA, compression ratio is 16, combustion bowl is re-entrant 5$^{\circ}$, nozzle hole diameter is $\Phi$0.28*6, turbocharger is GT40 model which are compressor A/R 0.58 and turbine A/R 1.19.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.4
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• pp.600-609
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• 2001

WSGGM based low-resolution spectral model for calculating radiation transfer in combustion gases is applied to estimate self-absorption of radiation energy in one-dimensional opposed flow flames. Development of such a model is necessary in order to enable detailed chemistry-radiation interaction calculations including self-absorption. Database of band model parameters which can be applied to various one-dimensional opposed flow diffusion and partially premixed flames is created. For the validation of the model and database, low resolution spectral intensities at fuel exit side are calculated and compared with the results of a narrow band model with those based on the Curtis-Godson approximation. Good agreements have been found between them. The resulting radiation model is coupled to the OPPDIF code to calculate the self-absorption of radiant energy and compared with the results of an optically thin calculation and the results of a discrete ordinates method in conjunction with the statistical narrow band model. Significant self-absorption of radiation is found for the flames considered here particularly for the fuel side of the reacting zone. However, the self-absorption does not have significant effects on the flame structure in this case. Even in the case of the low velocity diffusion flame and the partially premixed flame of low equivalence ratio, the effects of self-absorption of radiation on the flame temperature and production of minor species are not significant.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.1
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• pp.21-26
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• 2011

Ni-YSZ (Yttria Stabilized Zirconia) composite powders were fabricated by glycine nitrate process. The prepared powders were sintered at $1300{\sim}1400^{\circ}C$ for 4 h in air and reduced at $1000^{\circ}C$ for 2 h in a nitrogen and hydrogen atmosphere. The microstructure, electrical conductivity, thermal expansion and mechanical properties of the Ni-YSZ cermets have been investigated with respect to the volume contents of Ni. A porous microstructure consisting of homogeneously distributed Ni and YSZ phases together with well-connected grains was observed. It was found that the open porosity, electrical conductivity, thermal expansion and bending strength of the cermets are sensitive to the volume content of Ni. The Ni-YSZ cermet containing 40 vol% Ni was ascertained to be the optimum composition. This composition offers sufficient open porosity of more than 30 %, superior electrical conductivities of 917.4 S/cm at $1000^{\circ}C$ and a moderate average thermal expansion coefficient of $12.6{\times}10^{-6}^{\circ}C^{-1}$ between room temperature and $1000^{\circ}C$.

• Journal of the Korean Institute of Gas
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• v.25 no.2
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• pp.28-33
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• 2021

With the recent growing interest in eco-friendly cars, as interest in eco-friendly cars increases, interest and purchase of hydrogen fuel cell vehicles that do not emit pollutants are increasing. Recently, the government is supporting the expansion of hydrogen charging station and localization of core parts according to the government's hydrogen energy dissemination policy. In this study, the flow characteristics of the hydrogen flow control valve were investigated. As the differential pressure increases, the mass flow rate and flow coefficient tend to be different from the volume flow rate. And it was confirmed that it affects the hydrogen temperature due to the nozzle effect in the bottleneck section, and the change in density affects the mass flow rate.

• Journal of Welding and Joining
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• v.11 no.4
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• pp.70-78
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• 1993

An attempt was made to investigate the effect of brazing time on microstructure, microhardness, and corrosion of Zircaloy -4as well as the beryllium diffusion into its sheet. The sheets were coated with beryllium and brazed at $1020^{\circ}C$ for 20-40 minutes in $2{\times}10^{-5}$ torr vacuum atmosphere. 1. Microstructurally the brazed zone was largely divided into three regions: a region of continuous or partially formed of eutectic liquid films along grain boundaries; a region of precipitation in both grains and grain boundaries; a region of elongated wide structure of .alpha.-laths, which was not affected by beryllium. 2. Due to the precipitates, the beryllium-migrated region was hardened and the width of the hardened region increased with increasing brazing time. 3. Beryllium brazed Zircaloy -4 sheets showed a higher corrosion rate than those of as-received and heat-treated at a brazing temperature. 4. Diffusion coefficient of beryllium into Zircaloy -4 at $1020^{\circ}C$ for 30 minutes was $7.67{\times}10^{-7}cm^2/sec.$ It seemed that Be penetrated Zircaloy -4 by forming eutectic liquid films along grain boundaries in the proximity of Be/Zr interface and it, thereafter, diffused into Zircaloy mainly by interstitial solid solution.

• Proceedings of the KWS Conference
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• 2002.10a
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• pp.694-699
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• 2002

In autobody assembly, thin-wall, tubular connections have been used for the frame structure. Recent interest in light materials, such as aluminum or magnesium alloys, has been rapidly growing for weight reduction and fuel efficiency. Due to higher thermal expansion coefficient, low stiffness/strength, and low softening temperature of aluminum and magnesium alloys, control of welding-induced distortion in these connections becomes a critical issue. In this study, the material sensitivity to welding distortion was investigated using a T-tubular connection of three types materials; low carbon steel (A500 Gr. A), aluminum alloy (5456-H116) and magnesium alloy (AZ91C-T6). An uncoupled thermal and mechanical finite element analysis scheme using the ABAQUS software program was developed to model and simulate the welding process, welding procedure and material behaviors. The predicted angular distortions were correlated to the cumulative plastic strains. A unique relationship between distortion and plastic strains exists for all three materials studied. The amount of distortion is proportional to the magnitude and distribution of the cumulative plastic strains in the weldment. The magnesium alloy has the highest distortion sensitivity, followed by the other two materials with the steel connection having the least distortion. Results from studies of thin-aluminum plates show that welding distortion can be minimized by reducing the cumulative plastic strains by preventing heat diffusion into the base metal using a strong heat sink placed directly beneath the weld. A rapid cooling method is recommended to reduce welding distortion of magnesium tubular connections.