• 공업화학
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• 제28권2호
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• pp.186-192
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• 2017

본 연구에서는 OIMS90과 NP12 계면활성제 혼합물을 사용하여 물/벙커 C 오일 비율, 계면활성제 농도 및 조성, 유화 시간, 교반 속도 및 시간, 온도 등을 변화시키면서 유중수적형(water-in-oil, W/O) 에멀젼 연료를 제조하였다. OIMS90과 NP12 계면활성제 혼합물을 사용하여 제조한 에멀젼 연료는 벙커 C 오일에 비하여 미세먼지, $NO_2$, CO, $CO_2$ 및 $SO_2$ 등의 연소배기 가스 중의 대기 오염물 방출을 감소시키는데 효과적이며, 특히 계면활성제 조성 OIMS90/NP12 = 4 : 6, 계면활성제 농도 500 ppm, 수분 함량 10%을 사용하여 $80^{\circ}C$에서 제조한 에멀젼 연료가 배기가스 오염물 저감 효과가 가장 큰 것을 확인하였다. 또한 보일러 효율 측정 시험 결과, 에멀젼 연료가 벙커 C 오일과 비교하여 우수한 디젤 엔진 에너지 효율을 나타내었다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제16권5호
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• pp.90-96
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• 2011

Simultaneous removal of heavy metals (Cd, Pb) and diesel-fuel from a soil column was evaluated by respectively flushing with sodium dodecyl sulfate (SDS) solution, mixture of SDS and sodium iodide (SDS + NaI), and surfactant foam (SDS + NaI foam). First, this study evaluated these flushing methods to the heavy metals only-contaminated soil for removal of heavy metals from the heavy-metal only contaminated soil column. After 7 pore volume flushing of the soil column, Cd removal efficiencies from the soil were 40% by SDS solution, 50% by SDS + NaI mixture, and 60% by surfactant foam. The flushing results implied that anionic surfactant and ligand can be efficiently applied to extraction of Cd from the heavy metal contaminated soil. Furthermore, surfactant foam flushing showed an increased flushing efficiency with enhancing the contact between surfactant solution and soil. However, Pb removal efficiency by these flushing methods did not show any difference unlike those of Cd. Second, this study eventually evaluated flushing methods for simultaneous removal of heavy metals and diesel-fuel from the soil column with 7 pore volume flushing. Diesel-fuel removal efficiencies were 50% by SDS + NaI flushing and 90% by SDS + NaI foam flushing. Cd removal efficiency by the foam flushing reached to 80% which was higher than the result of the previous heavy metals onlycontaminated soil experiment. This result implied that diesel-fuel could act as a metal-solvent while it contacted to heavy metals present in the soil. This study clearly showed that surfactant foam flushing simultaneously removed heavy metals and diesel fuel from the soil column.

• 한국항공우주학회지
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• 제37권4호
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• pp.383-391
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• 2009

JP-7/산소 혼합기의 데토네이션 파 특성을 상세 반응 기구로부터 얻은 일 단계 유도 변수 모델을 (IPM) 이용하여 살펴보았다. 탄화수소 혼합기에 대한 상세 화학 반응 모델로 부터 신뢰할 만한 일 단계 반응 모델을 얻기 위한 일반적 과정을 본 연구에서 제시하였다. IPM은 상세 반응 모델 라이브러리로부터 획득한 유도 시간 데이터베이스를 재구성하여 얻었으며, 상세 반응 모델에 의한 결과와 비교하여 확인하였다. 이후 IPM을 유체역학해석 코드에 적용하였으며, 데토네이션 파 전파에 대한 수치해석에 이용하였다. 수치해석 결과는 탄화수소 연료 연소의 상세 반응 기구를 직접 적용해서는 가능하지 않은, JP-7/산소 혼합기의 데토네이션 파 전파 특성의 상세한 특징을 보여주었다.

• 오토저널
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• 제14권3호
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• pp.71-79
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• 1992

Recently, air pollution and energy security problems have necessitated the development of alternative fuel vehicles. As an alternative fuel vehicle FFV(Flexible Fuel Vehicle) which can be operated by and mixture between gasoline and M85(methanol 85% and gasoline 15% by vol. percent) has been drawing great attention. But poor cold startability of high methanol- content fuel which is characteristic of lower fuel volatility and higher latent heat of vaporization than gasoline is one of the major problems to be solved for the development of FFV. In this paper, important factors influencing cold startability of general S.I. engines are described. And, so-me cost-effective and practical methods were investigated in view of the optimization of fuel-ing parameters and ignition system for M85 fuel. The test results showed good startability up to (-22)-(-23).deg.C.

• 한국자동차공학회논문집
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• 제9권3호
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• pp.9-17
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• 2001

This paper is the second of 3 companion papers which investigate axial stratification process. In-cylinder fuel behavior has been investigated in the port injected Sl engine by visualizing for the purpose of understanding stratification. Planar laser light sheet from an Nd:YAG laser has been illuminated through the transparent quartz cylinder of the single cylinder optical engine and the Mie scattered light has been captured through the quartz window in the piston head with an ICCD camera. Fuel has been replaced with an air-ethanol mixture to utilize atomized fuel spray fur the visualization purposes. This results have been compared with steady flow concentration measurement. For low/medium swirl port, the early injection makes such a fuel distribution state that is upper-rich, middle-lean and lower-rich along the combustion chamber and cylinder by tumbling motion. On the other hand, the late injection induces upper-rich, middle-lean and lower-rich state due to the short fuel penetration.

• 한국자동차공학회논문집
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• 제9권3호
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• pp.18-26
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• 2001

This paper is the third of 3 companion papers which investigate axial stratification process. In-cylinder fuel behavior has been investigated in the port injected SI engine by visualizing for the purpose of understanding stratification. Planar laser light sheet from an Nd:YAG laser has been illuminated through the transparent quartz cylinder of the single cylinder optical engine and the Mie scattered light has been captured through the quartz window in the piston head with an ICCD camera. Fuel has been replaced with an air-ethanol mixture to utilize atomized fuel spray for the visualization purposes. This results have been compared with steady flow concentration measurement. In high swirl port, the most fuel remains at combustion chamber and upper cylinder region without being affected by injection timing. The macro-distributed state is not changed but the difference of the amount of fuel around the spark plug varies according to injection timing, which determines LML.

• 한국응용과학기술학회지
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• 제24권4호
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• pp.377-382
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• 2007

We designed capacitance sensor in order to examine characteristics of W/O type emulsified fuel, so it concluded the following conclusions. The capacitance value of emulsified fuel, using with capacitance sensor, increases as water content increases due to the coalescence. When surfactant increases, the capacitance value decreases, the condition of W/O type emulsified fuel was maintained stably. There was revealed the capacitance value difference of W/O type emulsified fuel in in according to water content. We checked the phase separation of emulsified fuel with the capacitance value difference. The surfactant(HLB=5.4) had better stable condition than surfactant(HLB=4.3). Also, we confirmed that two mixture surfactants were better than one surfactant.

• Journal of Advanced Marine Engineering and Technology
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• 제23권1호
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• pp.88-95
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• 1999

This study investigates the effects of different kind fuels on the flame structure by using the numerical simulation in triple flame made by a co-flowing fuels-air stream based on the elementary chemical reaction mechanism. Methane and Hydrogen were used as fuel for this study. In order to interpret the result of the study on numerical simulation Skeletal chemistry is employe as the elementary chemical reaction mechanism for methane Gutheil's as an offset ele-mentary chemical reaction mechanism for hydrogen. The result of this study is as follows. In com-parison between the apparent burning velocity change of triple flame and the one-dimensional pre-mixed flame hydrogen fuel flame is higher than methane fuel flame. The flame thrusts out for-ward in the down stream of the boundary between air-fuel mixture and air stream and a part of the flow is bent and forks out in this protruding flame so that a triple flame is originated.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 1999년도 춘계 학술발표회 논문집
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• pp.89-93
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• 1999

Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

• 해양환경안전학회지
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• 제16권3호
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• pp.301-306
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• 2010

DME는 환경 친화적인 특성으로 인해 현재 전 세계적으로 주목을 받고 있다. 지금까지 DME는 매연을 적게 생산하는 청정 에너지라는 특성으로 인해 디젤 자동차의 주요 대체 에너지로서 연구되어 왔다. 이에 본 연구에서는 에틸렌 대향류 확산화염에 DME를 5%, 14% 및 30% 혼합했을 때, DME의 혼합 비율에 따른 매연의 수밀도 및 크기에 대한 영향을 조사하였다. 레이저 투과법 및 산란법을 이용해 수밀도 및 크기를 측정하였다. 그 결과 DME를 30% 혼합한 경우에는 매연이 감소한 반면, 5%와 14%의 혼합 비율에서는 매연이 증가하는 경향을 나타내었다. 이 결과는 DME가 매연 생성이 적은 청정 연료로 알려진 것과는 달리 에틸렌 확산화염 내에서는 DME의 혼합에 따라 매연 생성이 증가될 수 있다는 것을 의미한다.