• Title/Summary/Keyword: Fuel conversion

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A Study on the Electrolytic Reduction Mechanism of Uranium Oxide in a LiCl-Li$_2$O Molten Salt (LiCl-Li$_2$O 용융염계에서 우라늄 산화물의 전기화학적 금속전환 반응 메카니즘에 관한 연구)

  • 오승철;허진목;서중석;박성원
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.25-39
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    • 2003
  • This study proposed a new electrolytic reduction technology that is based on the integration of simultaneous uranium oxide metallization and Li$_2$O electrowinning. In this electrolytic reduction reaction, electrolytically reduced Li deposits on cathode and simultaneously reacts with uranium oxides to produce uranium metal showing more than 99% conversion. For the verification of process feasibility, the experiments to obtain basic data on the metallization of uranium oxide, investigation of reaction mechanism, the characteristics of closed recycle of Li$_2$O and mass transfer were carried out. This evolutionary electrolytic reduction technology would give benefits over the conventional Li-reduction process improving economic viability such as: avoidance of handling of chemically active Li-LiCl molten salt increase of metallization yield, and simplification of process.

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Optimization of soaking in aqueous ammonia pretreatment of canola residues for sugar production (당 생산을 위한 카놀라 부산물의 암모니아 침지 전처리 공정의 최적화)

  • Yoo, Hah-Young;Kim, Sung Bong;Lee, Sang Jun;Lee, Ja Hyun;Suh, Young Joon;Kim, Seung Wook
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.114.1-114.1
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    • 2011
  • Bioenergy production from lignocellulosic biomass and agriculture wastes have been attracted because of its sustainable and non-edible source. Especially, canola is considered as one of the best feedstock for renewable fuel production. Oil extracted canola and its agriculture residues are reuseable for bioethanol production. However, a pretreatment step is required before enzymatic hydrolysis to disrupt recalcitrant lignocellulosic matrix. To increase the sugar conversion, more efficient pretreatment process was necessary for removal of saccharification barriers such as lignin. Alkaline pretreatment makes the lignocellulose swollen through solvation and induces more porous structure for enzyme access. In our previous work, aqueous ammonia (1~20%) was utilized for alkaline reagent to increase the crystallinity of canola residues pretreatment. In this study, significant factors for efficient soaking in aqueous ammonia pretreatment on canola residues was optimized by using the response surface method (RSM). Based on the fundamental experiments, the real values of factors at the center (0) were determined as follows; $70^{\circ}C$ of temperature, 17.5% of ammonia concentration and 18 h of reaction time in the experiment design using central composition design (CCD). A statistical model predicted that the highest removal yield of lignin was 54% at the following optimized reaction conditions: $72.68^{\circ}C$ of temperature, 18.30% of ammonia concentration and 18.30 h of reaction time. Finally, maximum theoretical yields of soaking in aqueous ammonia pretreatment were 42.23% of glucose and 22.68% of xylose.

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Transparent Amorphous Oxide Semiconductor as Excellent Thermoelectric Materials (비정질 산화물 반도체의 열전특성)

  • Kim, Seo-Han;Park, Cheol-Hong;Song, Pung-Geun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.52-52
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    • 2018
  • Only approximately 30% of fossil fuel energy is used; therefore, it is desirable to utilize the huge amounts of waste energy. Thermoelectric (TE) materials that convert heat into electrical power are a promising energy technology. The TE materials can be formed either as thin films or as bulk semiconductors. Generally, thin-film TE materials have low energy conversion rates due to their thinness compared to that in bulk. However, an advantage of a thin-film TE material is that the efficiency can be smartly engineered by controlling the nanostructure and composition. Especially nanostructured TE thin films are useful for mitigating heating problems in highly integrated microelectronic devices by accurately controlling the temperature. Hence, there is a rising interest in thin-film TE devices. These devices have been extensively investigated. It is demonstrated that transparent amorphous oxide semiconductors (TAOS) can be excellent thermoelectric (TE) materials, since their thermal conductivity (${\kappa}$) through a randomly disordered structure is quite low, while their electrical conductivity and carrier mobility (${\mu}$) are high, compared to crystalline semiconductors through the first-principles calculations and the various measurements for the amorphous In-Zn-O (a-IZO) thin film. The calculated phonon dispersion in a-IZO shows non-linear phonon instability, which can prevent the transport of phonon. The a-IZO was measured to have poor ${\kappa}$ and high electrical conductivity compared to crystalline $In_2O_3:Sn$ (c-ITO). These properties show that the TAOS can be an excellent thin-film transparent TE material. It is suggested that the TAOS can be employed to mitigate the heating problem in the transparent display devices.

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A Study on the Characteristic and Droplet Uniformity of Spray Injection to Exhaust Gas Flow from Urea Solution Injector (Urea 수용액의 배기가스 유동장내 분무 특성과 분무 균일도에 관한 연구)

  • Oh, Jung-Mo;Cha, Won-Sim;Kim, Ki-Bum;Lee, Jin-Ha;Lee, Ki-Hyung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.3
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    • pp.83-89
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    • 2011
  • Diesel engines can produce higher fuel efficiency and lower $CO_2$ emission, they are subject to ever more stringent emission regulation. However, there are two major emission concerns fo diesel engines like such as particulate matter (PM) and nitrogen oxides (NOx). Moreover, it is not easy to satisfy the regulations on the emission of NOx and PM, which are getting more strengthened. One of the solutions is to apply the new combustion concept using multistage injection such as HCCI and PCCI. The other solution is to apply after-treatment systems. For example, lean NOx trap catalyst, Urea-SCR and others have various advantages and disadvantages Especially, Urea-SCR system have advantages such as a high conversion efficiency and a wide operation conditions. Hence the key factor to implementation of Urea-SCR technology, good mixing of urea(Ammonia) and gas, reducing Ammonia slip. Urea mixer components are required to facilitate evaporation and mixing because the liquid state of urea poses significant barriers for evaporation, and the distance to mixer is the most critical that affect mixer performance. In this study, to find out the distance from injector to mixer and simulation factor, a laser diagnostics and high speed camera are used to analyze urea injector spray characteristics and to present a distribution of urea solution in transparent manifold In addition, Droplet Uniformity Index is calculated from the acquired images by using image processing method to clarify the distribution of spray.

A study on Property of Emission Gas by the Content Variation of Urea (UREA의 함량 변화에 따른 배출가스 특성분석)

  • Kang, Hyungkyu;Doe, Jinwoo;Hwang, Inha;Im, Jaeheuk;Ha, Jonghan;Na, Byungki
    • Journal of Energy Engineering
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    • v.24 no.4
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    • pp.24-32
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    • 2015
  • National and international regulations on the exhaust gases of diesel engines are being strengthened, and a study of the combutsion engine and the post-porcessing system are in progress as a variety of ways. There are many techniques for the removal of nitrogen oxide like HC-SCR, LNT, Urea-SCR. And the technical development on the Urea-SCR owing to high conversion efficiency and fuel economy characteristics has being processed. This study investigated the physical/chemical properties of urea according to the change of the urea content, and were analysed the characteristic of exhaust gas. According to the increase of urea content, the contests of biuret aldehyde, phosphate content was increased and the changes of emission quantity of carbon monoxide, hydrocarbons and particulate matter in the exhaust gas was very slight. The emission quantity of NOx was decreased in accordance with increasing the urea content and it was shown to be more than 80 % in the urea solution having more than 30 wt%.

A Study on Nutrient Intakes in Kang Won Province (강원도 일부지역의 영양섭취실태에 관한 연구)

  • 지의상;김동원
    • The Korean Journal of Food And Nutrition
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    • v.3 no.2
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    • pp.161-168
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    • 1990
  • The survey was conducted for the period from 25 th to 29 th July, 1990. The survey area were selected the mountain area in Kang Won Province. Intake of foods and nutrients of all members in the households surveyed by means of questionnaire was computed based on number of meals a day. On the other hand, daily intake of nutrients by an individual was calculated by sex, age and type of work based on the conversion rate of RDA (Korean Recommended Dietary Allowances for Adult). 1. Status of food intake. The average food intake per person per day in surveyed area was 1103.49 g. The total intake of food was consisted of 44.17% grains, 23.31% vegetables, 10.66% fruits, respectively. These findings led us to the conclusion that people in the surveyed area depended heavily on plant foods. 2. Status of nutrient intake, 1) The average intake of Calorie was 2567.54 Cal Per day, which was slightly higher than 2500 Cal of RDA. 2) The average Intake of protein was 82.92g per day, which was higher than 70g of RDA. Though the quantity was above the RDA, it was largely from plant foods 3) The average intake of calcium was 383.93 mg per day, which was much lower than 500 mg of RDA. 4) The average intake of iron was 11.88 me per day, which was nearly the same quantity as 10 mg of RDA. 5) Intake of vitamin group were high among the inhabitants than recommended by RDA 3. The Kinds of food intake The kinds of food intake in surveyed area were totally 66 different kinds. 4. Economic status. As for the education level, almost of the food handlers finished the primary school and the average monthly income was 364,600 in surveyed area. Households used gas(100%) for fuel.

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A study on the assessment of wildland fire hazard through statistic examination and calorie analysis according to the geographical distribution of vegetation (통계적 고찰과 수목분포에 따른 열량분석을 통한 산림화재 위험성 평가에 관한 연구)

  • 김광일;김동현
    • Fire Science and Engineering
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    • v.14 no.3
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    • pp.27-32
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    • 2000
  • The assessment of wildland fire hazard is the first priority to be considered in the prevention, extinction and control of wildland fire. For the standard to measure wildland fire hazard, the wildland fire Warning System is currently being used in Korea which computes the wildland fire occurrence hazard index through a stick weight to moisture conversion formula. It shows the risk of fuel substance being exposed to fire by meteorological factors. For a comprehensive assessment of wildland fire hazards by area, the major factors'hazards need to be measured and the assessment of wildland fire needs to be conducted through historical statistic examination. Therefore, the wildland (ire outbreak frequency and its seriousness of damage are analyzed through historical statistic examination to conduct the assessment of a wildland fire hazard, and then the calorific value of a forest is analyzed through differential scanning calorimeter measurement which assesses the comparative calorific hazard according to the geographical distribution of vegetation.

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A Kinetic Study of Steam Gasification of Rice Straw, Saw Dust Biomass and Coal (볏집, 톱밥 바이오매스와 석탄의 수증기 가스화반응 Kinetics 연구)

  • Song, Byungho;Zhu, Xueyan
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.76-82
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    • 2012
  • Biomass and coal are great potential energy sources for gasification process. These solids can be gasified to produce syngas and bio-oil which can be upgraded further to transportation fuel. Two biomass and three coals have been gasified with steam in a thermobalance reactor under atmospheric pressure in order to evaluate their kinetic rate information The effects of gasification temperature ($600{\sim}850^{\circ}C$) and partial pressure of steam (30~90 kPa) on the gasification rate have been investigated. The three different types of gas-solids reaction models have been applied to the experimental data to compare their predictions of reaction behavior. The modified volumetric reaction model predicts the conversion data well, thus that model was used to evaluate kinetic parameters in this study. The gasification reactivity of five solids has been compared. The obtained activation energy of coal and biomass gasification were well in the reasonable range. The expression of apparent reaction rates for steam gasification of five solids have been proposed as basic information for the design of coal gasification processes.

Fabrication of nickel nanoparticles-embedded carbon particles by solution plasma in waste vegetable oil

  • Pansuwan, Gun;Phuksawattanachai, Surayouth;Kerdthip, Kraiphum;Sungworawongpana, Nathas;Nounjeen, Sarun;Anantachaisilp, Suranan;Kang, Jun;Panomsuwan, Gasidit;Ueno, Tomonaga;Saito, Nagahiro;Pootawang, Panuphong
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.10
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    • pp.894-898
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    • 2016
  • Solution plasma is a unique method which provides a direct discharge in solutions. It is one of the promising techniques for various applications including the synthesis of metallic/non-metallic nanomaterials, decomposition of organic compounds, and the removal of microorganism. In the context of nanomaterial syntheses, solution plasma has been utilized to produce carbon nanoparticles and metallic-carbon nanoparticle systems. The main purpose of this study was to synthesize nickel nanoparticles embedded in a matrix of carbon particles by solution plasma in one-step using waste vegetable oil as the carbon source. The experimental setup was done by simply connecting a bipolar pulsed power generator to nickel electrodes, which were submerged in the waste vegetable oil. Black powders of the nickel nanoparticles-embedded carbon (NiNPs/Carbon) particles were successfully obtained after discharging for 90 min. The morphology of the synthesized NiNPs/Carbon was investigated by a scanning electron microscope, which revealed a good dispersion of NiNPs in the carbon-particle matrix. The X-ray diffraction of NiNPs/Carbon clearly showed the co-existence of crystalline Ni nanostructures and amorphous carbon. The crystallite size of NiNPs (through the Ni (111) diffraction plane), as calculated by the Scherrer equation was found to be 64 nm. In addition, the catalytic activity of NiNPs/Carbon was evaluated by cyclic voltammetry in an acid solution. It was found that NiNPs/Carbon did not show a significant catalytic activity in the acid solution. Although this work might not be helpful in enhancing the activity of the fuel cell catalysts, it is expected to find application in other processes such as the CO conversion (by oxidation) and cyclization of organic compounds.

Methane-Steam Reforming Simulation for a High Temperature Solar Chemical Reactor (고온 태양열 화학 반응기에서의 메탄-수증기 개질반응 시뮬레이션)

  • Ko, Jo-Han;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.29 no.1
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    • pp.44-49
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    • 2009
  • Steam reforming of methane in the high temperature solar chemical reactor bas advantage in its heating method. Using concentrated solar energy as a heating source of the reforming reaction can reduce the $CO_2$ emission by 20% compared to hydrocarbon fuel. In this paper, the simulation result of methane-steam reforming on a high temperature solar chemical reactor(SCR) using Fluent 6.3.26 is presented. The high temperature SCR is designed for the Inha Dish-1, a Dish type solar concentrator installed in Songdo city. Basic SCR performance factors are referred to the former researches of the same laboratory. Inside the SCR porous metal is used for a receiver/reactor. The porous metal is carved like a dome shape on the incident side to increase the heat transfer. Also, ring-disc set of baffle is inserted in the porous metal region to increase the path length. Numerical and physical models are also used from the former researches. Methane and steam is mixed with the same mole fraction and injected into the SCR. The simulation is performed for a various inlet mass flow rate of the methane-steam mixture gas. The result shows that the average reactor temperature and the conversion rate change appreciably by the inlet mass flow rate of 0.0005 kg/s.