• Advances in Energy Research
• /
• 제1권1호
• /
• pp.53-78
• /
• 2013

Methane carbon dioxide reforming (MCDR) is a promising way of utilizing greenhouse gas for hydrogen-rich fuel production. Compared with other types of reactors, Compact Reformers (CRs) are efficient for fuel processing. In a CR, a thin solid plate is placed between two porous catalyst layers to enable efficient heat transfer between the two catalyst layers. In this study, the physical and chemical processes of MCDR in a CR are studied numerically with a 2D numerical model. The model considers the multi-component gas transport and heat transfer in the fuel channel and the porous catalyst layer, and the MCDR reaction kinetics in the catalyst layer. The finite volume method (FVM) is used for discretizing the governing equations. The SIMPLEC algorithm is used to couple the pressure and the velocity. Parametrical simulations are conducted to analyze in detail the effects of various operating/structural parameters on the fuel processing behavior.

• 유체기계공업학회:학술대회논문집
• /
• 유체기계공업학회 2005년도 연구개발 발표회 논문집
• /
• pp.240-243
• /
• 2005

This study deals with the shape optimization of a wire spacer fuel assembly of Liquid Metal Reactors (LMRs). The Response Surface based optimization Method is used as an optimization technique with the Reynolds-averaged Navier-Stokes analysis of fluid flow and heat transfer using Shear Stress Transport (SST) turbulence model as a turbulence closure. Two design variables namely, pitch to fuel rod diameter ratio and lead length to fuel rod diameter ratio are selected. The objective function is defined as a combination of the heat transfer rate and the inverse of friction loss with a weighting factor. Three level full-factorial method is used to determine the training points. In total, nine experiments have been performed numerically and the resulting datas have been analysed for optimization study. Also, a comparison has been made between the optimized surface and the reference one in this study.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2005년도 제17회 워크샵 및 추계학술대회
• /
• pp.648-654
• /
• 2005

The performance prediction of a planar-type solid oxide fuel ceil is conducted by a computational analysis. The transport processes are formulated with the help of a simplified treatment of heat generation by the electrochemical reaction. From the result of the computational analysis, it is shown that the electrochemical reaction is closely related to the transport phenomena inside a solid oxide fuel cell. Transport phenomena including heat and mass transfer have influence on the distribution of local current density and as a result, on the performance characteristics of the fuel cell. Computational analysis is also extended to the parametric study to investigate the performance behavior of the fuel cell with different amount of supplied fuel flow rates. It is also demonstrated that the mathematical formulation and computational procedures proposed in this study can be applied to prove the importance of the specific TPB(Three-Phase-Boundary) area in the manufacturing process of electrodes in a solid oxide fuel cell.

• 한국수소및신에너지학회논문집
• /
• 제11권1호
• /
• pp.19-27
• /
• 2000

The polymer electrolyte membrane fuel cell (PEMFC) system was developed. In order to enhance the performance of membrane electrode assembly (MEA), the transfer printing method of the electrocatalyst layer on membrane was developed. The $H_2/O_2$ single cell with an electrode area of $50cm^2$ was fabricated and tested using 20 wt.% Pt/C as an electrocatalyst and the commercial and hand-made MEA such as Nafion 115, Hanwha, Dow, Flemion T and Gore Select. The 100-cell PEMFC stack with an active electrode area of $300cm^2$ was designed and fabricated using 40 wt.% Pt/C and 30 wt.% Pt-Ru/C as a cathode and anode electrocatalysts, respectively. The performance of PEMFC system was obtained to be 7kW (250A at 28V) and 3.5kW (70A at 50V) at $80^{\circ}C$ by flowing $H_2/air$ and methanol reformed fuel gas/air, respectively.

• 한국세라믹학회지
• /
• 제42권12호
• /
• pp.846-853
• /
• 2005

For the performance prediction of a planar-type solid oxide fuel cell, the computational analysis of transport phenomena with a simplified treatment of heat generation by the electrochemical reaction is conducted. From the result of the computational analysis, it is shown that the electrochemical reaction is closely related to the transport phenomena inside a solid oxide fuel cell. Transport phenomena including heat and mass transfer influences on the distribution of local current density and, as a result, on the performance characteristics of the fuel cell. Computational analysis is also extended to the parametric study to investigate the performance behavior of the fuel cell with different amount of supplied fuel flow rates. It is also demonstrated that the mathematical formulation and computational procedures proposed in this study can be applied to prove the importance of the specific TPB area in the manufacturing process of electrodes in solid oxide fuel cells.

• Nuclear Engineering and Technology
• /
• 제54권12호
• /
• pp.4499-4513
• /
• 2022

Spent fuel behavior of dry storage was simulated in a continuous state from steady-state operation by modifying FRAPCON-4.0 to incorporate spent fuel-specific fuel behavior models. Spent fuel behavior of a typical PWR was compared with that of NuScale Power Module (NPM^TM). Current PWR discharge burnup (60 MWd/kgU) gives a sufficient margin to the hoop stress limit of 90 MPa. Most hydrogen precipitation occurs in the first 50 years of dry storage, thereby no extra phenomenological safety factor is identified for extended dry storage up to 100 years. Regulation for spent fuel management can be significantly alleviated for LWR-based SMRs. Hydride embrittlement safety criterion is irrelevant to NuScale spent fuels; they have sufficiently lower plenum pressure and hydrogen contents compared to those of PWRs. Cladding creep out during dry storage reduces the subchannel area with burnup. The most deformed cladding outer diameter after 100 years of dry storage is found to be 9.64 mm for discharge burnup of 70 MWd/kgU. It may deteriorate heat transfer of dry storage by increasing flow resistance and decreasing the view factor of radiative heat transfer. Self-regulated by decreasing rod internal pressure with opening gap, cladding creep out closely reaches the saturated point after ~50 years of dry storage.

• 방사성폐기물학회지
• /
• 제21권3호
• /
• pp.359-370
• /
• 2023

The thermal integrity of spent nuclear fuels has to be maintained during their long-term dry storage. The detailed temperature distributions of spent fuel assemblies are essential for evaluating the integrity of their dry storage systems. In this study, a subchannel analysis model was developed for a canister of a single fuel assembly using the COBRA-SFS code. The thermal parameters affecting the peak cladding temperature (PCT) of the spent fuel assembly were identified, and sensitivity analyses were performed based on these parameters. The subchannel analysis results indicated the presence of a recirculation flow, based on natural convection, between the fuel assembly and downcomer region. The sensitivity analysis of the thermal parameters indicated that the PCT was affected by the emissivity of the fuel cladding and basket, convective heat transfer coefficient, and thermal conductivity of the fluid. However, the effects of the wall friction factor of the canister, form loss coefficient of the grid spacers, and thermal conductivities of the solid materials, on the PCT were predominantly ignored.

• Bulletin of the Korean Chemical Society
• /
• 제34권12호
• /
• pp.3649-3653
• /
• 2013

As anode fabrication with different materials has been proven to be a successful alternative for enhancing power generation in the microbial fuel cells, a new approach to improved performance of MFCs with the use of menadione/carbon powder composite-modified carbon cloth anode has been explored in this study. Menadione has formal potential to easily accept electrons from the outer membrane cytochromes of electroactive bacteria that can directly interact with the solid surface. Surface bound menadione was able to maintain an electrical wiring with the trans-membrane electron transfer pathways to facilitate extracellular electron transfer to the electrode. In a single chamber air cathode MFC inoculated with aerobic sludge, maximum power density of $1250{\pm}35mWm^{-2}$ was achieved, which was 25% higher than that of an unmodified anode. The observed high power density and improved coulomb efficiency of 61% were ascribed to the efficient electron shuttling via the immobilized menadione.

• Journal of Mechanical Science and Technology
• /
• 제20권3호
• /
• pp.391-398
• /
• 2006

This work involves a method for modeling the flow distribution in the stack of a solid oxide fuel cell. Towards this end, a three dimensional modeling of the flow through a Solid Oxide Fuel Cell (SOFC) stack was carried out using the CFD analysis. This paper examines the efficacy of using cold flow analysis to describe the flow through a SOFC stack. It brings out the relative importance of temperature effect and the mass transfer effect on the SOFC manifold design. Another feature of this study is to utilize statistical tools to ascertain the extent of uniform flow through a stack. The results showed that the cold flow analysis of flow through SOFC might not lead to correct manifold designs. The results of the numerical calculations also indicated that the mass transfer across membrane was essential to correctly describe the cathode flow, while only temperature effects were sufficient to describe the anode flow in a SOFC.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 추계학술대회 논문집
• /
• pp.143-146
• /
• 2009

The metal-supported SOFC has beed developed as a new concept of SOFC which has higher mechanical strength. However, the mass transfer rate in this type of SOFC may be decreased due to the contact layer and the support layer and that can cause the low performance. Therefore, numerical analysis of the heat and mass transfer characteristics in a metal-supported solid oxide fuel cell(SOFC) is studied in this paper. Governing equations and electrochemical equations are calculated simultaneously. And the numerical results are compared with the experimental results for the code validation. The current density, temperature, and pressure drop are suggested as numerical results.