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Review and Strategy for Study on Korean Buffer Characteristics Under the Elevated Temperature Conditions: Mineral Transformation and Radionuclide Retardation Perspective

  • Park, Tae-Jin;Yoon, Seok;Lee, Changsoo;Cho, Dong Keun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.4
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    • pp.459-467
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    • 2021
  • In the majority of countries, the upper limit of buffer temperature in a repository is set to below 100℃ due to the possible illitization. This smectite-to-illite transformation is expected to be detrimental to the swelling functions of the buffer. However, if the upper limit is increased while preventing illitization, the disposal density and cost-effectiveness for the repository will dramatically increase. Thus, understanding the characteristics and creating a database related to the buffer under the elevated temperature conditions is crucial. In this study, a strategy to investigate the bentonite found in Korea under the elevated temperatures from a mineral transformation and radionuclides retardation perspective was proposed. Certain long-term hydrothermal reactions generated the bentonite samples that were utilized for the investigation of their mineral transformation and radionuclide retardation characteristics. The bentonite samples are expected to be studied using in-situ synchrotron-based X-Ray Diffraction (XRD) technique to determine the smectite-to-illite transformation. Simultaneously, the 'high-temperature and high-pressure mineral alteration measurement system' based on the Diamond Anvil Cell (DAC) will control and provide the elevated temperature and pressure conditions during the measurements. The kinetic models, including the Huang and Cuadros model, are expected to predict the time and manner in which the illitization will become detrimental to the performance and safety of the repository. The sorption reactions planned for the bentonite samples to evaluate the effects on retardation will provide the information required to expand the current knowledge of repository optimization.

A Study for Analysis of Micro Heat Grid Configuration and Deduction of Optimal Size in Hydrogen Cities (수소도시 내 마이크로 히트그리드 구성 방안 및 최적 규모 산정 연구)

  • JONGJUN LEE;SEUL-YE LIM;KYOUNG A SHIN;NAMWOONG KIM;DO HYEONG KIM;CHEOL GYU PARK
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.6
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    • pp.845-855
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    • 2022
  • In response to climate change, the world is continuing efforts to reduce fossil fuels, expand renewable energy, and improve energy efficiency with the goal of achieving carbon neutrality. In particular, R&D is being made on the value chain covering the entire cycle of hydrogen production, storage, transportation, and utilization in order to shift the energy supply system to focus on hydrogen energy. Hydrogen-based energy sources can produce heat and electricity at the same time, so it is possible to utilize heat energy, which can increase overall efficiency. In this study, calculation of the optimal scale for hydrogen-based cogeneration and the composition of heat sources were reviewed. It refers to a method of the optimal heat source size according to the external heat supply and heat storage to be considered. The results of this study can be used as basic data for establishing a hydrogen-based energy supply model in the future.

A Study on the Design of the Grid-Cell Assessment System for the Optimal Location of Offshore Wind Farms (해상풍력발전단지의 최적 위치 선정을 위한 Grid-cell 평가 시스템 개념 설계)

  • Lee, Bo-Kyeong;Cho, Ik-Soon;Kim, Dae-Hae
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.7
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    • pp.848-857
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    • 2018
  • Recently, around the world, active development of new renewable energy sources including solar power, waves, and fuel cells, etc. has taken place. Particularly, floating offshore wind farms have been developed for saving costs through large scale production, using high-quality wind power and minimizing noise damage in the ocean area. The development of floating wind farms requires an evaluation of the Maritime Safety Audit Scheme under the Maritime Safety Act in Korea. Floating wind farms shall be assessed by applying the line and area concept for systematic development, management and utilization of specified sea water. The development of appropriate evaluation methods and standards is also required. In this study, proper standards for marine traffic surveys and assessments were established and a systemic treatment was studied for assessing marine spatial area. First, a marine traffic data collector using AIS or radar was designed to conduct marine traffic surveys. In addition, assessment methods were proposed such as historical tracks, traffic density and marine traffic pattern analysis applying the line and area concept. Marine traffic density can be evaluated by spatial and temporal means, with an adjusted grid-cell scale. Marine traffic pattern analysis was proposed for assessing ship movement patterns for transit or work in sea areas. Finally, conceptual design of a Marine Traffic and Safety Assessment Solution (MaTSAS) was competed that can be analyzed automatically to collect and assess the marine traffic data. It could be possible to minimize inaccurate estimation due to human errors such as data omission or misprints through automated and systematic collection, analysis and retrieval of marine traffic data. This study could provides reliable assessment results, reflecting the line and area concept, according to sea area usage.

Development of a continuous electrolytic system with an ion exchange membrane for pH-control with only one discharge of electrolytic solution and its characteristics (단일 전해액 배출만을 가지는 pH조절용 연속식 이온 교환막 전해 시스템의 개발과 그 특성)

  • Kim Kwang-Wook;Kim In-Tae;Park Geun-Il;Lee Eil-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.4
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    • pp.269-278
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    • 2005
  • In order to produce only a pH-controlled solution without discharging any unwanted solution, this work has developed a continuous electrolytic system with a pH-adjustment reservoir being placed before an ion exchange membrane-equipped electrolyzer, where as a target solution was fed into the pH-adjustment reservoir, some portion of the solution in the pH-adjustment reservoir was circulated through the cathodic or anodic chamber of the electrolyzer depending on the type of the ion exchange membrane used, and some other portion of the solution in the pH-adjustment reservoir was discharged from the electrolytic system through the other counter chamber with its pH being controlled. The internal circulation of the pH-adjustment reservoir solution through the anodic chamber in the case of using a cation exchange membrane and that through the cathodic chamber in the case of using an anion exchange membrane could make the solution discharged from the other counter chamber effectively acidic and basic, respectively. The phenomena of the pH being controlled in the system could be explained by the electro-migration of the ion species in the solution through the ion exchange membrane under a cell potential difference between anode and cathode and its consequently-occurring non-charge equilibriums and electrolytic water- split reactions in the anodic and cathodic chambers.

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Measurement of Journal Bearing Friction Loss of Turbocharger in a Passenger Vehicle (승용차용 터보과급기의 저널 베어링 마찰 손실 측정)

  • Chung, in-Eun;Jeon, Se-Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.7
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    • pp.9-15
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    • 2018
  • The turbochargers, which are used widely in diesel and gasoline engines, are an effective device to reduce fuel consumption and emissions. On the other hand, turbo-lag is one of the main problems of a turbocharger. Bearing friction losses is a major cause of turbo lag and is particularly intense in the lower speed range of the engine. Current turbochargers are mostly equipped with floating bearings: two journal bearings and one thrust bearing. This study focused on the bearing friction at the lower speed range and the experimental equipment was established with a drive-motor, load-cell, magnetic coupling, and oil control system. Finally, the friction losses of turbochargers were measured considering the influence of the rotating speed from 30,000rpm to 90,000rpm, oil temperature from $50^{\circ}C$ to $100^{\circ}C$, and oil supply pressure of 3bar and 4bar. The friction power losses were increased exponentially to 1.6 when the turbocharger speed was increased. Friction torques decreased with increasing oil temperature and increased with increasing oil pressure. Therefore, the oil temperature and pressure must be maintained at appropriate levels.

Development of Friction Loss Measurement Device at Low Speed of Turbocharger in a Passenger Vehicle (승용차용 터보과급기의 저속 영역 마찰 손실 측정 장치 개발)

  • Chung, Jin Eun;Lee, Sang Woon;Jeon, Se Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.1
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    • pp.585-591
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    • 2017
  • Turbocharging is widely used in diesel and gasoline engines as an effective way to reduce fuel consumption. But turbochargers have turbo-lag due to mechanical friction losses. Bearing friction losses are a major cause of mechanical friction losses and are particularly intensified in the lower speed range of the engine. Current turbochargers mostly use oil bearings (two journal bearings and one thrust bearing). In this study, we focus on the bearing friction in the lower speed range. Experimental equipment was made using a drive motor, load cell, magnetic coupling, and oil control system. We measured the friction losses of the turbocharger while considering the influence of the rotation speed, oil temperature, and pressure. The friction power losses increased exponentially when the turbocharger speed increased.

Improved Treatment Technique for the Reuse of Waste Solution Generated from a Electrokinetic Decontamination System (동전기제염장치에서 발생한 폐액의 재사용을 위한 개선된 처리기술)

  • Kim, Wan-Suk;Kim, Seung-Soo;Kim, Gye-Nam;Park, Uk-Ryang;Moon, Jei-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.1
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    • pp.1-6
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    • 2014
  • A large amount of acidic waste solution is generated from the practical electrokinetic decontamination equipments for the remediation of soil contaminated with uranium. After filtration of uranium hydroxides formed by adding CaO into the waste solution, the filtrate was recycled in order to reduce the volume of waste solution. However, when the filtrate was used in an electrokinetic equipment, the low permeability of the filtrate from anode cell to cathode cell due to a high concentration of calcium made several problems such as the weakening of a fabric tamis, the corrosion of electric wire and the adhension of metallic oxides to the surface of cathode electrode. To solve these problems, sulfuric acid was added into the filtrate and calcium in the solution was removed as $CaSO_4$ precipitate. A decontamination test using a small electrokinetic equipment for 20 days indicated that Ca-removed waste solution decreased uranium concentration of the waste soil to 0.35 Bq/g, which is a similar to a decontamination result obtained by distilled water.

Study of the Electrolytic Reduction of Uranium Oxide in LiCl-Li$_{2}$O Molten Salts with an Integrated Cathode Assembly

  • Park Sung-Bin;Seo Chung-seok;Kang Dae-Seung;Kwon Seon-Gil;Park Seong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.2
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    • pp.105-112
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    • 2005
  • The electrolytic reduction of uranium oxide in a LiCl-Li$_{2}$O molten salt system has been studied in a 10 g U$_{3}$O$_{8}$ /batch-scale experimental apparatus with an integrated cathode assembly at 650$^{\circ}C$. The integrated cathode assembly consists of an electric conductor, the uranium oxide to be reduced and the membrane for loading the uranium oxide. From the cyclic voltammograms for the LiCl-3 wt$\%$ Li$_{2}$O system and the U$_{3}$O$_{8}$-LiCl-3 wt$\%$ Li$_{2}$O system according to the materials of the membrane in the cathode assembly, the mechanisms of the predominant reduction reactions in the electrolytic reactor cell were to be understood; direct and indirect electrolytic reduction of uranium oxide. Direct and indirect electrolytic reductions have been performed with the integrated cathode assembly. Using the 325-mesh stainless steel screen the uranium oxide failed to be reduced to uranium metal by a direct and indirect electrolytic reduction because of a low current efficiency and with the porous magnesia membrane the uranium oxide was reduced successfully to uranium metal by an indirect electrolytic reduction because of a high current efficiency.

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A Development of Green Transportation Design for Special Identity of Jecheon Area - centered on Exterior Design for Development of Design Business - (제천지역의 특성화를 위한 친환경운송수단 디자인개발 - 디자인비즈니스 개발을 위한 익스테리어 디자인을 중심으로 -)

  • Mun Keum-Hi
    • Archives of design research
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    • v.19 no.4 s.66
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    • pp.175-186
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    • 2006
  • In the 21C, each nation controls exhaust fumes from automobiles and makes an effort to develop alternative energy because of serious environmental problem. Jechon area has many historical and cultural archeological sites. And Jechon city sponsors various cultural events. But the way of transportation which is connected with Jecheon and around sightseeing places is general and not ready yet. Therefore, if a special means of vehicle is developed, it could play an another role of sightseeing resources. Special identity of Jecheon area for establishment of green vehicle traffic system which gives Jecheon area specific character was investigated for theoretical background. Traffic system was studied for establishment of direction through existent successful case study. Moreover content, method, structure and advantage & shortcoming etc. of vehicle that use green energy resource such as solar car, fuel cell car, hybrid car, natural gas car etc. were examined. The suitable means of vehicle for Jechon area was proposed to three directions with research and investigation. After comparison and investigation by inquiry of each section's experts, the most suitable traffic system of which energy resource of car, form of vehicles, the complement, dimension of vehicles etc. were decided. Design proposal should be drawn according to process of automobile design in decided direction. Special Exterior design of vehicle that use green energy resource connecting Jecheon and around area should be suggested in Jecheon City Hall and Chungchong-bukdo provincial office for vivify image of cleanliness area.

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Study on Hydrogen Production and CO Oxidation Reaction using Plasma Reforming System with PEMFC (고분자 전해질 연료전지용 플라즈마 개질 시스템에서 수소 생산 및 CO 산화반응에 관한 연구)

  • Hong, Suck Joo;Lim, Mun Sup;Chun, Young Nam
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.656-662
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    • 2007
  • Fuel reformer using plasma and shift reactor for CO oxidation were designed and manufactured as $H_2$ supply device to operate a polymer electrolyte membrane fuel cell (PEMFC). $H_2$ selectivity was increased by non-thermal plasma reformer using GlidArc discharge with Ni catalyst simultaneously. Shift reactor was consisted of steam generator, low temperature shifter, high temperature shifter and preferential oxidation reactor. Parametric screening studies of fuel reformer were conducted, in which there were the variations of the catalyst temperature, gas component ratio, total gas ratio and input power. and parametric screening studies of shift reactor were conducted, in which there were the variations of the air flow rate, stema flow rate and temperature. When the $O_2/C$ ratio was 0.64, total gas flow rate was 14.2 l/min, catalytic reactor temperature was $672^{\circ}C$ and input power 1.1 kJ/L, the production of $H_2$ was maximized 41.1%. And $CH_4$ conversion rate, $H_2$ yield and reformer energy density were 88.7%, 54% and 35.2% respectively. When the $O_2/C$ ratio was 0.3 in the PrOx reactor, steam flow ratio was 2.8 in the HTS, and temperature were 475, 314, 260, $235^{\circ}C$ in the HTS, LTS, PrOx, the conversion of CO was optimized conditions of shift reactor using simulated reformate gas. Preheat time of the reactor using plasma was 30 min, component of reformed gas from shift reactor were $H_2$ 38%, CO<10 ppm, $N_2$ 36%, $CO_2$ 21% and $CH_4$ 4%.