• 한국수소및신에너지학회논문집
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• 제26권2호
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• pp.127-135
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• 2015

High-Temperautre Polymer Electrolyte Membrane Fuel Cell (HT-PEMFC) with phosphoric acid-doped polybenzimidazole (PBI) membrane has high power density because of high operating temperature from 100 to $200^{\circ}C$. In fuel cell stack, heat is generated by electrochemical reaction and high operating temperature makes a lot of heat. This heat is caouse of durability and performance decrease about stack. For these reasons, heat management is important in HT-PEMFC. So, we developed HT-PEMFC model and study heat flow in HT-PEMFC stack. In this study, we placed coolant plate number per cell number ratio as variable and analysed heat flow distribution in stack.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1250-1251
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• 1997

Among the fuel cell system, solid oxide fuel cell is constructed of ceramics, so stack construction is simple, power density is very high, and there is no corrosion problem. The purpose of this research is to investigate the characteristics of state of art for SOFC.

• 전기화학회지
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• 제4권2호
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• pp.65-69
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• 2001

상온$\cdot$상압에서 운전되는 휴대전원용 연료전지 시스템에서 연료에 따른 애노드와 캐소드의 전위특성과 알코올 크로스오버의 영향 및 운전에 적합한 알코올 연료의 농도를 확인한 결과, 고분자 전해질 막을 통한 액상연료의 크로스오버는 메탄올, 에탄올, 그리고 이소프로필 알코올 모두에서 발생하였고, 고정형 연료시스템을 적용한 단위전지의 성능은 4.5 M의 메탄올이 0.23V에서 $31mW/cm^2$로 가장 우수하였다.

• 한국전기전자재료학회논문지
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• 제20권10호
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• pp.918-923
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• 2007

Fuel cell is a modular, high efficient and environmentally energy conversion device, it has become a promising option to replace the conventional fossil fuel based electric power plants. The high temperature fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. Corrosions in molten electrolytes and the electric conductivity across the oxide scale have crucial characteristics. When molten salts are involved, high temperature corrosions become severe. In this sense, corrosions of alloys with molten carbonates have the most severe material problems. Systematic investigation on corrosion behavior of Fe/21Cr/Ti or Al alloy has been done in (62+38)mol% (Li+K)$CO_3$ melt at $650^{\circ}C$ using the electrochemical impedance spectroscopy method. It was found that the corrosion current of these Fe-based alloys decreased with increasing Al or Ti. And Al addition improved the corrosion resistance of this type of specimen and more improvement of corrosion resistance was observed at the specimen added with Al.

• 한국수소및신에너지학회논문집
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• 제19권3호
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• pp.232-238
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• 2008

Research has been proceeded on fuel cell which is fueled by hydrogen. Polymer electrolyte membrane fuel cell (PEMFC) is promising power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, temperature dependent performance. These problems could be solved by experiment which is useful for analysis and optimization of fuel cell performance and heat management. In this paper, when hydrogen flows constantly at the stoichiometry of ${\xi}=1.6$, the performance of the fuel cell stack was increased and the voltage difference between each cells was decreased according to the increase of air stoichiometry by 2.0, 2.5, 3.0. Therefore, the control of air flow rate in the same gas channel is important to get higher performance. Purpose of this research is to expect operation temperature, flow rate, performance and mass transportation through experiment and to help actual manufacture of PEM fuel cell stack.

• 한국자동차공학회논문집
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• 제15권3호
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• pp.124-132
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• 2007

The main objective of this work is to investigate the characteristics of a heat pump system for fuel cell electric vehicle (FCEV). The present heat pump system adopts an electrically driven compressor running with R134a and uses the heat from the fuel cell stack as the heat source for the exterior heat exchanger. The experimental work has been done with various operating conditions such as different compressor speeds, fuel cell stack coolant temperatures and flow rates. The heating capacity was measured to be from 4 to 10 kW at $-20^{\circ}C$ ambient temperature, and the outlet temperature of interior heat exchanger was up to $70^{\circ}C$. After 30 seconds from start-up, the system reached a steady state and the heating capacity of 6.8 kW was acquired, and after 90 seconds, the air outlet temperature of interior heat exchanger became $35^{\circ}C$.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1252-1254
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• 1997

Direct methanol fuel cell based on a proton-exchange membrane electrolyte was investigated. 60% Pt-Ru/C and 60%Pt/C catalysts were employed for methanol oxidation and oxygen reduction, respectively. Morphologies of the catalysts were investigated by x-ray power diffraction, energy dispersive x-ray spectroscopy, and transmission microscopy. Electrochemical characteristics of the catalysts were tested by using cyclic voltametry technique. I-V characteristics of the fuel cell were tested by changing methanol concentration, temperature, and Nafion type as a proton-exchange membrane electrolyte. AC impedance technique was used to investigate the electrochemical performance of the fuel cell. The performance of single cell was enhance with increasing cell temperature. High operation temperature attributed to the combined effects of the reduction of ohmic resistance and polarization. High cell voltage was obtained from the concentration of 205M methanol. With Nafion 112, a current density of $230mA/cm^2$ at 0.55V was obtained from the concentration of 2.5M methanol.

• 한국수소및신에너지학회논문집
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• 제33권5호
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• pp.557-565
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• 2022

The effect of flow configuration in ammonia-fed solid oxide fuel cell are investigated by using a three-dimensional numerical model. Typical flow configurations including co-flow and counter-flow are considered. The ammonia is directly fed into the stack without any external reforming process, resulting in an internal decomposition of NH3 in the anode electrode of the stack. The result showed that temperature profile in the case of counter-flow is more uniform than the co-flow configuration. The counter-flow cell, the temperature is highest at the middle of the channel while in the case of co-flow, the temperature is continuously increased and reached maximum value at the outlet area. This leads to a higher averaged current density in counter-flow compared to that of co-flow, about 5%.

• 대한기계학회논문집B
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• 제41권11호
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• pp.735-742
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• 2017

본 연구에서는 PEM 연료전지 온도 센서의 고장을 감지 및 판별할 수 있는 모델 기반 센서 고장 감지 방법이 적용된다. 연료전지 차량이 작동하는 과정에서 스택 온도는 연료전지의 내구성에 영향을 미친다. 따라서 고장 진단 알고리즘이 고장 신호를 감지하는 것은 중요하다. 센서 고장 감지의 주요 목적은 연료전지 시스템의 안정적인 작동을 보장하여 고온과 저온으로부터 스택을 보호하는 것이다. 상태 공간에 기반한 패러티 방정식이 스택 온도와 냉각수 입구 온도와 같은 센서 고장을 감지하는데 적용되며, 잔차는 정상적인 온도 신호와 비교된다. 그리고 잔차는 현재의 센서 고장을 감지하는 다양한 고장 시나리오에 의해 평가된다. 결론적으로, 본 연구에서 설계된 고장 알고리즘이 고장 신호를 감지할 수 있다.

• 플랜트 저널
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• 제10권3호
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• pp.45-51
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• 2014

본 연구에서는 기존 가정용연료전지에서 활용이 미약한 중저온의 배열을 건물난방부하에 적용할 수 있도록 온도 안정화 장치를 개발하였으며 이 장치가 기존 난방설비와 연계가 가능하도록 제어시스템을 구축하였다. 연료전지 시스템의 정상작동을 위해서는 연료전지로부터 배출되는 온수의 공급온도가 $60^{\circ}C$이어야 하고 다시 연료전지로 회수되는 작동 유체의 환수온도는 항상 $55^{\circ}C$로 유지하여야 한다. 본고에서는 먼저 스택배열 활용을 극대화하기 위해 CFD 분석을 통해 소형열교환기와 기존 난방설비배관과의 최적 연계장치시스템을 구성하였다. 또한 계절별 난방 수온의 불규칙한 온도변화에 대응하기 위해서 연료전지 스택의 열원과 아파트세대 난방용 환수관을 연결한 온도자동조절 밸브를 사용하여 온도안정화 장치를 개발하였다. 소형열교환기와 통합 활용할 수 있도록 설정된 온수의 온도가 편차 ${\pm}0.5^{\circ}C$ 이내에서 유지되도록 하였다. 이 연구결과를 통해 연료전지인 PEMFC의 배열을 건물난방부하에 활용이 추후 가능할 것으로 예상된다.