• Title/Summary/Keyword: Freezing point depression

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The Analysis of Textbook Contents and Science Teachers' Conceptions on Freezing Point Depression Phenomenon (어느점 내림 현상에 대한 교과서 내용 및 중등 과학 교사들의 개념 분석)

  • Ha, Seong-Ja;Kim, Bum-Gi;Paik, Seoung-Hey
    • Journal of The Korean Association For Science Education
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    • v.25 no.2
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    • pp.88-97
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    • 2005
  • The purpose of this study was to investigate explanations of science textbooks and science teachers' conceptions related to freezing point depression phenomenon. Seven kinds of middle school science textbooks and five kinds of high school chemistryII textbooks were analyzed for the purpose. The teachers' conceptions were searched by a questionnaire developed in this study. The subjects were 146 science teachers. The explanation types of science textbooks were divided into two; 'Description of the phenomenon' and 'Vapor pressure lowering'. The explanations in most of middle school science textbooks and high school chemistryII textbooks belong to 'Description of the phenomenon' and there was no explanation of the reason. The graphs related to depression of freezing point were diverse, too. Most of the science teachers also did not have scientific conception. The percentage of the teachers who thought that the cause of freezing point depression was blocking of solute in solution was high. But the teacher could not find meaningful relation the 'Blocking of solute' explanation represented for elevation of boiling point with depression of freezing point. It is insisted that entropy concept is need to explain depression of freezing point phenomenon in this study.

A Thermodynamic Study on Freezing Characteristics of Weathered Tuff Soil- Freezing Point Depression with the Variation of Overburden Pressure - (응회암 풍화토의 동결특성에 관한 열역학적 연구-상재하중과 동결점 저하를 중심으로-)

  • 서상열
    • Journal of the Korean Geotechnical Society
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    • v.15 no.6
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    • pp.297-306
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    • 1999
  • In this research, the frost heave mechanism of the weathered tuff soil sampled from the area tying between Ulanbator and Beijing was studied. The frost heave tests were carried maintaining the constant temperature at both upper$(+5^{\circ}C)\; and\; lower(-5^{\circ}C)$ ends of the sample. Here, main emphasis is given on variation of the freezing point depression with the variation of applied overburden pressure. The expansion of ice lens and migration of the pore water towards freezing front were observed in the test. It was found that with the increase in overburden pressure there is decrease in heave rate and increase in the absolute value of a segregation-freezing temperature. Hence the equation between segregation-freezing temperature and overburden pressure could be suggested. Also the water content of the samples at the frozen side was shown to be higher than those at the unfrozen side. Similarly, the water at warmer part of the frozen tuff was found much higher than that of the cooler part.

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Elementary Pre-service Teachers' Conceptions on 'the Freezing Point Depression' and a Proposal of Explanatory Models ('어는점 내림'에 대한 초등 예비교사들의 인식 조사 및 설명 모형 제안)

  • Kim, Han-Je;Joung, Yong Jae;Jang, Myoung-Duk
    • Journal of Korean Elementary Science Education
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    • v.32 no.2
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    • pp.206-224
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    • 2013
  • The purpose of this study is to investigate the elementary pre-service teachers' conceptions on 'the freezing point depression' focusing on the survey from a National University of Education. Eighteen pre-service teachers who had completed high school Chemistry II coursework were selected to participate in the study. Participants answered a four question survey to measure their scientific knowledge and conceptions of this phenomenon. Each answer was qualitatively analyzed to determine whether they have 'scientific conceptions' or 'quasi-scientific conceptions' or 'misconceptions'. The results from the study are as follows: First, it was showed that none of the eighteen participants had 'scientific conceptions', six had 'quasi-scientific conceptions' and eight had 'misconceptions' about the caused effect when $CaCl_2$ is scattered on the ice. Second, it was found that three participants had 'scientific conceptions', eight had 'quasi-scientific conceptions' and two had 'misconceptions' for the second survey question. Third, ten out of eighteen participants demonstrated 'scientific conceptions' about the phenomenon of salt water freezing. Fourth, only three of eighteen participants illustrated appropriate 'scientific conceptions' for the fourth survey question. Fifth, of all participants, none answered more than three questions correctly, and only three participants answered any combination of two questions correctly. Based on the findings of this study, five explanatory models were developed. And the models were proposed for pre-service teachers to enhance their understanding of the freezing point depression phenomenon.

Physico-Chemical Characteristics of Components and Their Effects on Freezing Point Depression of Garlic Bulbs (마늘의 성분조성(成分組成)과 내한성(耐寒性) 연구(硏究))

  • Park, Moo-Hyun;Kim, Jun-Pyong;Kwon, Dong-Jin
    • Korean Journal of Food Science and Technology
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    • v.20 no.2
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    • pp.205-212
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    • 1988
  • The effect of physicochemical characteristics on the freezing point depression of garlic bulb was studied to examine the reasons of cryoprotectivity in garlic bulb stored at subzero temperature. The composition of fresh garlic was characterized by having high soluble solids($40^{\circ}$ Brix; 90% on dry basis), comparing with $10^{\circ}$ Brix in case of other fruits and vegetables. Soluble solids were composed of 70% sugars, 20% protein, and 10% insoluble solids(including 3% of ash, 3% of crude fiber, and 4% of fat). The main component of sugars in garlic was fructosan with 1-29 degree of polymerization(D.P) and the fructosan of 4-5 D.P was over 50% of total fructosan. Freezing point of garlic bulb, which is a parameter of cryoprotectivity, was depressed as the concentration of soluble solids increased, and as the D.P value decreased in the same concentration of soluble solids.

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FREEZING POINT DEPRESSION OF RAW GOAT'S MILK FROM THE REGION OF GOIÂNIA, BRAZIL

  • de Sousa, J.T.;Dias, M.J.;Tanezini, C.A.;D'Alessandro, W.T.;de Olineira, B.C.;de Melo Rocha, J.;dos Santos Pontes, I.
    • Asian-Australasian Journal of Animal Sciences
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    • v.6 no.4
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    • pp.555-559
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    • 1993
  • Studies at freezing point depression (FPD) for goat milk are described in this paper. The 432 samples of raw goat milk collected in a period of two years and analysed by the use of an electronic cryoscope gave a mean value of FPD: $-0.565{\pm}0.01^{\circ}C$. Statistical significant differences were found between the morning and evening milk. The evening milk showed better quality considering the lactose and others dissolved solutes. Among the Brown, Saanen and Anglo-nubian goats, the greatest increase in FPD, occurred in the Anglo-nubian breed. The statistical analysis revealed a significant breed difference (p<0.05), when climate variation was observed. The superior and inferior values found to the FPD of the caprine milk (-0.545 to $-0.585^{\circ}C$), is important in establishing regional rules, to improve the quality control criteria and legal interpretation of standards found in the pertinent legislation. The results are also important to improve herd management so that one can increase the animal production which will affect the technological composition, and the nutritional characteristics of the resultant products.

Studies on the Low-temperature Storage of Strawberry Pulp and Red Pepper Paste by Cryoprotectants (동결방지제에 의한 딸기펄프와 붉은생고추 페이스트의 저온저장에 관한 연구)

  • Jeong, Jin-Woong;Jo, Jin-Ho;Kwon, Dong-Jin;Kim, Young-Boong
    • Korean Journal of Food Science and Technology
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    • v.22 no.4
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    • pp.434-438
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    • 1990
  • With adding cryoprotectants to red pepper paste and strawberry pulp, the effects of freezing point depression and the energy requirement for storage at $-15^{\circ}C$ were studied. In case of red pepper paste, the freezing point was pressed to $-9.6^{\circ}C$ by adding NaCl(15% w/w) and citric acid after removing stem. And the components of combined cryoprotectants to keep strawberry pulp in the unforzen state at $-15^{\circ}C$ were dextrose(25% w/'w), fructose(17% w/w) sorbitol(8% w/w) and ascorbic acid(0.2%, w/w). Also, when compared with No-treatment, the storage time reduced about 50% and resulted in about $70{\sim}80%$ cut-down in the energy requirement for storage of food products at low-temperature.

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Estimating the freezing and supercooling points of Korean agricultural products from experimental and quality characteristics (국내산 농산물의 과냉각 및 동결점 분석)

  • Park, Jong Woo;Kim, Jinse;Park, Seok Ho;Choi, Dong Soo;Choi, Seung Ryul;Kim, Yong Hoon;Lee, Soo Jang;Park, Chun Wan;Han, Gui Jeung
    • Food Science and Preservation
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    • v.23 no.3
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    • pp.438-444
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    • 2016
  • This study was performed to determine the optimal freezing point for the reliable cold storage of Korean agricultural products, and to provide basic data for determining the storage temperature based on the quality characteristics. Additional supercooling temperature analysis was conducted to explore the possibility of supercooling storage. To determine the effects of quality characteristics on the freezing point, the hardness, acidity, moisture and sugar content were analyzed. The crops were frozen using customized cooling unit and their freezing and supercooling points were determined based on their heat release points. The freezing temperatures of garlic, leek, cucumber, hot pepper, grape, oriental melon, netted melon, peach, cherry tomato, plum, daikon, sweet persimmon, apple, sweet potato, mandarin, pear, and strawberry were -1.6, -0.5, -0.5, -0.7, -1.6, -1.6, -1.3, -0.8, -0.3, -1.1, -0.3, -1.7, -1.5, -1.5, -0.8, -1.5, and -$0.9^{\circ}C$, respectively; otherwise, supercooling points were -7.8, -3.7, -3.3, -4.9, -5.7, -4.6, -2.8, -3.3, -5.9, -4.2, -0.8, -4.7, -3.2, -3.7, -4.7, -4.2, and -$3.4^{\circ}C$, respectively. These results suggest that the ideal freezing temperature of crops could be estimated through freezing point depression because of their sugar content, and this technique should be used to maintain an optimum storage temperature. However, cold storage is complicated and further study is required because of the effects of long-term cold storage on the crops.

Studies on Cold Resistance of Garlic Bulbs at Subzero Temperature (영하온도(零下溫度)에서 마늘의 내한특성(耐寒特性)에 관한 연구(硏究))

  • Park, Moo-Hyun;Kim, Jun-Pyong;Shin, Dong-Bin
    • Korean Journal of Food Science and Technology
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    • v.20 no.2
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    • pp.200-204
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    • 1988
  • Cryoprotectivity of garlic bulb caused by the freezing point depression was studied to establish the possibility of preserving the garlic at subzero temperature. Freezing point of fresh garlic tissue showed almost consistency, ranged from $-4^{\circ}C\;to\;-5^{\circ}C$ regardless of the cultivation area. However, the freezing point was varied with the postharvest treatment and storage conditions, so that freezing point of fresh garlic was $-3.5^{\circ}C$ before predrying, $-4.5^{\circ}C$ after predrying, $-5.5^{\circ}C$ after 5 months of storage and that of dead tissue was $-2.5^{\circ}C$. Freezing lethality of fresh garlic bulb preserved at -4, -6.5 and $-15.5^{\circ}C$ were 0, 10 and 70%, respectively. From these results, it was concluded that critical lethal temperature might be $-5{\sim}-6^{\circ}C$. The respiration rate of garlic bulb decreased with lowering the storage temperature down to $-4^{\circ}C$. $Q_{10}$ value was 2 at the temperature range of $-4{\sim}-5^{\circ}C$, 3 at $5{\sim}15^{\circ}C$ and 1.2 at $15{\sim}37^{\circ}C$. In conclusion, optimal temperature for garlic storage was $-4^{\circ}C$ when considering the cryoprotectivity of garlic bulb at subzero temperature.

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Measurement and Verification of Unfrozen Water Retention Curve of Frozen Sandy Soil Based on Pore Water Salinity (간극수 염분농도에 따른 동결 사질토의 부동수분곡선 산정 및 검증 연구)

  • Kim, Hee-Won;Go, Gyu-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.39 no.11
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    • pp.53-62
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    • 2023
  • The characteristics of unfrozen water content in frozen soils significantly impact the thermal, hydraulic, and mechanical behavior of the ground. A thorough analysis of the unfrozen water content characteristics of the target subsoil material is crucial for evaluating the stability of frozen ground. This study conducted indoor experiments to measure the freezing point and unfrozen water content of sandy soil while considering pore water salinity. Utilizing the experimental data, we introduced a novel empirical model to conveniently estimate the unfrozen water retention curve. Furthermore, the validity of the unfrozen water retention curve was assessed by comparing the experimental data with the results of a simulation model that utilized the proposed empirical model as input data.

Freezing Preservation of Liquid Egg by Freezing Point Depression (빙점강하에 의한 액란의 냉동저장에 관한 연구)

  • Lee, Young-Chun;Lee, Kyung-Hae
    • Korean Journal of Food Science and Technology
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    • v.20 no.4
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    • pp.594-599
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    • 1988
  • Methods by which liquid egg could be stored in liquid state at frozen storage temperature$(-15^{\circ}C)$ with selected cryoprotectants and enzyme treatment were investiated, and quality changes in samples during storage were examined. The concentration of cryoprotectants (45% fructose and 55% glucose) to be added to egg yolk and whole egg to store them at $-15^{\circ}C$ in unfrozen state were 45.2% and 70.3%, respectively. Changes in consistency, precipitation of protein and microstructure of egg samples during storage indicated that adding cryoprotectants to liquid egg could effectively inhibit development of gelation during storage at $-15^{\circ}C$. Treating liquid egg with 0.15% papain could inhibit gelation during storage to some extent.

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