• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.2
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• pp.173-180
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• 2005

Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the mechanical and durability test such as compressive/tensile/flexural strength test, chloride ion diffusion, chemical attack and repeated freezing and thawing, carbonation test. In the mechanical tests, 10~15% for binder is optimum substitute rate. And, in the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient was more reduced. In the chemical attack test, by the filler effect of fine powder such metakaolin and silica-fume, the resistance is more excellent than normal concrete. In the other durability test, the concrete using metakaolin also compared with those of silica-fume substitute concrete. Through these tests, we recognized that metakaolin can be used as a substitute for silica-fume.

• Journal of the Korean GEO-environmental Society
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• v.17 no.12
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• pp.35-43
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• 2016

With the development of construction technology, constructions of dam and levee (dike) as well as the environmental problems are becoming issues. Recently, many countries have tried to develop and used CSG (Cemented Sand and Gravel), which needs fewer requirements than others in aggregates, constructability and ground condition during the dam construction. Mixing up with small amount of cement, CSG is able to increase the strength and proceed accelerated construction without artificial gradation adjustment of riverbed aggregate and crushed rock on construction site. Thus, CSG can minimize environmental damage resulted from quarries mining and reduce cost of construction. Unlike heat of hydration condition that regular concrete usually met, CSG exposes to repeated dry-wet and freezing and thawing environment. Thus, consider the importance of structure of dam or levee, intensive study on the durability of CSG is needed. In this study, freezing and thawing experiment was carried out to evaluate the durability of CSG. In results, the durability factor of CSG is 30~40 or >40 when the amount of cement is $0.4{\sim}0.6kN/m^3$ or $0.8{\sim}1.0kN/m^3$, respectively. The unconfined compressive strength is reduced to 30~50% or 40~70% when the amount of cement is $0.4{\sim}0.6kN/m^3$ or $0.8{\sim}1.0kN/m^3$, respectively. Taken together, the strength and durability of CSG is reliable when the amount of cement is over $0.8kN/m^3$.

• Journal of the Korean Geosynthetics Society
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• v.11 no.3
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• pp.27-35
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• 2012

In this paper, the frost heaving and thawing characteristics of flexible pavement structure were evaluated in the large scale freezer which have a specification of temperature range $-20^{\circ}C{\sim}10^{\circ}C$ and $3.2m(L){\times}3.2m(B){\times}2.4m(H)$ in size. The insulated steel box with the size of $0.9m(L){\times}0.9m(B){\times}0.9m(H)$ was used to simulate actual pavement road structure. The variation of temperature, frost heave amount and frost heave pressure were measured through the instrument of TDS-602 data logger. LFWD (light falling weight deflectometer) was used to determine the change of deflection due to the frost heaving and thawing. Furthermore, the influence of aggregate layer to the freezing of the subgrade soil was studied to verify the function and effectiveness of the anti-freezing layer.

• Journal of the Korean GEO-environmental Society
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• v.18 no.12
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• pp.5-11
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• 2017

The 19 mm-sized aggregate was produced by melting vinyl waste (waste polyethylene film) generated from vinyl greenhouses in rural areas. It was mixed with As'cone at various weight ratios, and then insulation effect test, tension test after repeated freezing and thawing, ice pull-out strength test and field density test were conducted for the mixtures. These results demonstrated that as the mixing ratio of polyethylene aggregate increased, the insulation effect increased, due to the many pore spaces that existed in the polyethylene aggregate. After repeatedly freezing and thawing As'cone, the tensile strength significantly increased at 2.5% of the polyethylene aggregate content rather than 0% of polyethylene aggregate content but it also slightly decreased at 5% and 10% of polyethylene aggregate content in comparison to 2.5% of its polyethylene aggregate content. As'cone added with polyethylene aggregate by 2.5% resulted in lower ice pull-out strength than that of normal As'cone. As a result of the porosity test for the samples taken at the site, porosity of the As'cone, which added polyethylene aggregate, was smaller than that of the general As'cone.

• Advances in concrete construction
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• v.11 no.4
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• pp.307-314
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• 2021

Activated hwangtoh (ACT) is a natural resource abundant in South Korea, approximately 15.0% of soil. It is an efficient mineral admixture that has activated pozzolanic properties through high-temperature heating and rapid cooling. The purpose of this study is to improve a curb mixture that can reduce NOx outside and investigate durability performance. To this end, mortar curb specimens were manufactured by replacing OPC with ACT. The ACT substitution ratios of 0.0, 10.0, and 25.0% were considered, and mechanical and durability tests on the curb specimens were conducted at 28 and 91 days of age. Steam curing was carried out for three days for the production of curbs, which was very effective to strength development at early ages. The reduction in strength at early ages could be compensated through this process, and no significant performance degradation was evaluated in the tests on chloride attack, carbonation, and freezing and thawing. The mortar curb with an ACT of 10.0~25.0% replacement ratio exhibited clear NOx reduction through photocatalytic (TiO2) treatment. This is due to the increase in physical absorption through surface absorption and the photocatalyst-containing TiO2 coating. In this study, the reasonable range of the ACT replacement ratio for NOx reduction was quantitatively evaluated through a comprehensive analysis of each test.

• Computers and Concrete
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• v.3 no.2_3
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• pp.163-175
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• 2006

This research was conducted to determine effect of pumice aggregate ratio, cement dosage and slumps on freeze-thaw resistance, density, water absorption and elasticity of concrete. In the first batch, $300kg/m^3$ cement dosage were kept constant and pumice ratios were changed as 25%, 50%, 75% and 100% of replacement for normal aggregate by volume for $3{\pm}1cm$, $5{\pm}1cm$ and $7{\pm}1cm$ slumps. Other batches were prepared with $200kg/m^3$, $250kg/m^3$, $350kg/m^3$, $400kg/m^3$ and $500kg/m^3$ cement dosages and 25% pumice aggregate +75% normal aggregate at a constant slump. Test results showed that when pumice-aggregate ratio decreased the density and freeze-thaw resistance of concretes increased. With increasing of cement dosage in the mixtures, density of the concretes increased, however, freeze-thaw resistance of concretes decreased. Water absorption of the concrete decreased with increasing cement dosage but increased with the pumice ratio. Water absorption of the concrete also decreased after freeze-thaw cycles. Freeze-thaw resistance of concretes was decreased with increasing the slumps.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.577-580
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• 2006

This paper presents the experimental results of frost durability characteristics including freezing-thawing and de-icing salt scaling of the concrete used for gutter of the road. Mixtures were proportioned with the three level of water-binder ratio (W/B), 0.58, 0.53, and 0.48, and two binder compositions corresponding to Type I cement without any supplementary cementitious materials (OPC) and Type I cement with 30% blast-furnace slag replacement (Slag30). Also, two different solutions of calcium chloride and water that contains 0 and 8g of anhydrous calcium chloride in each 100 mL of solution, respectively, were used to evaluate their effect on the frost durability resistance. Test results showed that the Slag30 mixture exhibited higher durability factor and lower mass loss values than those made with OPC. Among the mixture tested in this work, the mixtures (OPC and Slag30) made with a relatively higher W/B of 0.58 exhibited large amount of the de-icing salt scaling regardless of calcium chloride concentration. Finally, the use of slag can be used effectively in terms of economy and frost durability of the concrete designated for gutter.

• Clinical and Experimental Reproductive Medicine
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• v.28 no.2
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• pp.121-129
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• 2001

Objective: The aim of this study is to compare the efficiency of a method for the cryopreservation of mouse blastocyst.. Methods: Mouse embryos were obtained at 2-cell stage and cultured to blastocyst stage in T6 medium supplemented with 10% fetal bovine serum. Morphologically normal blastocysts were collected and randomly divided to one control and four experimental groups. In control group, blastocysts were cultured in vitro continuously for additional two days. In group 2, blastocysts were exposed to vitrification solution (ethylene glycol) only without cryopreservation (exposure only group). In group 3, 4 and 5, blastocysts were cryopreserved by slow-freezing procedure with glycerol (slow-fteezing group) or by vitrification procedure using EM grids (EM grids group) and cryoloop (cryoloop group), respectively. Frozen blastocysts were thawed and cultured for additional two days. Twenty four hours after thawing, some blastocysts were fixed and stained with Hoechst 33342 (bisbenzimide) and the number of nuclei in each blastocysts were counted to confirm the survival of bias to cysts in experimental groups. Results: Survival rate and hatching rate of the blastocysts in slow-freezing group (24 h: 72.4% and 66.0%, 48 h: 63.2% and 64.6%) and EM grids group (24 h: survival rate 77.3%, 48 h: 70.1% and 71.4%) were significantly lower ($X^2$-test p<0.05) than those of control group (24 h: 93.4% and 86.0%, 48 h: 88.5% and 90.7%). In contrast, the survival rate and hatching rate of the blastocysts in cryoloop group (24 h: 84.1% and 84.1%,48 h 79.3% and 87.7%) is well compared with those in the control group. The mean (${\pm}SD$) cell number of blastocyst in the exposure only ($89.2{\pm}11.5$), EM grids ($85.0{\pm}10.3$) and cryoloop ($89.0{\pm}11.0$) groups, except slow-freezing group ($79.0{\pm}10.0$), were not significantly different from that of control group ($93.1{\pm}13.9$) 24 h after thawing (Student's t-test). Conclusion: This study demonstrates that higher survival rate of vitrified-thawed mouse blastocyst can be obtained using cryoloop as the embryo container at freezing rather than slow-freezing or vitrification using EM grids. The results of this study suggest that vitrification using cryoloop (with ethylene glycol) may be a preferable procedure for mouse blastocyst cryopreservation and could be applied to the human blastocyst cryopreservation.

• International Journal of Highway Engineering
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• v.19 no.2
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• pp.7-15
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• 2017

PURPOSES : Infiltration of moisture, polluted material, and deicer into concrete, accompanied by freeze and thaw can cause significant deterioration of concrete pavement. In order to protect concrete from deterioration, it is necessary to prevent the infiltration of these concrete external materials. The moisture-repellent agent, which is a surface treatment and maintenance material added to concrete structures to render them water resistant, has advantages such as prevention of water infiltration and security against air permeation. Nano-coat, which is referred to as silicon hydride, is typically used as a moisture-repellent agent. Therefore, in this study, an attempt is made to use penetration-type Nano-coat as an alternative in order to evaluate its applicability through environmental resistance tests. METHODS : This study aimed to evaluate the applicability of penetration-type Nano-coat, which can provide water repellency to concrete, in concrete pavements, through various environmental resistance tests such as freezing and thawing resistance, chloride ion penetration resistance, and surface scaling resistance tests. The applicability of penetration-type Nano-coat was demonstrated based on the specification of KS F 2711, KS F 2456, and ASTM C 672. RESULTS :In the case of penetration-type Nano-coat applied on sound concrete, an increase in concrete durability was demonstrated by the negligible chloride ion penetrability and the absence of scaling, as revealed by visual observation of the surface, after 50 cycles of scaling resistance test. In addition, test result of the application of penetration-type Nano-coat on deteriorated concrete established that concrete surface pretreated by grinding provided improved durability than non-treated concrete. CONCLUSIONS :This study indicates that penetration-type Nano-coat is applicable as an effective alternative, to increase the durability of concrete structures. In addition, it was known that pretreatment of deteriorated concrete surface, such as grinding, is required to improve the long-term performance of concrete pavement.

• International Journal of Highway Engineering
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• v.18 no.6
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• pp.123-130
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• 2016

OBJECTIVES : The objective of this research is to determine the moisture resistance of the freeze-thaw process occurring in low-noise porous pavement using either hydrated-lime or anti-freezing agent. Various additives were applied to low-noise porous asphalt, which is actively paved in South Korea, to overcome its disadvantages. Moreover, the optimum contents of hydrated-lime and anti-freezing agent and behavior properties of low-noise porous asphalt layer are determined using dynamic moduli via the freeze-thaw test. METHODS : The low-noise porous asphalt mixtures were made using gyratory compacters to investigate its properties with either hydrated-lime or anti-freezing agent. To determine the dynamic moduli of each mixture, impact resonance test was conducted. The applied standard for the freeze-thaw test of asphalt mixture is ASTM D 6857. The freeze-thaw and impact resonance tests were performed twice at each stage. The behavior properties were defined using finite element method, which was performed using the dynamic modulus data obtained from the freeze-thaw test and resonance frequencies obtained from non-destructive impact test. RESULTS : The results show that the coherence and strength of the low-noise porous asphalt mixture decreased continuously with the increase in the temperature of the mixture. The dynamic modulus of the normal low-noise porous asphalt mixture dramatically decreased after one cycle of freezing and thawing stages, which is more than that of other mixtures containing additives. The damage rate was higher when the freeze-thaw test was repeated. CONCLUSIONS : From the root mean squared error (RMSE) and mean percentage error (MPE) analyses, the addition rates of 1.5% hydrated-lime and 0.5% anti-freezing agent resulted in the strongest mixture having the highest moisture resistance compared to other specimens with each additive in 1 cycle freeze-thaw test. Moreover, the freeze-thaw resistance significantly improved when a hydrated-lime content of 0.5% was applied for the two cycles of the freeze-thaw test. Hence, the optimum contents of both hydrated-lime and anti-freezing agent are 0.5%.