• Title/Summary/Keyword: Free-formed

Search Result 941, Processing Time 0.03 seconds

EVALUATION OF HYDROGEN INDUCED DISBONDING FOR CR-MO-V STEEL/AUSTENITIC STAINLESS OVERLAY

  • Kim, Byung-Hoon;Kim, Dong-Jin;Kim, Jeong-Tae
    • Proceedings of the KWS Conference
    • /
    • 2002.10a
    • /
    • pp.211-216
    • /
    • 2002
  • To investigate transition region in welded overlay relating to disbonding crack, the effect of vanadium addition on disbonding of Cr-Mo steels overlay welded with austenitic stainless steel was studied. V modified Cr-Mo steels have a higher resistance to disbonding than V free Cr-Mo steel. One reason is due to the fact that fine vanadium carbide precipated in base metal traps hydrogen and thus decreases the susceptibility to the disbonding. The second is related to the higher stability of the vanadium and stable carbides formed during PWHT, in which the carbon diffusion to the interface is lower than for V free Cr-Mo steel. Decreasing the carbon content at the interface of the weld overlay shows good resistance to the disbonding. Hence, it is important to control the carbon content at the interface of the weld overlay.

  • PDF

Blob and Wave Formation at the Free Edge of an Initially Stationary fluid Sheet (액체 필름 끝단에서의 유동특성에 관한 수치연구)

  • Song Museok;Ahn Jail
    • Proceedings of the KSME Conference
    • /
    • 2002.08a
    • /
    • pp.307-310
    • /
    • 2002
  • A two-dimensional numerical method for inviscid two-fluid flows with evolution of density interface is developed, and an initially stationary two-dimensional fluid sheet surrounded by another fluid is studied. The Interface between two fluids is modeled as a vertex sheet, and the flow field u÷th the evolution of interface is solved by using vortex-in-cell/front-tracking method. The edge of the sheet Is pulled back into the sheet due to surface tension and a blob is formed at the edge. This blob and fluid sheet are connected by a thin neck. In the inviscid limit, such process of the blob and neck formation is examined in detail and their kinematic characteristics are summarized with dimensionless parameters. The edge recedes at $V=1.06({\sigma}/{\rho}h)^{0.5}$ and the capillary wave Propagating into the fluid sheet must be considered for bettor understanding of the edge receding.

  • PDF

Visualization of Interacting Parallel Supersonic Free Jets using NO-LIF

  • Niimi Tomohide;Ishida Toshihiko
    • 한국가시화정보학회:학술대회논문집
    • /
    • 2001.12a
    • /
    • pp.36-43
    • /
    • 2001
  • The flow field structures of two interacting parallel supersonic free jets are studied by flow visualization using planar laser-induced fluorescence of NO seeded in nitrogen gas. The experiments are carried out for several distances between two orifice centers and for various ratios of the pressure in the reservoir to that in the expansion chamber. The flow fields are visualized mainly on the plane including two jet centerlines and its characteristic shock system, especially a cell structure formed secondly by interaction of two jets, are analyzed. The positions of the normal shock depending on the pressure ratios are also compared.

  • PDF

Doping-free Transparent Conducting Schottky Type Heterojunction Solar Cells

  • Kim, Joon-Dong
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.209-209
    • /
    • 2012
  • High-efficient transparent conductive oxide (TCO) film-embedding Si heterojunction solar cells were fabricated. An additional doping was not applied for heterojunction solar cells due to the spontaneous junction formation between TCO films and an n-type Si substrate. Three different TCO coatings were formed by sputtering method for an Al-doped ZnO (AZO) film, an indium-tin-oxide (ITO) film and double stacks of ITO/AZO films. An improved crystalline ITO film was grown on an AZO template upon hetero-epitaxial growth. This double TCO films-embedding Si heterojunction solar cell provided significantly enhanced efficiency of 9.23% as compared to the single TCO/Si devices. The effective arrangement of TCO films (ITO/AZO) provides benefits of a lower front contact resistance and a smaller band offset to Si leading enhanced photovoltaic performances. This demonstrates a potential scheme of the effective TCO film-embedding heterojunction Si solar cells.

  • PDF

Characteristics of VOCs Oxidation using Copper Phthalocyanine Catalysts (구리 프탈로시아닌 촉매의 VOCs 산화 특성)

  • 서성규;윤형선
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.20 no.4
    • /
    • pp.515-521
    • /
    • 2004
  • The catalytic oxidation of volatile organic compounds (methanol. acetaldehyde) has been characterized using the copper phthalocyanine catalyst in a fixed bed flow reactor under atmospheric pressure. The catalytic activity for pretreatment conditions was examined by this reaction system. The catalytic activity was ordered as follows: metal free-PC<Cu ($\alpha$)-PC<Cu ($\beta$)-PC The formaldehyde, carbon monoxide as a partial oxidation product of methanol and acetaldehyde over Cu ($\alpha$)-PC catalyst were detected and the conversions of methanol and acetaldehyde were accomplished above 95% over Cu ($\alpha$) -PC, Cu ($\beta$) - PC catalyst at 35$0^{\circ}C$. The pretreated metal free -PC, Cu($\alpha$)-PC, Cu($\beta$)-PC catalysts have been characterised by TGA, EA and XRD analysis. The catalytic activity pretreated with air and $CH_3$OH mixture (P-4) or air only (P-5) was very excellent. XRD and EA results showed that Cu($\alpha$)-PC, Cu($\beta$)-PC were destroyed an(1 new metal oxide such as CuO were formed.

Formation of Reactive Oxygen Species and Cr(V) Entities in Chromium(VI) Exposed A549 Cells (크롬 6가 투여 후 A549 세포에서의 Reactive Oxygen Species와 크롬 5가의 발생)

  • 박형숙
    • Environmental Analysis Health and Toxicology
    • /
    • v.11 no.1_2
    • /
    • pp.49-57
    • /
    • 1996
  • The production of reactive oxygen species on addition of hexavalent chromium (potassium dichromate, $K_2Cr_2O_7$ ) to lung cells in culture was studied using flow cytometer analysis. A Coulter Epics Profile flow cytometer was used to detect the formation of reactive oxygen species after $K_2Cr_2O_7$ was added to A549 cells grown to confluence. The cells were loaded with the dye, 2',7'-dichlorofluorescein diacetate, after which cellular esterases removed the acetate groups and the dye was trapped intracellularly. Reactive oxygen species oxidized the dye, with resultant fluorescence. Increased doses of Cr(VI) caused increasing fluorescence (10-fold higher than background at 200 gM). Addition of Cr(III) compounds, as the picolinate or chloride, caused no increased fluorescence. Electron paramagnetic resonance (EPR) spectroscopic studies indicated that three (as yet unidentified) spectral "signals" of the free radical type were formed on addition of 20, 50, 100 and 200 gM Cr(VI) to the A549 cells in suspension. Two other EPR 'signals" with the characteristics of Cr(V) entities were seen at field values lower than the standard free radical value. radical value.

  • PDF

The triple layer anode for flexible top emission organic lightemitting devices

  • Chung, Sung-Mook;Hwang, Chi-Sun;Lee, Jeong-Ik;KoPark, Sang-Hee;Yang, Yong-Suk;Do, Lee-Mi;Chu, Hye-Yong
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2007.08a
    • /
    • pp.698-701
    • /
    • 2007
  • A top emission organic light emitting diode comprising of a triple anode on polycarbonate $film/TNATA/NPB/Alq_3:C545T/cathodes$ has been fabricated. The triple layer structure of Cr/Al/Cr allowed for fabrication of a crack-free anode and provided better higher work function than ITO anode.The anode showed compatibility with flexible plastic substrate and no crack was formed during bending test while ITO anode showed crack.

  • PDF

Evaluation of Nonchromated Thin Organic Coatings for Corrosion Inhibition of Electrogalvanized Steel

  • Park, Jong Myung;Kim, Kyoo Young
    • Corrosion Science and Technology
    • /
    • v.6 no.2
    • /
    • pp.68-73
    • /
    • 2007
  • The toxicity of chromium that is used to impart corrosion resistance to galvanized steel created environmental and health-related concerns and generated a great deal of interest in developing chrome-free treatment coatings. In the present work, organic-inorganic composite coatings were used to coat electrogalvanized steel (EG) sheets for corrosion protection without degrading its weldability property. The new coatings composed of specially modified polyurethane dispersion hybridized with silicate and unique inorganic-organic inhibitors were developed during this work. It was found that about $1{\mu}m$ thickness of coating layer is secure enough in corrosion resistance of flat and formed part even after alkaline degreasing. Overall chemical resistances including fingerprint resistance and paint adhesion property were satisfied with the test specification of Sony technical standard of SS-00260-2002. Therefore, it is concluded that the newly developed chrome-free product can replace the conventional chromated product.

Preparation of Crack-free YBCO Films by EPD on Silver

  • Soh, Dea-wha;Li, Young-mae;Korobova N.;Park, Sung-Jai
    • Journal of information and communication convergence engineering
    • /
    • v.1 no.1
    • /
    • pp.27-30
    • /
    • 2003
  • Electrophoretic deposition (EPD) of alcohol YBCO suspensions on the Ag wire electrode is studied. Poly(ethylene glycol) was coordinated to a structure formed by the EPD process with YBCO particles. The suspension is characterized in terms of zeta potential and conductivity. The d.c electric fields of 200-300 V/cm are applied for 1-10 min. The optimal condition for the EPD allows modifying the properties and microstructure of the deposited films. Superconducting coatings with nanometer-sized pores and a preferred orientation along the c-axis were prepared from the result with chemically modified precursor solution. In contrast, YBCO coatings of submicrometer-sized pores and randomly orientated grains were prepared from the solution without PEG.

A Study on The Electrochemical Behavior of CF/Al Composite in Aqueous Solutions (수용액 중 탄소섬유/알루미늄 복합재의 전기화학적 거동에 관한 연구)

  • Nam, Yun-Gyeong;Mun, Seong-Mo;Jeong, Yong-Su;Sin, Seung-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2011.05a
    • /
    • pp.158-159
    • /
    • 2011
  • In this work, The electrochemical behavior of CF/Al composite was investigated at constant current densities in aqueous solutions. The surface and cross section of PEO-treated CF/Al were observed using SEM, EDS and OM. The CF/Al composite contains carbon fibers of about 40 Vol.% with 5~7 um diameter and 100~150 um length. The carbon fibers appeared to b removed by anodic oxidation in sulfuric acid solution, leaving a carbon-fiber free zone in the surface region. Anodic oxide films were formed in the carbon-free region by plasma electrolytic oxidation(PEO) method in alkaline solutions.

  • PDF