• Title/Summary/Keyword: Free Water

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Biological Monitoring of Human Exposure to Volatile Halogenated Hydrocarbons Using Urinalysis with Capillary GC-ECD

  • Jung, Won-Tae;Sohn, Dong-Hun
    • Archives of Pharmacal Research
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    • v.15 no.2
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    • pp.109-114
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    • 1992
  • For the risk assessment of human exposure to volatile halogenated hydrocarbons, a dynamic purge trap/on-column cryofocusing method using capillary gas chromatograph-$^{63}Ni$ electron capture detector and thermal desorption unit was applied to analyze the free forms, metabolites of 1, 1, 2-trichloroethylene and 1, 1, 2, 2-tetrachloroethylene. The urine sample was diluted with distilled water, hydrolyzed and sealed. Then the inert gas was infused to purge out free 1, 1, 2-trichloroethylene, free 1, 1, 2, 2-tetrachloroethylene and urichloroethanol. These compounds were trapped to $Tenax^R$ / GC-gas trap device throughout clean up tube. Being undertectable to gas chromatograph directly, trichloroacetic acid was methyl esterificated and trapped in the manner above mentioned. The optimal incubation time to get best recovery of methyl ester was 4 hours at $60^circ$C. The concentrations of free volatile halogenated hydrocarbons and their metabolites in urine were obtained of free volatile halogenated hydrocarbons and their metabolites in urine were obtained from 5 healthy volunteers. This analytical method is expected to make the biological monitoring more precise and convenient.

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Flow Characteristics around a Circular Cylinder according as the Depth from Free Surface (자유수면에 접한 원형실린더 주위의 유동계측)

  • Shon, Chang-Bae;Gim, Ok-Sok;Oh, Woo-Jun;Lee, Chang-Woo;Lee, Gyoung-Woo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2010.04a
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    • pp.389-391
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    • 2010
  • The Free surface influenced the wake behind a circular cylinder and its effects were investigated experimentally in a circulating water channe with the variation of water depth Instantaneous velocity fields were measured in this paper. the measured results has been compared with each other to investigate the flow characteristics of the circular cylinder's 2-dimensional section at $Re=1.0\times10^3$ using 2-frame grey level cross correlation PIV method. The flow around the circular cylinder with free surface affected the wake structure. especially, in case of d=1.0D, the boundary layer was measured in the whole area. The separation point and boundary layer of the circular cylinder could be controlled by the water depth.

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Risk free zone study for cylindrical objects dropped into the water

  • Xiang, Gong;Birk, Lothar;Li, Linxiong;Yu, Xiaochuan;Luo, Yong
    • Ocean Systems Engineering
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    • v.6 no.4
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    • pp.377-400
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    • 2016
  • Dropped objects are among the top ten causes of fatalities and serious injuries in the oil and gas industry (DORIS, 2016). Objects may accidentally fall down from platforms or vessels during lifting or any other offshore operation. Proper planning of lifting operations requires the knowledge of the risk-free zone on the sea bed to protect underwater structures and equipment. To this end a three-dimensional (3D) theory of dynamic motion of dropped cylindrical object is expanded to also consider ocean currents. The expanded theory is integrated into the authors' Dropped Objects Simulator (DROBS). DROBS is utilized to simulate the trajectories of dropped cylinders falling through uniform currents originating from different directions (incoming angle at $0^{\circ}$, $90^{\circ}$, $180^{\circ}$, and $270^{\circ}$). It is found that trajectories and landing points of dropped cylinders are greatly influenced by the direction of current. The initial conditions after the cylinders have fallen into the water are treated as random variables. It is assumed that the corresponding parameters orientation angle, translational velocity, and rotational velocity follow normal distributions. The paper presents results of DROBS simulations for the case of a dropped cylinder with initial drop angle at $60^{\circ}$ through air-water columns without current. Then the Monte Carlo simulations are used for predicting the landing point distributions of dropped cylinders with varying drop angles under current. The resulting landing point distribution plots may be used to identify risk free zones for offshore lifting operations.

Effects of Environmental Factors on Growth and Nitrogen Fixation Activity of Kummerowia striata (매듭풀의 생육과 질소고정 활성에 미치는 환경요인의 영향)

  • Song, Seung-Dal;Jung-Sook Park;In-Sook Kim
    • The Korean Journal of Ecology
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    • v.18 no.1
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    • pp.43-54
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    • 1995
  • Effects of environmental factors of N, P, pH, moisture, temperature and oxygen on growth and nitrogen fixation activity of kummerowia striate (Thunb.) Schindler seedling, bearing symbiotic root nodules, were quantitatively analyzed during the growing period. The specific nitrogenase activity (ARA) of nodules showed the maximum value of 187 μmol C₂H₄g fr wt-1 h-1 6 weeks after seeds were germinated. The total nitrogenase activities per plant attained as 1.56, 0.85, 0.09 and 4.0, 1.11, 0.04 μmol C₂H₄hr-1, respectively for the treatments of 1, 3 and 5 mM NO₃ ̄and NH₄+ on the 60th day. While the plant grown in N-free media for 20 days after treatments of 5 mM NH₄+for 40 days resulted in 30 mg fr wt of nodule formation and exhibited the relative activities of 152% and 162% for total and specific ARA in comparison with those of control plant grown with N-free for 60 days. Total biomass and ARA was by 70% and 86% lower in N and P deficiency, respectively. The N and P deficient plot showed 70% and 86% decreases of total biomass and ARA in comparison with those of control. The plant grown with N-free for 20 days after pretreatment with N and P free media for 40 days showed the relative values of 77%, 118% and 150%, respectively for nodule biomass, total and specific ARA in comparison with those of control. The treatment with acid or alkali gradients resulted in significant decreases of nodule biomass and ARA. The optimum temperature and pO₂for ARA were 30°C and 40 kPa, respectively. Two peaks of diurnal variation appeared at 11:00 and 23:00 o'clocks by the continuous light condition. The plants with water stress by temporary wilting point rsulted in 95~97% inhibition for nodule respiration, transpiration and specific ARA. Transpiration and ARA ware recovered to 88% and 38% of those of water unstressed plants, respectively, 6 hours after the plants were rewatered from water stressed condition.

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Extraction Characteristics and Antioxidative Activity of Lycium chinense Extracts (구기자 추출물의 추출특성 및 항산화 효과)

  • Kim Hyun-Ku;Na Gyung-Min;Ye Su-Hyang;Han Ho-Suk
    • Food Science and Preservation
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    • v.11 no.3
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    • pp.352-357
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    • 2004
  • The present study was conducted to investigate extraction characteristics and antioxidative activity of Lycium chinense extracts. Lycium chinense were extracted by reflux extraction(RE) under different extraction conditions including solvent. The solid yield, turbidity, color value, titratable acidity, free sugar contents, electron donating ability(EDA) and superoxide dismutase(SOD)-like ability of Lycium chinense extracts were determined. The highest solid yield value were obtained with water of 10 fold. No significant difference in turbidity and color value were found among the extracts prepared with various extraction solvents, 75$\%$ ethanol, 50$\%$ ethanol and water. The highest titratable acidity were obtained with water of Lycium chinense. The free sugar contents of Lycium chinense extracted with water showed the highest value. Lycium chinense extracts with water included higher contents of free sugar compared with those of the other solvent extracts, 50$\%$ ethanol and 75$\%$ ethanol extracts. The total polyphenol compounds content of Lycium chinense extracted with 50% ethanol showed the highest value. Lycium chinense extracts with 50$\%$ ethanol included higher contents of total polyphenol compound compared with those of the other solvent extracts, water and 75$\%$ ethanol extracts.

The Anomalies of Supercooled Water

  • Yoon, Byoung-Jip;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.2
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    • pp.82-86
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    • 1984
  • The anomalous behaviors of supercooled water are explained by using a two-solid-like structure model in which an equilibrium is assumed between open structures and closed structures. Besides these structures, small fraction of monomer exists in liquid water. The anomalies of liquid water are classified into two groups: structural and energetic. The structural anomalies appear in enlarged fashions in a supercooled state where the free volume is small.

Effect of Interillage and Muddying by Free-Ranging Ducks on pH and Dissolved Oxygen of Stagnant Water, and Soil Physicochemical Properties in Paddy field Soil (논 방사오리에 의한 중경탁수가 관개수의 pH, 용존산소농도 및 토양 이화학적 성질에 미치는 영향)

  • 고병대
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.3
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    • pp.262-266
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    • 2003
  • The present study was carried out to investigate the relationships among intertillage and muddying by free-ranging ducks (Chinese native ducks) and pH, dissolved oxygen of irrigation water, and physicochemical properties of soil. Two paddy fields comprised of the muddying (muddy water without physical stimulation to a rice plant by the ducks) and the control plots (no ducks) were used for this study. As a muddying plot, 50 hills were randomly selected and each hill was fenced with a wire net in order to prevent from stimulating physically by the ducks. The variation in irrigation pH was smaller in the muddying plot than the control plot, and the pH was around 7.4. Dissolved oxygen was significantly higher (P<0.01) in the muddying plot than the control plot during the first half period after the ducks were introduced. Then it decreased rapidly as the rice plants grew in all plots. The contents of the suspended soil and turbidity in irrigation water were not changed over the free-ranging period, but $\textrm{NH}_3\textrm{-N}$ and $\textrm{P}_2\textrm{O}_5$ were decreased by intertillage and muddying by the ducks. There were no differences in both the soil physics and chemistry between the muddying plot and the control plot during and after finishing of the free-ranging period. These results indicate that intertillage and muddying by the ducks resulted in a small variation in stagnant water pH, and reduced the dissolved oxygen and $\textrm{P}_2\textrm{O}_5$, although the physiochemical properties of soil were not changed.

Oblique water entry of a three dimensional body

  • Scolan, Yves-Marie
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.6 no.4
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    • pp.1197-1208
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    • 2014
  • The problem of the oblique water entry of a three dimensional body is considered. Wagner theory is the theoretical framework. Applications are discussed for an elliptic paraboloid entering an initially flat free surface. A dedicated experimental campaign yields a data base for comparisons. In the present analysis, pressure, force and dynamics of the wetted surface expansion are assessed.