• Title/Summary/Keyword: Free Chlorine

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수소 중성입자빔을 이용한 실리콘 에칭

  • Kim, Dae-Cheol;Hong, Seung-Pyo;Kim, Jong-Sik;Park, Jong-Bae;O, Gyeong-Suk;Kim, Yeong-U;Yun, Jeong-Sik;Lee, Bong-Ju;Yu, Seok-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.278-278
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    • 2011
  • 수소 중성입자빔을 이용한 silicon etching은 기존의 silicon etching 공정 가스(Fluorine이나 Chlorine 계열의 가스) 사용 시 배출되는 유해 가스로 인한 지구 온난화 방지 및 폐기물 처리에 추가적인 비용이 발생하지 않는 친환경 etching 공정이다. 본 연구에 사용된 수소 중성입자빔을 발생시키기 위한 플라즈마 소스는 낮은 압력에서 높은 플라즈마 밀도를 발생시킬 수 있는 ECR 플라즈마 소스를 사용하였으며 중성입자빔의 에너지를 조절할 수 있는 중성화판과 플라즈마로부터의 전하손상을 방지할 수 있어 charge free 공정을 가능하게 하는 Limiter로 구성되어 있다. 본 연구에서는 플라즈마 밀도, 공정 압력 그리고, 중성입자빔의 에너지를 조절하여 수소 중성입자빔을 이용한 poly-crystal silicon과 a-Si:H 간의 etch rate와 etching selectivity를 관찰하였다.

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Detection and Distribution of the Pathogenic Bioagent Aeromonas (Gamma-Proteobacteria) in Water Supplies of Seoul (서울시 상수계통에서 병원성균 Aeromonas (감마-프로테오박테리아) 분포연구)

  • Lee, Eun-Sook;Lee, Mok-Young;Han, Sun-Hee;Ka, Jong-Ok
    • Korean Journal of Microbiology
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    • v.43 no.2
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    • pp.106-110
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    • 2007
  • The detection and distribution of Aeromonas in water supplies were investigated by using the USEPA Method 1605. Water samples were collected from the Han River, finished waters and tap waters supplied from Water Treatment Plants in Seoul monthly from July 2002 to December 2003. Aeromonas species in each water sample were quantified based on the development of yellow colonies on the surface of membrane filter using a selective medium (Ampicillin-Dextrin Agar with Vancomycin). The Quality Control (QC) for this study met the acceptance criteria of Method 1605. The concentrations of Aeromonas species in surface water samples ranged from $1.0{\times}10^{0}\;to\;9.8{\times}10^{3}\;CFU/ml$. Aeromonas species were found only in one tap water sample with concentration of 1 CFU/500 ml. No Aeromonas species were found in any finished water samples. Aeromonas species detected here were identified as A. salmonicida(51%), A. caviae(4.7%), A. schubertti(3.4%), A. sobria(3.8%), A. hydrophila(2.1%), and A. ichithiosmia(0.4%). A. salmonicida was the dominant species, which is of no significance to human health. Chlorine resistance of A. salmonicida was evaluated and as a result, 99.99% of A. salmonicida decreased after 30 seconds exposure at residual free chlorine 0.2 mg/L. These suggest that the waters supplied in Seoul may be safe against the pathogenic agent Aeromonas.

Manufacture of Printing and Writing Papers from Old Corrugated Containers (OCC) (Old Corrugated Containers (OCC)로부터 인쇄·필기용지 제조)

  • Lee, Goo;Ahn, Byoung-Jun;Paik, Ki-Hyon
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.367-373
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    • 1999
  • Increasing consumer demand for recycle of most paper products is challenging manufacturers to use lower value raw materials while maintaining high quality. This study was carried out to investigate the composition of old corrugated containers (OCC) and to manufacture printing and writing papers of over 85% (ISO) brightness by ECF and TCF bleaching from OCC. Fiber length of American old corrugated container (AOCC) was longer than that of Korean old corrugated container (KOCC) in fiber length. The former was composed of unbleached kraft pulp (UKP) of about 80 percentage, the latter about 20 percentage. OCC is feasible for manufacturing of pulps i.e., AOCC is for printing and writing papers and KOCC is for whiteboards, in the aspects of brightness and mechanical properties on the other hand, the cost of manufacturing upgraded papers by OCC is high because of bleaching chemicals. Neverthless, considering various aspects, especially environment, there are many advantages in recycling. In case of the treated AOCC pulp, over 85% (ISO) brightness can be achieved through TCF or ECF bleaching step, while the treated KOCC pulp did not allow high brightness through TCF bleaching. The tensile index of the bleached KOCC pulp was lower than that of the bleached AOCC pulp, but the burst and tear index of KOCC was higher than that of AOCC.

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Effects of Chlorine dioxide ($ClO_{2}$) Gas Treatment on Postharvest Quality of Grapes (포도의 Chlorine Dioxide Gas 훈증처리 및 저장방법에 관한 연구)

  • Chang, Eun-Ha;Chung, Dau-Sung;Choi, Jong-Uck
    • Food Science and Preservation
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    • v.14 no.1
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    • pp.1-7
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    • 2007
  • This study was conducted to determine if chlorine dioxide ($ClO_{2}$) gas might minimize microbial contamination of fresh produce. After exposing grapes to 20 ppm or 40 ppm of chlorine dioxide gas in a closed container, grapes treated with 20 ppm $ClO_{2}$ were packaged in Ny/PE/L-LDPE pouches, stapes treated with 40 ppm $ClO_{2}$ were placed in an empty corrugated box, and untreated control grapes were placed in a box with a sachet containing $ClO_{2}$ gas adsorbed to silica gel (a silica gel pad). The free volume of the sachet material allowed the release of $ClO_{2}$ gas into the headspace of packages containing fresh grapes. Control fruit not exposed to $ClO_{2}$, was placed in a box and stored at either $25^{\circ}C$ or $0^{\circ}C$. Fruit in Ny/PE/L-LDPE film treated with 20 ppm $ClO_{2}$ lost almost no weight during storage at either $25^{\circ}C$ or $0^{\circ}C$. Such fruit had a lower soluble solid content than did other fruit samples. Titratable acidity tended to fall rapidly during storage at either $25^{\circ}C$ or $0^{\circ}C$. Anthocyanin content of grapes decreased over 21 days at $25^{\circ}C$ but increased over 10 weeks at $0^{\circ}C$. The total microbial count of grapes treated with $ClO_{2}$ gas and silica gel pads were lower than controls at $25^{\circ}C$. Fruit treated with 20 ppm $ClO_{2}$ and packaged in Ny/PE/L-LDPE pouches had lower microbial counts than other fruit samples when stored at $0^{\circ}C$. The silica gel pad did not significantly improve total microbial count (compared to untreated control samples) at $0^{\circ}C$. This result may be attributed to a higher rate of diffusion of $ClO_{2}$ gas at room temperature.

Changes in Lipid Oxidation and Taste Compounds of Chicken Breast Meat by Slow-released ClO2 Gas Gel-pack during Storage (서방출형 이산화염소 가스 젤팩 첨가가 닭가슴육 저장 중 지질산패 및 정미성분의 변화)

  • Lee, Kyung-Haeng;Kwon, Hye-Won;Yoon, Ye-Ji;Kim, Hong-Gil
    • The Korean Journal of Food And Nutrition
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    • v.32 no.4
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    • pp.294-303
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    • 2019
  • To extend the shelf-life of chicken breast meat, samples were treated with gel-packs containing slow-released $ClO_2$ gas at 7-15 ppm for 8 days at $4^{\circ}C$. And the changes in lipid oxidation and taste compounds of the samples were investigated. TBARS value of the chicken breast was slightly increased during storage. TBARS value of gas treatments was similar to the control during storage. There were 14 fatty acids in the chicken breast. And there was no change in the fatty acid composition during storage, and there was no significant difference between the control and gas treatments. The content of free amino acids was gradually increased during storage. The content of free amino acids were not significantly different between the control and gas treatments during storage. The content of GMP in the control and gas treatments were decreased during storage. However, gas treatments showed slightly higher content than that of control. AMP was not significantly different between the control and gas treatments. IMP gradually decreased during storage and the content of inosine and hypoxanthine was increased. IMP, inosine and hypoxanthine contents of gas treatment were similar to control, but the control tended to change more rapidly than those of gas treatments.

A Study on the guidelines for Tasty and Healthy Drinking Water Supply (청정급수를 위한 쾌적수질기준 설정에 관한 기초조사 연구)

  • 금영환;문량조;유재근
    • Journal of environmental and Sanitary engineering
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    • v.10 no.1
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    • pp.106-125
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    • 1995
  • Recently, in accordance with elevation of life style and economics, the public demand became increasingly concerned about drinking water quality. Without an adequate supply of safe water, healthy and comfortable life could not exist. Therefore, the purpose of this study is to provide the guidelines and the basic informations to enable supply of clean, tasty and healthy drinking water acceptable for various demands. We analyzed the quality of tap water, mineral water, purified tap water using home tap water purifier. And we researched on the sense of the public complaint over the tap water. We proposed several items relating to the comfortableness of water quality and the target value. Also we presented a case of water supply system for purity and the points at problem The items and target value are as follows 1. turbidity : not more than 1 degree 2. dry residue : $30~200{\;}mg/{\ell}$ 3. hardness : $10~100mg/{\ell}$ 4. free carbon dioxide : not more than $20mg/{\ell}$ 5. $KMnO_{4}$ consumption not more than $3mg/{\ell}$ 6. odor threshold not abnormal 7. residual chlorine : not more than $0.4mg/{\ell}$ 8. water temperature' not more than $20^{\circ}C$ 9. manganese : not more than $0.01mg/{\ell}$ 10. iron : not more than $0.02mg/{\ell}$ 11. aluminum : not more than $0.1mg/{\ell}$

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Variations of Disinfection By-products in a Chlorinated Drinking Water Distribution System

  • Lee, Soo-Hyung;Park, Jeong-Kun;Lee, Hyung-Jun;Kim, He-Kap
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.2
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    • pp.71-78
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    • 2000
  • The chlorination of municipal drinking water supplies leads to the formation of so-called disinfection by-products(DBPs), many of which have been reported to cause harmful health effects based on animal studies. This study was conducted: 1) to observe seasonal changes in the major DBPs at four sampling sites on a drinking water distribution system located in Chunchon, Kangwon Do; and 2) to examine the effects of major water quality parameters on the formation of DBPs. During the field sampling, the water temperature, pH, and total and free chlorine residuals were all measured. The water samples were then analyzed for total organic carbon(TOC) and eight disinfection by-products in the laboratory. Chloroform, dichloroacetic acid, and trichloroacetic acid were the major constituents of the measured DBPs. The concentrations of the total DBPs were highest in fall, particularly in October, and lowest in summer. The concentrations of the total DBPs increased with increasing TOC concentrations. Multiple regression analyses showed that the concentrations of chloroform, bromodichloromethane, and chloral hydrate were linearly correlated with the pH. Other water parameters were not included in the regression equations. Accordingly, these results suggest that TOC and pH are both important factors in the formation of DBPs.

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The Effect of Hydrogen Peroxide Bleaching on the Properties of Hardwood Kraft Pulp Absorbed with Birchwood Xylan

  • Li, Lizi;Lee, Sang-Hoon;Lee, Hak-Lae
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2010.04a
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    • pp.195-206
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    • 2010
  • Xylan can be applied to improve the strength properties of paper; however the optical properties, such as brightness, are decreased significantly. To solve that problem, an applicable bleaching process is therefore desired. The aim of this research was to investigate the impact of hydrogen peroxide bleaching on hardwood kraft pulp pretreated with birchwood xylan by measuring optical properties (whiteness, brightness, opacity) as well as physical properties (tensile index, tearing index, bulk) of handsheets made from the bleached pulp. Hydrogen peroxide bleaching, as a kind of totally chlorine free (TCF) bleaching method, is quite important industrially for chemical pulp. In our work, the process variables of peroxide bleaching including bleaching temperature, time, initial pH and $MgSO_4$ dosage were studied. The results showed that both good mechanical properties and optical properties could be achieved when the operating parameters were controlled properly and therefore hydrogen peroxide bleaching was proved to be a suitable method for bleaching hardwood kraft pulp with adsorption of birchwood xylan.

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Developing Trend of Clean Propellants (청정 추진제 개발 동향)

  • Kim In-Chul;Ryoo Baek-Neung;Kim Chang-Kee
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.5-8
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    • 2005
  • In this report the developing trends of several clean and green propellants have been summarized. A low-acid clean propellant has been developed, which substantially reduced the content of hydrochloric acid(HCl) in the solid rocket exhaust. Although the chlorine-free approach is now preferred, this technology has not been proved yet. Another acid suppression effect of Magnalium(Mg-Al Alloy) was investigated. Reports says that the concentration of HCl could be reduced to approximately one-fifth of conventional propellant. Many 'green' propellants with low toxicity are being developed for next-generation post-boost propulsion systems, in which combustion research on the Al or Mg fine metal particles with hot steam in various stoichiometric conditions are being performed.

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Microbial Quality and Safety of Fresh-Cut Broccoli with Different Sanitizers and Contact Times

  • Das, Basanta Kumar;Kim, Ji-Gang
    • Journal of Microbiology and Biotechnology
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    • v.20 no.2
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    • pp.363-369
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    • 2010
  • This study was conducted to investigate the effects of different sanitizers and contact times on storage quality and microbial growth in fresh-cut broccoli. Fresh broccoli samples were cut into small pieces, washed each for 90 s and 180 s in normal tap water (TW), $100\;{\mu}/l$ chlorinated water (CL, pH 7), electrolyzed water (EW, pH 7.2) containing $100\;{\mu}/l$ free chlorine, or $2\;{\mu}/l$ ozonated water ($O_3$). Then, samples were packaged in 30-${\mu}m$ polyethylene bags and stored at $5^{\circ}C$ for 9 days. No significant differences were observed in gas composition and color parameters ($L^*$, $a^*$, $b^*$, and hue angle) among different sanitizers with contact times. No off-odor was detected during the storage. A longer contact time was not effective in reducing microbial population, except with $O_3$ washing. $O_3$ with 90 s was not much effective in reducing microbial population compared with Cl or EW. However, samples washed with $O_3$ for 180 s observed the lowest numbers of total aerobic and coliform plate counts. The result suggested that, a longer contact time of ozone can be used as a potential sanitizer to maintain the microbial quality and safety of fresh-cut broccoli.