• 자원환경지질
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• 제21권4호
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• pp.335-348
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• 1988

The author aimed to describe the volcano-stratigraphy and petrology of the volcanic mass in the Koheung peninsula, South Cheolla province. The volcanic mass is composed of the volcanics and intrusives of late Cretaceous which extruded the Pre-cambrian metamorphic(Jirisan gneiss complex) and the early Cretaceous sedimentary(Duwon Formation) basement. The volcanic pile consists of, in ascending order, Bibongsan andesite, Koheung tuff and breccia, and Palyeongsan welded tuff, and are intruded by ring intrusives( intrusive breccia, andesite porphyry, intrusive rhyolite and fine-grained quartz-diorite) and central pluton(diorite, quartz monzodiorite, biotite granite and micrographic granite). Bibongsan andesite mainly consists of andesite tuff and lava. Koheung tuff consists of alternation of fine tuff, coarse tuff and lapilli tuff, and Palyeongsan welded tuff which overlies Koheung tuff, comprises K-feldspar and quartz phenocrysts, elongated brown fiamme, lithic fragments in matrix of devitrified brown glass shards, and mainly consists of rhyodacite to rhyolite vitric ash-flow tuff. The results of petrochemical studies of the igneous rocks suggest that the rocks were a serial differentiational products of fractional crystallization of calc-alkaline magma series. This study reveals that the volcanic mass in this area is inferred to the remnant of the resurgent cauldron, measuring 30 by 25 km in diameter. The cauldron block was lowered at least 1,000 m by ring fault displacement.

• 자원환경지질
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• 제33권1호
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• pp.19-30
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• 2000

The Sannae-Eonyang granitic rocks are a large fossil hydrothermal system containing the Sannae Mo-W fissure-vein type and the Eonyang amethyst deposits in the southeastern Kyongsang Basin. They evolved through similar stages showing the similarities in chemical and mineralogical compositions, fractionation trends and early magmatic fluids. Major, trace and rare earth element(REE) variations can be accounted for fractional crystallization combined with variable degrees of metasomatism. Based on the aqueous fluids exsolved directly from the crystallizing melt, the Sannae-Eonyang granitic rocks were emplaced at similar depth or pressure conditions. High temperature fluid interaction with the granitic rocks affects the elements such as K, Na, Rb, Ba, Sr, Eu, and heavy REE (HREE) mostly through feldspar re-equilibration. Although hydrothermal fluids produced partly positive Eu anomalies and HREE depletion in the granitic rocks at the Sannae Mo-W mine, the chemical concentrations defining fractionnation trends have survived the effects of alteration. Aqueous fluids exsolved from the crystallizing melt appears to be widespread, whereas fluids of moderate to low salinity and low-density with relatively high homogenization temperatures and $Co_2$-rich fluids appear to be mainly restricted and responsible for Mo-W and amethyst mineralization, respectively. Hydrothermal system of the Sannae-Eonyang granitic rocks represents repeated fluid events; from exsolution of aqueous fluids from the crystallizing melt, through fluid immiscibility and meteoric convection to later mineralization.

• 자원환경지질
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• 제23권1호
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• pp.105-123
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• 1990

Igneolls rocks of the Hamyang area consist of Hamyang foliated granites and hornblende diorite. Hamyang foliated granites are classified into four rock types in terms of mineral composition and texture. The four rock types are foliated hornblende biotite granodiorite, foliated porphrytic granodiorite, foliated fine biotite granodiorite and foliated leuco granite. Petrochemical data of these rocks suggest that Hamyang foliated granites is calc-alkali rock series of differentiated products of cogenetic magma by fractional crystallization. Igneous rocks of studied area correspond to I-type, peraluminous and calc alkali rock series. Rb-Sr age and $Sr^{87}/Sr^{86}$ initial ratio for foliated prophrytic granodiorite is $200{\pm}Ma$and $0.711{\pm}0.0037$, respectively. K-Ar(hornblende) age of hornblende diorite is $179{\pm}9Ma$. These data come to an coincidence with Igneous activity of South Korea which were proposed by O.J. Kim(1975), that is, they correspond to Hamyang foliated granites of products of Songrim Disturbance, and to hornblende diorite of Daebo Orogeny.

• Ocean and Polar Research
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• 제23권1호
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• pp.23-34
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• 2001

Geochemical and Sr-Nd isotopic compositions and K-Ar ages are analyzed in volcanic rocks from Weno Island, Caroline Islands. Seven Weno lava samples of alkali basalt and basaltic trachyandesite are aphyric or sparsely phyric comprising olivine, plagioclase, and clinopyroxene phenocrysts. Whole-rock geochemical variation of Weno lavas reflects main fractional crystallization of olivine and Cr-spinel phenocrysts. Newly determined K-Ar ages of Weno lavas range from 6.7 to 11.3 Ma (late Miocene), indicating their formation during primary volcanic stage of Chuuk Islands. Trace element compositions of Weno lavas are very similar to those of typical ocean island basalts (OIBs), suggesting their formation during intra-plate mantle plume activity. The plume composition is isotopically very similar to that of Hawaiian hot spot. However, the age span of Chuuk volcanism is longer than that of the other individual volcanoes in the Pacific.

• Archives of Pharmacal Research
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• 제17권3호
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• pp.135-138
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• 1994

Acyclonucleoside homologues of 1-$(\omega$-cyabnoalkyl)-and 1, 3-bis $(\omega$-cyanoalkyl) uracils were synthesized by the series of alkylation reactions of uracil with the $\omega$-chloroalkyl nitrile ${(Cl-(CH}_2)_n$-CN;n=1, 2, 3, 4) in DMSO under $50-70^circ{C}$ temperature. The 1-$(\omega$-cyanoalkyl)-and 1, 3-bis$(\omega$-cyanoalkyl) uracils were separated either by the fractional crystallization or column chromatography. The antitumor activities for these synthesized compounds were determined against four cell lines (J-82 cell, P388 cell, FM-3A cell and U-937 cell lines). These compounds failed to exhibit any significant antitumor activity.

• 자원환경지질
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• 제25권4호
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• pp.435-446
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• 1992

REE, major and trace elements analyses of the Jurassic Daebo granite and Cretaceous Bulguksa granite were carried out to interpet their petrogenesis and relationships between petrogenesis and tectonics. Analytical results are summarized as follows. (1) $SiO_2$ content of the Bulguksa granite (aver. 74.6%) are significantly higher than those of the Daebo granite (aver. 68.1%). Major elements of $TiO_2$, $Al_2O_3$, $P_2O_5$, CaO, MgO, Total FeO, and trace elements of Co, V and Sr are negatively correlated with $SiO_2$. Incompatible elements such as Ba, Sr, Y, Zr and HREE are contained differently in the Bulguksa granites distributed in between Okchon folded belt and Kyongsang sedimentary basin. (2) Trace element abundances show a good discrimination between two goups of granitic rocks. Ba, Sr and V are enriched in Daebo granites, while Zn and Cr are depleted in them. (3) Jurassic granites have quite different Eu anomalies and REE patterns from those of Cretaceous granites: Large negative Eu anomaly in the former and mild or absent Eu anomaly in the latter. The large Eu negative of Cretaceous granitic rocks are interpreted as a differentiated product of fractional crystallization of granitic magma from the upper mantle. Meanwhile, the Daebo plutonic rocks was resulted from the partial melting of subcrustal material or crustal contamination during ascending granitic magma from the mantle. Senario of igneous activities of Mesozoic age in South Korea was proposed based on Kula-Pacific ridge subduction model.

• 자원리싸이클링
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• 제19권6호
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• pp.27-35
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• 2010

희토류 원소의 합금과 화합물은 첨단 산업용 소재의 구성성분이다. 국내에 모나자이트가 매장되어 있으나 자원개발에 많은 어려움이 있다. 희토류광석은 극히 일부 국가에만 매장되어 있고 자국산업의 보호를 위해 수출 통제의 대상이 되고 있다. 희토류 광석의 95%를 차지하는 bastnasite, monazite와 xenotime로부터 희토류 성분을 회수하는 습식과 건식제련공정을 조사하였다. 또한 첨단 소재용으로 사용되는 희토류 화합물은 6N정도의 순도가 요구되므로 희토류 성분을 분리할 수 있는 분별결정, 분별석출, 이온교환 및 용매추출에 대해 조사하였다.

• 자원환경지질
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• 제48권6호
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• pp.431-449
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• 2015

연구지역은 영남육괴 지리산지구에 분포하는 선캠브리아기 암주상 산청 회장암복합체 (이하, 회장암체)의 서부에 위치한다. 본 논문은 산청 회장암체에 대한 노두별 상세한 야외지질조사를 통하여 산청 회장암체의 암상, 엽리, 산상의 특징을 조사하고, 산청 회장암체의 형성과정과 그 메커니즘을 연구하였다. 산청 회장암체는 괴상형과 엽상형 산청 회장암 (이하, SA), 철-티탄 광체 (이하, FTO), 고철질 백립암 (이하, MG)으로 구분된다. 괴상형 SA를 제외한 산청 회장암체에는 엽리가 발달한다. 엽상형 SA, FTO, MG의 엽리는 SA가 완전히 고결되지 않은 물리적 상태에서 FTO 및 MG 용융체의 유동과 SA 블록들 사이의 상호운동의 결과로 형성된 마그마 엽리이며, 이들은 동원 마그마의 분화작용을 통해 연속적으로 형성되었다. 산청 회장암체는 괴상형 SA (고압 하에서 모 마그마의 1차 분별정출작용)${\rightarrow}$ 엽상형 SA [저압 하에서 모 마그마로부터 1차적으로 분화된 사장석-풍부 결정-용융 혼합체 (회장암질 마그마)의 2차 분별정출작용]${\rightarrow}$ FTO (회장암질 마그마의 2차 분별정출작용의 최종 분화단계에 잔류된 고철질 마그마의 압착여과작용에 의해 완전히 고화되지 않은 SA로 주입)${\rightarrow}$ MG (최종 잔류된 고철질 마그마의 고화작용) 순으로 형성되었다. 이는 산청 회장암체를 구성하는 괴상형과 엽상형 SA, FTO, MG는 성인과 시대를 달리하는 서로 다른 마그마의 분화 및 관입 산물이 아니라 동일시대의 동일기원 마그마로서 다단계 분별정출작용과 다중압력 결정화작용을 통해 형성되었음을 의미한다.

• 자원환경지질
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• 제35권1호
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• pp.75-95
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• 2002

안동심성암체는 3개 암상으로 구분되는 동원성 마그마로부터 유래되었다. 이 암체는 전체적으로 중앙부에 각섬석 흑운모 토날라이트가 노출되고 이의 연변부에 흑운모 화강섬록암이 놓이며, 상단부(복동부)에 반상 흑운모 화강암이 놓인다. 결과적으로 이들은 토날라이트를 중심으로 하는 동심원상 분포를 하며, 중앙부에 고온 광물군의 고철질 암석이 우세하고 연변부와 상단부로 갓수록 보다 저온 광물군의 규장질 암석이 우세한 역누대를 나타낸다. 이 암체의 모드 및 화학 자료는 중앙부에서 연변부, 상단부 순으로 역누대 조성변화를 보여준다. 이 조성변화는 인접하는 암상간에서 매우 점이적으로 변화한다. 각섬석과 흑운모 등의 고철질 광물은 중앙부의 토날라이트에서 가장 풍부하고 연변부로 갈면서 감소하고 상단부로 갈수록 더욱 감소한다. 석영과 K-장석 등의 규장질 광물은 이와 반대로 변화한다. 화학적으로도 고철질 광물을 지배하는 원소들은 중앙부에서 최고치이고 이로부터 연변부와 상단부로 갈수록 점차 감소되는 양상을 보이며, 반면에 규장질 광물을 주로 지배하는 원소들은 이와 반대 양상을 나타낸다. 이 역누대 심성암체는 열중력확산작용과 분별결정작용에 의해 수정된 마그마챔버의 상부 규장질 부분 속으로 하부의 더 고철질 부분이 재이동(소생)된 결과이다. 진화의 초기 단계에 , 이 마그마챔비는 하부에 토날라이트질, 중부에 화강섬록암질, 상부에 화강암질 마그마를 갖는 화학적 조성누대를 이룬 암석화학계이었다. 후기 단계에 챔버 기저에서 더 고철질 마그마의 유입에 의해 하부의 토날라이트질 조성대가 상부의 규장질 조성대 속으로 재이동을 야기시켰다.

• 자원환경지질
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• 제27권2호
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• pp.181-190
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• 1994

Petrochemical study on the micrographic granite distributed in the Wando area, the southernmost part of the Yeongdong-Kwangju depression is performed to investigate the petrogenesis and differentiation processes of the granitic magma. Polarized light microscopy for modal analyses, electron probe microanalyses of feldspars and biotite, inductively coupled plasma analyses for major and trace element contents were adopted in the study. The lithology of the study area consists of Precambrian metasediments, Mesozoic volcanic and sedimentary rocks, and micrographic granite which intrude into the former. The micrographic granite in the Wando area are distributed in the shape of a cauldron. Modal and nonnative mineral analyses of the micrographic granite fall in the area of granite and granodiorite. The chemical composition indicates that the micrographic granite is I-type and magnetite series. The micrographic granite is characterized by more than 90% of micrographic texture in volume percent. Feldspars in the micrographic granite is alkali feldspars (Or, 45~93) and plagioclases (albite to oligoclase). The biotite has a intermediate composition between phlogopite and annite solid solution. The results of the petrochemical studies indicate that the granitic magma of calc-alkaline source materials reactivated in a compressional environment at the continental margin, and then was differentiated by fractional crystallization. The micrographic granite intruded into a shallow level of the crust (5~7 km) in the late Cretaceous.