• Title/Summary/Keyword: Fouling materials

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Membrane Technologies in Biotechnology (생물공학에서의 막분리기술)

  • 구윤모
    • Membrane Journal
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    • v.8 no.2
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    • pp.69-76
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    • 1998
  • Membrane technologies have been used frequently in industries, taking advantage of that it is energy-saving and employable in relatively large scale. The fact that a non-mass separating agent is used in mild conditions without phase change in membrane separation makes it a method of choice in the recovery of biological materials. Recently, the development of noble separating modules has been solving the inherent problems in membrane separation, the fouling and the concentration polarization. In addition, membrane separation has broadened its applications from the conventional crude separation to the purificational use by the advent of the new and functional membrane materials. The role of membrane technologies is expected to be enormous in the production and recovery of biological products, considering the excellent applicability of membrane in the fields of integrated separation and in-situ separation, the two trends in modem bioseparation.

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Problems and Control Measures of Industrial Cooling Water (공업용 냉각수의 문제점과 처리법)

  • Bae, Jong-Su;Lee, Gyu-Hwa
    • 한국기계연구소 소보
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    • s.16
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    • pp.117-126
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    • 1986
  • Trouble-free operation of cooling water systems is essential for efficient pro¬duction in most industrial facilities. Improper water treatments frequently cause such problems as corrosion, scaling, fouling and slime formation. Water quality, methods of cooling and materials of construction in the cooling circuit should be carefully studied before making selection of the water treatment programs. This paper reviewed cooling water problems encountered frequently in the open recirculating cooling systems and discussed the counter measures how to cope with them.

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Research on the Replacement of Bed Material and Multifunctional Additives in Circulating Fluidized Bed Combustion Using Solid Fuels (고형연료사용 순환유동층 연소로에서의 유동사 대체 및 다기능성 첨가제에 관한 연구)

  • Park, In su;Nam, Jeong soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.115-116
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    • 2023
  • In this study, it was confirmed whether kaolin can play a role as a bed materials and a role in reducing clinkers by using kaolin with a bed materials for the purpose of removing clinkers such as slagging and fouling generated in circulating fluidized bed combustion furnaces using solid fuel.

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New Gain Function Based on Attenuation Characteristics of Ballast Track for GPR Analysis (GPR 분석을 위한 자갈궤도 자갈의 감쇄특성을 이용한 이득함수 개발)

  • Shin, Jihoon;Choi, Yeongtae;Jang, SeungYup
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.4
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    • pp.13-21
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    • 2017
  • Ballasted track has been used as track system for more than 100 years. Ballasted track has advantages of low construction cost, flexible maintenance, low noise and vibration, and so on. However, ballasted track leads to continuous settlement which causes maintenance. Recently, increase in speed, traffic volume, and weight of train requires more frequent maintenance. Fouling, well-known phenomenon of accumulation of fine materials due to intrusion of subgrade and breakage of ballast materials, expedites the settlement (i.e., irregular settlement) of track. Ground Penetrating Radar (GPR) can be one of non-destructive tools that can evaluate fouling level of ballast. In this paper, a gain function based on the attenuation characteristics of ballast material is suggested in conjunction with Hilbert transform. Lab box tests and full-scale tests indicate that the suggested method reasonably classifies clean, fouled layers, and subgrade. However, additional study to eliminate effect of sleeper and to include the scattering features of the electromagnetic wave in ballast voids should be required in order to enhance the accuracy.

Electrokinetics Evaluation of Poly(styrene-ethylene-butylene-styrene) Based Anion Exchange Membrane (Poly(styrene-ethylene-butylene-styrene)계 고분자 음이온교환막 계면동전위 특성평가)

  • Son, Tae Yang;Yun, Jun Seong;Han, Song I;Nam, Sang Yong
    • Membrane Journal
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    • v.27 no.5
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    • pp.399-405
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    • 2017
  • The zeta potential, called an electrokinetic potential, refers to the potential difference caused by electrodynamic phenomenon, which is a value obtained by quantifying the surface charge property. The zeta potential has been actively studied for membrane fouling, confirmation of modification and substituent confirmation through surface charge analysis. The methods of measurement for zeta potential were developed on the basis of electrophoresis, electrosmosis and streaming potential. Among them, it was known that the streaming potential method was suitable for the flat sheet membrane. So, in this study, aminated poly(styrene-ethylene-butylene-styrene) membranes were prepared by introducing ammonium groups and the streaming potentials of the prepared membranes were measured by using an electrokinetic potential analyzer (SurPASS) and the results were analyzed.

Characterization of Membrane Fouling and It's Optimal Chemical Cleaning Method in MF Process using D dam water (D댐수를 이용한 정밀여과 공정에서 막오염 특성 및 최적 화학세정방법 조사)

  • Kim, Chung H.;Lim, Jae L.;Lee, Byung G.;Chae, Seon H.;Park, Min G.;Park, Sang H.
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.5
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    • pp.559-569
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    • 2007
  • The purposes of this study were to find the main foulant of membrane and the optimal chemical cleaning method for MF(microfiltration) drinking water treatment system using D dam water as water source. The MF pilot plant which can treat maximum $500m^3/d$ consisted of 3 racks and was operated for 10 months under various operation conditions. After 10 months operation, $1^{st}$ and $2^{nd}$ rack of membrane pilot plant system were cleaned chemically and the degree of the restoration of the fouled membrane in terms of the pure water flux was detemnined. Inorganic compounds which contained in chemical cleaning waste was analyzed by Inductively Coupled Plasma (ICP). One membrane module for 3rd rack was disjointed and membrane fouling materials, especially inorganic compounds were investigated by Electron Probe Microanlysis (EPMA) to elucidate the reason of TMP increase. And also, the various chemical reagents (1N HCl or $H_2SO_4$, oxalic acid as acid and 0.3% NaOCl as alkali) were tested by combination of acid and alkali to determine the optimal chemical cleaning method for the MF system using micro-modules manufactured using the disjointed module. It was verified that the inside and outside of membrane module was colorized with black. As a result of the quantitative and semi-qualitative analysis of membrane foulant by ICP, most of inorganic foulant was manganese which is hard to remove by inorganic acid such as HCI. Especially, it was observed by EPMA that Mn was attached more seriously in inside surface of membrane than in outside surface of that. It was supposed that Mn fouling in inside surface of membrane might be caused by the oxidation of soluble manganese (Mn(II)) to insoluble manganese ($MnO_2$) by chlorine containing in backwashing water. The optimal cleaning method for the removal of manganese fouling was consecutive cleaning with the mixture of 1N HCl and 1% of oxalic acid, 0.3% NaOCl, and 1N HCl showing 91% of the restoration of the fouled membrane.

Fouling Study with Binary Protein Mixtures in Microfilration (이성분계 단백질 혼합물의 미세막 분리공정에서 막오염에 관한 연구)

  • Ahn, Byung Hun;Moon, Dong Ju;Yoo, Kye Sang;Ho, Chia Chi
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.236-242
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    • 2005
  • Membrane fouling by protein mixtures during microfiltration has been investigated for binary mixtures of bovine serum albumin (BSA), casein, lysozyme, pepsin, and ovalbumin. Filtration experiments were carried out using $0.2{\mu}m$ polycarbonate track-etched (PCTE) membrane in a stirred cell under constant transmembrane pressure (14 kPa) and concentration of hydrogen ion (pH=11) to study the effect of mixture composition on filtrate flux decline. Flux decline data were analyzed using a pore blockage-cake formation model developed recently. It was found that the model is in a good agreement with the experimental data. Fouling parameters such as the rate of pore blockage(${\alpha}$), the initial resistance of the protein deposit ($R_{po}$) and the increasing rate of the protein layer resistance(${\beta}$) were used to evaluate the rate of filtrate flow by membrane fouling in the binary mixture system. Generally, the trend of ${\alpha}$ is comparable with that of filtrate flux decline. It was also found that fast flux decreasing was observed over the binary mixture containing casein. The result is due to high value of the initial resistance of the protein deposit ($R_{po}$) over casein.

Removal of Ammonia in Water using Acid-impregnated Activated Carbon and Dynamic Membrane System (산 첨착활성탄과 동적막 공정을 이용한 수중 암모니아 제거)

  • Choi, Won Kyung;Shin, Dong-Ho;Lee, Yong Taek
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.310-316
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    • 2006
  • In this study, activated carbon in a powder form was used to remove dissolved ammonia which causes a fouling smell in water. Since the adsorption capacity of common powder activated carbon is not high enough, we prepared powder activated carbon deposited on an acid solution to enhance the adsorption capacity. The acid-impregnated activated carbon was applied on the surface of porous fibril support ($10{\sim}50{\mu}m$) by which adsorption and separation processes take place simultaneously by varying effective pressure. As the result, the ammonia removal efficiency is above 60% in the mixing process which is 10~15% higher than general powder activated carbon. From the result of an experiment on the pure permeable test of a dynamic membrane, its transmittance is 400~700 LMH (liter per hour), indicating that the prepared membrane works as a microfiltration membrane. Therefore, it is expected that the membrane prepared in this way would improve the efficiency of water treatment than conventional membranes.

Surface Modification of Polypropylene Membrane by ${\gamma}$ Irradiation Methods and their Solutes Permeation Behaviors

  • Shim, J. K.;Lee, S. H.;Kwon, O. H.;Lee, Y. M.;Nho, Y. C.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.99-101
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    • 1998
  • 1. Introduction : The conventional grafting polymerization technique requires chemically reactive groups on the surface as well as on the polymer chains. For this reason, a series of prefunctionalization steps are necessary for covalent grafting. The surface prefunctionalizational technique for grafting can be used to ionization radiation, UV, plasma, ion beam or chemical initiators. Of these techniques, radiation method is one of the useful methods because of uniform and rapid creation of active radical sites without catalytic contamination in grafted samples. If the diffusion of monomer into polymer is large enough to come to the inside of polymer substrate, a homogeneous and uniform grafting reaction can be carried out throughout the whole polymer substrate. Radiation-induced grafting method may attach specific functional moieties to a polymeric substrate, such as preirradiation and simultaneous irradiation. The former is irradiated at backbone polymer in vacuum or nitrogen gas and air, and then subsequent monomer grafting by trapped or peroxy radicals, while the latter is irradiated at backbone polymer in the presence of the monomer. Therefore, radiation-induced polymerization can be used to modification of the chemical and physical properties of the polymeric materials and has attracted considerable interest because it imparts desirable properties such as blood compatibility. membrane quality, ion excahnge, dyeability, protein adsorption, and immobilization of bioactive materials. Synthesizing biocompatible materials by radiation method such as preirradiation or simultaneous irradiation has often used $\gamma$-rays to graft hydrophilic monomers onto hydrophobic polymer substrates. In this work, in attempt to produce surfaces that show low levels of anti-fouling of bovine serum albumin(BSA) solutions, hydroxyethyl methacrylate(HEMA) was grafted polypropylene membrane surfaces by preirradiation technique. The anti-fouling effect of the polypropylene membrane after grafting was examined by permeation BSA solution.

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