• 제목/요약/키워드: Fluidity Properties

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석유계 피치가 첨가된 고온 탄소복합재용 페놀수지의 열 유변학적 거동 연구 (Thermo-rheological behaviors of Phenolic Resins Blended with Petroleum-based Pitches for High Temperature Carbon Composites)

  • 양재연;국윤수;서민강;김병석
    • Composites Research
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    • 제33권6호
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    • pp.329-335
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    • 2020
  • 본 연구에서는 각각에 다른 연화점을 갖는 석유계 피치의 열 유변학적 특성을 연구하였으며, 이를 함침용 페놀수지에 석유계 피치를 첨가하여 B-stage 형태의 페놀수지/석유계 피치 혼합물을 제조하였다. 그 결과, 연화점이 다른 석유계 피치는 QI의 함량이 증가할수록 피치의 유동성이 감소하였고, 고체의 점탄성 특성을 나타내었다. 또한, 다른 연화점을 갖는 석유계 피치를 페놀수지에 첨가함으로써, 페놀수지의 경화거동과 열 유변학적 특성에 미치는 영향에 대해 고찰하였을 때, 다른 연화점의 석유계 피치를 첨가함에 따라 페놀수지의 경화속도 및 경화거동을 조절할 수 있었으며, 이 중 P-Pitch 2가 첨가된 페놀수지 혼합물의 경우 동일한 경화 온도조건에서 다른 혼합물에 비해 유동성이 높은 것을 확인할 수 있었다.

도라지 분획성분이 인지질막 Liposome의 유동성에 미치는 영향 (The Effect of the Membrane Fluidity of Bellflower(Platycodon grandiflorum A.) Fractions on Liposomal Phospholipid Membranes)

  • 배송자;강보영
    • 생명과학회지
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    • 제12권2호
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    • pp.121-128
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    • 2002
  • 세포막 유동성은 생체의 항상성 유지의 가장 기본적이며 중요한 기능으로서, 도라지의 용매별 분획물의 첨가로 세포막 유동성에 미치는 영향을 열시차 열량분석법 (differential scanning calorimetry, DSC)으로 측정하였다. DPPC liposome에 도라지의 용매별 분획물 첨가시 첨가물의 농도 증가에 따라 서서히 상전이 온도가 저하되었고 thermogram도 넓어졌으며 이에 따라 협동 단위($\Delta$ $H_{vH}$ /$\Delta$ $H_{cal}$)수도 감소됨을 알 수 있었다. 이는 도라지 분획물의 첨가로 DPPC liposome의 유동성이 증가하였음을 보여주는 결과로 생각 되어진다. 시료의 각 용매별 분획물의 유동성 효과는 ethyl-ether 분획층인 PGMEE의 경우 상전이온도 Tm이 시료첨가 최고농도에서 DPPC liposome 만의 경우보다 4.3$^{\circ}C$가 저하되어 다른 분획물보다 그 정도가 두드러졌으며 그 순서는 hexane 분획층 PGMH, ethylacetate 분획층인 PGMEA 및 methanol 분획층 PGMM의 순이었으며 butanol 층인 PGMB는 그 효과가 미미하여 앞서의 열역학적 요소에 거의 영향을 미치지 못했다. 이와 같은 결과는 PGMB를 제외한 시료의 각 분획물 성분 중 분자내 hydrophobicity가 큰 물질들이 DPPC liposome 이중층의 소수성부분에 더 깊숙히 침투됨으로써 인지질 liposome의 유동성을 증가시킨 현상이라고 생각된다. 도라지의 용매별 분획물의 막유동성 증가는 이온, 약물, 영양물의 흡수, 수송 및 교환등 생체막의 주요기능에 영향을 미치므로 막유동성을 증가시키는 도라지 분획물들의 생리활성물질에 대한 더욱 구체적인 연구가 기대되어 진다.

보통강도 고유동 콘크리트용 PC계 고성능 감수제를 사용한 시멘트 페이스트의 레올로지 특성 평가 (The Rheology of Cement Paste Using Polycarboxylate-Based Superplasticizer for Normal Strength-High Fluidity Concrete)

  • 공태웅;이한승
    • 한국건설순환자원학회논문집
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    • 제9권3호
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    • pp.276-286
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    • 2021
  • 기존 고유동 콘크리트는 소요의 유동성과 작업성 확보를 위해 대부분 단위시멘트량이 높은 고강도 콘크리트 영역으로써, 현재 사용되고 있는 대부분의 콘크리트 구조물이 보통강도(18~35MPa) 수준임을 감안한다면 현실적인 사용범위확대 및 실용성에 한계가 있었다. 고유동 콘크리트의 사용범위를 확대하기 위해 보통강도 수준에서도 유동성과 점성을 발휘할 수 있고 일반건축물뿐만 아니라 특수건축물에서도 사용가능하며, 타설시간과 인건비를 대폭 감축할 수 있는 보통강도 고유동 콘크리트의 개발이 필요한 실정이다. 보통강도 고유동 콘크리트의 개발은 유동성 및 점성을 발휘하여 자기 충전성을 확보함으로써 다짐작업 최소화에 따른 인건비 감축, 공사비 절감, 공기 단축 등의 시공효율성 뿐만 아니라 공사품질을 향상시킬 수 있다. 본 연구에서는 출발원료(WR, HB, RT)의 조합별로 PCE를 제조하고 링플로콘과 회전형 점도계를 사용하여 시멘트 페이스트의 레올로지 특성을 분석하였다. 실험결과 WR 80%, HB 6.5% RT 13.5%를 조합한 PCE를 적용할 경우, 결합재량이 낮은 보통강도 고유동 콘크리트에서 소성점도를 확보하면서 항복응력은 최소화시킬 수 있으며 동시에 높은 분산효과로 인한 고유동성의 확보가능성을 확인할 수 있었다.

고강도 Self-Leveling재의 최적 결합재비 (The Optimum Binder Ratio for High-Strength Self-Leveling Material)

  • 김진만
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2002년도 학술.기술논문발표회
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    • pp.67-76
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    • 2002
  • Self-leveling material(SLM) is one of the floor finishing materials which make flat surface like as water level by itself in a short time. So it is possible to increase construction speed and enhance economical efficiency. In this study, author intended to develop SLM for the industrial warehouse and factory loading heavy weight machinery and vehicles. The demanded properties for this type of SLM are above 20mm of flow value and above 300kgf/cm2 of 28-days compressive strength. To possess demended strength and fluidity, SLM have to be composed of many types of binders and chemical additives. So it is difficult to decide suitable mixing proportion of composition materials. In this study, author investigated the weight percentage effect of main composition materials for high-strength self-leveling material, by experimental design such as tables of orthogonal arrays and simplex design, and by statistical analysis such as analysis of variance and analysis of response surface. Variables of experiments were ordinary portland cement(OPC), alumina cement(AC), anhydrous gypsum(AG), lime stone(LS) and sand, and properties of tests were fluidity of fresh state and strength of hardened state. Results of this study are showed that suitable mix proportions of binders for the high strength self-leveling materials are two groups. One is 78~85.5% OPC, 7.5~9.5% AC, 9~12.5% AG and the other is 72.5~78% OPC, 9~12.5% AC, 13~l5% AG.

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Al-2Zn-0.2Fe-xMg 합금의 물성 및 주조특성에 미치는 Mg함량의 영향 (Effects of Mg Content on the Properties and Casting Characteristics of Al-2Zn-0.2Fe-xMg Alloys)

  • 김정민;박준식;김기태;고세현
    • 한국주조공학회지
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    • 제32권2호
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    • pp.86-90
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    • 2012
  • Aluminium-silicon based casting alloys have received an attention for high electrical and thermal conductivity applications, however relatively low conductivity of Al-Si alloys often limits the application. Efforts have been made to develop new high conductivity aluminium casting alloys containing no or less silicon. In this study Al-Zn-Fe based alloys were selected as the new alloys, and the effect of Mg additions on their properties and casting characteristics were investigated. As the magnesium content was increased, the tensile strength of Al-2Zn-0.2Fe based alloy was remarkably increased, while the electrical conductivity was deteriorated. It was observed that the fluidity of the alloys was generally inversely proportional to the Mg content but the hot cracking resistance was rather proportional to it. Cooling curve analyses were carried out to measure the actual solidification range and dendrite coherency temperature.

초음파 진동에 의한 A328 알루미늄 합금 용탕의 탈가스 (Degassing of Molten A328 Aluminum Alloy by Ultrasonic Vibration)

  • 최경환;장훈;임정규;김상섭;조규섭
    • 한국주조공학회지
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    • 제31권6호
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    • pp.342-346
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    • 2011
  • A328 alloy is an attractive candidate for recycle-friendly aluminum alloy in the recycling of automotive components. In this study, A328 alloy melt was degassed by ultrasonic vibration and the effect of treatment time on the density, fluidity and mechanical properties was investigated. Experimental results reveal that a constant value of density can be reached after less than 180 seconds of ultrasonic treatment time, but the density decreased when the treatment time was 300 seconds. Ti which was dissolved from the horn during ultrasonic treatment reduced the fluidity of melt. After degassing by ultrasonic vibration for 180 seconds, tensile strength increased from 201MPa to 250MPa, and elongation increased from 2.38% to 3.50%, however, further treatment deteriorated the mechanical properties.

Al-Zn-Fe-Si 합금의 물성 및 주조특성 (Properties and Casting Characteristics of Al-Zn-Fe-Si Alloys)

  • 윤호섭;김정민;박준식;김기태
    • 한국주조공학회지
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    • 제33권1호
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    • pp.8-12
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    • 2013
  • Although aluminum-silicon based commercial casting alloys have been used in applications that demand high electrical or thermal conductivity, new aluminum casting alloys that possess higher conductivities are currently required for advanced applications. Therefore, there is much research into the development of new high conductivity aluminum casting alloys that contain lower amounts of or no silicon. In this research, the properties and casting characteristics of Al-Zn-Fe-Si alloys with various Fe and Si contents were investigated. Two types of AlFeSi phases were formed depending on the Fe and Si contents. As the silicon content increased, the tensile strength of the Al-Zn-Fe-Si alloy increased slightly, while the electrical conductivity decreased slightly. It was also observed that both the fluidity and hot cracking susceptibility of the investigated alloys were closely related to the formation of the AlFeSi phases.

석탄화도의 지표와 석탄조직성분과의 관계 (Relationship between maceral composition and some parameters indicating the degree of coalification)

  • 박홍수
    • 자원환경지질
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    • 제32권1호
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    • pp.83-91
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    • 1999
  • Coal properties are controlled by the following two factors : One is the maceral components and the other is the degree of coalification. In other words, even if coals in question indicate the same degree of coalification, their chemical and physical properties considerably vary one another when their maceral components are different. It is well known that virtrinite reflectance is the best single criterion for the degree of coalification covering the whole range of coal rank. Some authors have recently insisted that sporinite fluorescence is more leliable coal rank parameter than vitrinite reflectance in case of low rank coals. In this paper, to examine the relince of sporinite fluorescence as coal rank parameter, fluidity analysis of coals is newly performed and the data are analyzed in comparision with those of virinite reflectance, sporinite fluorescence and maceral components. The results of this study are as follows; 1) Vitrinite reflectance becomes low when degradinite content is high within one columnar samples, and vice versa. 2) variation of vitrinite reflectance depend on degradinite content and on difference of roiginal plant. 3) In dealing with the Japanese paleogene coals, sporinite fluorescence is more reliable parameter indicating the degree of coalification than vitrinite reflectance. 4) Maximum fluidity increases exponetially in proportion to the increases of degradinite content.

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나일론 섬유의 형상비 및 혼입률 변화에 따른 고강도 콘크리트의 폭렬특성 (Spalling Properties of High Strength Concrete Made with Various Aspect Ratios and Fiber Contents of Nylon Fiber)

  • 송용원;허영선;이성연;한창평;양성환;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2007년도 춘계학술논문 발표대회
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    • pp.55-58
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    • 2007
  • This study investigates the spatting properties of high strength concrete, $60\sim80MPa$ class, designed with diverse aspect ratios and fiber content of nylon(NY). Test showed that increase of fiber content and aspect ratio in concrete decreased the fluidity of fresh concrete, especially for 1580 and 3000 aspect ratio of fiber. As for the compressive and tensile strength, adding NY fiber did not significantly affect the values In the range of high strength. After completing the fire test, the specimens containing both 750 and 1000 aspect ratios of fiber protected the spatting occurrence even in 0.05vol.% of fiber content. This specimens indicated the residual compressive strength ratio at 37%, showing the most favorable value among other specimens. Therefore, it is demonstrated that to protect the spalling in high strength concrete considering the effective fluidity, strength and economic efficiency altogether, adding 0.05vol.% of NY fiber with 750 aspect ratio Is beneficial.

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CKD 치환율 및 증점안정화제 혼입율 변화에 따른 경량기포 콘크리트의 품질특성 (Quality Properties of Lightweight Foamed Concrete with Variances in Incorporating Ratio of CKD and Adding Ratio of Stability Agent)

  • 신현섭;유승엽;정광복;배장춘;김성수;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2006년도 추계 학술논문 발표대회 논문집
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    • pp.67-70
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    • 2006
  • This study investigates the properties of light weight foamed concrete designed with various incorporating ratios of CKD and adding ratios of PS. Test showed that increase of CKD and PS decreased fluidity of fresh concrete, which need more addition of superplasticizer to secure proper fluidity. As for the sinking depth of specimens, using more CKD or PS decreased the value, due to the improvement of viscosity by micro particles of CKD and reduction of air loss by PS. Those methods are very effective to solve the sinking problem of light weight foamed concrete, which has been highly concerned. For the hardened concrete, compressive strength of specimens exhibited that using around 10% of CKD or 0.02% of PS increased the strength value, but decreased when incorporated or added more amounts of that, due to reduction of the sinking depth, caused by filling effect of the micro particle and improvement of the viscosity.

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